Concept explainers
(a)
Interpretation:
The Lande
Concept introduction:
The change in energy
The value of
(b)
Interpretation:
The reason why need never worry about this unusual value is to be stated.
Concept introduction:
The change in energy
The value of
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Chapter 16 Solutions
Physical Chemistry
- For a particle in a state having the wavefunction =2asinxa in the range x=0toa, what is the probability that the particle exists in the following intervals? a x=0to0.02ab x=0.24ato0.26a c x=0.49ato0.51ad x=0.74ato0.76a e x=0.98ato1.00a Plot the probabilities versus x. What does your plot illustrate about the probability?arrow_forwardWhat is the physical explanation of the difference between a particle having the 3-D rotational wavefunction 3,2 and an identical particle having the wavefunction 3,2?arrow_forwardIn a plot of ||2, the maximum maxima in the plot is/are called the most probable positions. What is/are the most probable positions for a particle-in-a-box when: a n=1 b n=2 c n=3 d Do you see a trend?arrow_forward
- State the Born-Oppenheimer approximation in words and mathematically, and indicate how the mathematical form is implied by the statement.arrow_forwardBased on the trend shown in Figure 11.5, draw the probability distribution of a harmonic oscillator wavefunction that has a very high value of n. Explain how this is consistent with the correspondence principle.arrow_forward
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