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Concept explainers
(a)
Interpretation: The total number of
Concept introduction: Triacylglycerol is produced by the reaction of one molecule of glycerol and three molecules of fatty acid. The three hydroxyl groups of glycerol get esterified on reaction with fatty acids.
(b)
Interpretation: The number of different kinds of functional groups present in a triacylglycerol in which all fatty acid residues present come from saturated fatty acids has to be predicted.
Concept introduction: Triacylglycerol is produced by the reaction of one molecule of glycerol and three molecules of fatty acid. The three hydroxyl groups of glycerol get esterified on reaction with fatty acids.
(c)
Interpretation: The names for the functional groups present in a triacylglycerol in which all fatty acid residues present come from saturated fatty acids has to be predicted.
Concept introduction: Triacylglycerol is produced by the reaction of one molecule of glycerol and three molecules of fatty acid. The three hydroxyl groups of glycerol get esterified on reaction with fatty acids.
(d)
Interpretation: The number of subunit linkages present in a triacylglycerol in which all fatty acid residues present come from saturated fatty acids has to be predicted.
Concept introduction: Triacylglycerol is produced by the reaction of one molecule of glycerol and three molecules of fatty acid. The three hydroxyl groups of glycerol get esterified on reaction with fatty acids.
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Chapter 19 Solutions
EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
- Which of the following are possible products of the partial hydrogenation, with two molecules of H2, of the following molecule? 18:2 Fatty acid 18:0 Fatty acid 18:1 Fatty acid (Select all that apply.) O 18:1, 18:0, 18:0 O 18:0, 18:0, 18:1 O 18:0, 18:0, 18:0arrow_forwarddraw condensed structural formula for monosaturated omega-3 fatty acid with 14 carbon atoms. draw the condensed structural formula for the triacylglycerol made from 3 saturated fatty acids that are 20 carbons longarrow_forwardName the following fatty acids by the symbol (C:B)arrow_forward
- Describe the structure of triacylglycerol (TAG) and explain the hydrolysis of TAG.arrow_forwardDraw the skeletal structure of the products formed when the given triacylglycerol is hydrolyzed with water in the presence of sulfuric acid. You may draw the structures in any arrangement that you like, so long as they aren't touching. Oarrow_forwardConsider olive oil, an oil with a high percentage of fat derived from oleic acid (otherwise known as cis[18:1] fatty acid). a, Explain why such a structure may allow olive oil to be one of the "healthier" oils? b, why such a structure may allow olive oil to be a liquid at room temperature, while butter and lard are solid at room temperature? c, why such a structure may cause olive oil to be prone to oxidative damage upon exposure to air and heat?arrow_forward
- Using skeletal structures, draw the structure of a simple triacylglyceride containing 1 eicosapentanoic acid, 1 myristic acid and 1 oleic acid residues, with label.arrow_forwardisomaltose is a disaccharide which can be obtained by enzymatic hydrolysis of amylopectin. Deduce the structure of isomaltose from the following data: a. The hydrolysis of 1 mole of isomaltose with acid or alpha-glucosidase yields 2 moles of D- glucose. b. Isomaltose is a reducing sugar c. Isomaltose is oxidized with bromine water to isomaltonic acid. Insomaltonic acid methylation followed by hydrolysis yielded 2,3,4,6-tetra-O-methyl-D-glucose and 2,3,4,5- tetra-O-methyl-D-gluconate acid. d. Isomaltose methylation itself followed by hydrolysis to produce 2,3,4,6-tetra-O-methyl- D-glucose and 2,3,4-tri-O-methyl-D-glucose. Describe according to the four points abovearrow_forwardOlestra has been used in certain snack foods as an alternative to fats and oils. Its structure consists of a sucrose molecule in which all free hydroxyl groups have formed esters with oleic acid (an 18-carbon monounsaturated fatty acid). Olestra molecules have no caloric value because they are exceptionally large and cannot be digested. Draw the structure of olestra. Use R-COOH as an abbreviation for oleic acid.arrow_forward
- Draw the structures of the products formed by hydrolysis of the following tripeptide at physiological pH. Val-Gly-Ile Note: Reference the Naturally occurring amino acids data table for additional information.arrow_forwardDraw the structure of a triacylglycerol containing stearic acid, palmitic acid, and oleic acid.arrow_forwardWrite the structural formula of a triacylglycerol that contains one unit each of lauric acid, palmitic acid, and oleic acid. How many other triacylglycerols, each containing all three of these acids, are possible?arrow_forward
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