Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 19, Problem 19.32P
Interpretation Introduction
Interpretation:
The structure of imine derivative of pyridoxal phosphate with the lysine residue of protein is to be drawn.
Concept introduction:
The chemical compounds that consist of a double bond between carbon and nitrogen atom
The chemical compounds in which carbon is bonded with the acidic and basic group along with hydrocarbon side chain are known as amino acids. They combine sequentially to generate a protein.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Give the structure of azo dye that would be formed from the given amine and coupling component.
The side chain of cysteine is weakly acidic. Suppose in a protein, the side chain of a cysteine residue is surrounded by the side chains of several isoleucine residues. Would this make the side chain of the cysteine residue more acidic or less acidic? Please explain your answer.
Bradykinin is a linear nonapeptide released by blood plasma globulin in response
to a wasp sting. It is a very potent pain-causing agent. Its constituent amino
acids are 2R, G, 2F, 3P, S. The sue of 2,4-dinitrofluorobenzene and
carboxypeptidase shows that both terminal residues are arginine. Partial
hydrolysis of bradykinin gives the following di- and tripeptides:
FS + PGF +PP + SPF + FR + RP
Chapter 19 Solutions
Organic Chemistry
Ch. 19 - Prob. 19.1PCh. 19 - Prob. 19.2PCh. 19 - Prob. 19.3PCh. 19 - Prob. 19.4PCh. 19 - Prob. 19.5PCh. 19 - Prob. 19.6PCh. 19 - Prob. 19.7PCh. 19 - Prob. 19.8PCh. 19 - Prob. 19.9PCh. 19 - Prob. 19.10P
Ch. 19 - Prob. 19.11PCh. 19 - Prob. 19.12PCh. 19 - Prob. 19.13PCh. 19 - Prob. 19.14PCh. 19 - Prob. 19.15PCh. 19 - Prob. 19.16PCh. 19 - Prob. 19.17PCh. 19 - Prob. 19.18PCh. 19 - Prob. 19.19PCh. 19 - Prob. 19.20PCh. 19 - Prob. 19.21PCh. 19 - Prob. 19.22PCh. 19 - Prob. 19.23PCh. 19 - Prob. 19.24PCh. 19 - Prob. 19.25PCh. 19 - Prob. 19.26PCh. 19 - Prob. 19.27PCh. 19 - Prob. 19.28PCh. 19 - Prob. 19.29PCh. 19 - Prob. 19.30PCh. 19 - Prob. 19.31PCh. 19 - Prob. 19.32PCh. 19 - Prob. 19.33PCh. 19 - Prob. 19.34PCh. 19 - Prob. 19.35PCh. 19 - Prob. 19.36PCh. 19 - Prob. 19.37PCh. 19 - Prob. 19.38PCh. 19 - Prob. 19.39PCh. 19 - Prob. 19.40APCh. 19 - Prob. 19.41APCh. 19 - Prob. 19.42APCh. 19 - Prob. 19.43APCh. 19 - Prob. 19.44APCh. 19 - Prob. 19.45APCh. 19 - Prob. 19.46APCh. 19 - Prob. 19.47APCh. 19 - Prob. 19.48APCh. 19 - Prob. 19.49APCh. 19 - Prob. 19.50APCh. 19 - Prob. 19.51APCh. 19 - Prob. 19.53APCh. 19 - Prob. 19.54APCh. 19 - Prob. 19.55APCh. 19 - Prob. 19.56APCh. 19 - Prob. 19.57APCh. 19 - Prob. 19.58APCh. 19 - Prob. 19.59APCh. 19 - Prob. 19.60APCh. 19 - Prob. 19.61APCh. 19 - Prob. 19.62APCh. 19 - Prob. 19.63APCh. 19 - Prob. 19.64APCh. 19 - Prob. 19.65APCh. 19 - Prob. 19.66APCh. 19 - Prob. 19.67APCh. 19 - Prob. 19.68APCh. 19 - Prob. 19.69APCh. 19 - Prob. 19.70APCh. 19 - Prob. 19.71APCh. 19 - Prob. 19.72AP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- A. Distinguish the amine component from the coupling component in the given azo dye. B. Sketch the azo dye that would be formed from the two given components.arrow_forwardWhen the (R,R) isomer of the amine shown is treated with an excess of methyl iodide, then silver oxide, then heated, the majorproduct is the Hofmann product.) Some Zaitsev product is also formed. It has the (E) configuration. When the same amine is treated with mCPBA and heated, theZaitsev product has the (Z) configuration. Use stereochemical drawings of the transition states to explain these observationsarrow_forwardExperimental observations show that thiocyanate (SCN- ), the conjugate base of thiocyanic acid (pKa = 1.1 at 25 °C), is quite soluble in neutral water at pH > 2. In the space provided below, explain this experimental observation. That is, why does SCN– readily dissolve in water when the pH > 2?arrow_forward
- The phospholipid structure shown above provides for ___? The hydrophobic by-layer of cell membranes The hydrophilic inner and outer surfaces of cell membranes a and barrow_forwardaminophylline is a good water soluble derivative of theophylline as ethylene diamine derivative in order to enhance its water solubility for formulation options and to enhance the bioavailability of theophylline . dose complexation phenomena involved in aminophylline preparation? how? show through drawing chemical structure as well as drawing the electronic configuration for complexationarrow_forwardWhich of the attached amines can be used to resolve a racemic mixture of amino acids?arrow_forward
- Give a suitable chemical reaction to distinguish between a primary and a secondary amine. Suggest one way of Increasing the basicity of an amine and give a specific example of its application.arrow_forwardGlutamic acid is a naturally occurring α-amino acid that contains acarboxy group in its R group side chain. (Glutamic acid isdrawn in its neutral form with no charged atoms, a form that does not actually exist at any pH.) a.) What form of glutamic acid exists at pH = 1?b.) If the pH is gradually increased, what form of glutamic acid exists afterone equivalent of base is added? After two equivalents? After threeequivalents?c.) Propose a structure of monosodium glutamate, the common flavorenhancer known as MSG.arrow_forwardGive answers to these questions. Choose from the options A.The efficacy of salicylic acid as well as its solubility in water as compared to p-hydroxybenzoic acid is greatly affected by what phenomenon? Dipole moment Hydrogen bonding Ionic bonding Hydrophobic effect B.This is the most important CYP 450 isozyme that is responsible for the metabolism of almost 50% of the drugs available in the market CYP 2D6 CYP 2A9 CYP3A4 CYP 1A2 C.Ketones are oxidized into Aldehydes Carboxylic acid Secondary alcohol Unable to oxidized D.G- protein coupled receptors are activated via these secondary messengers, except cAMP DAG IP3 ATP E.The gas use for sterilizing heat labile substances Gluteraldehyde Ethylene oxide Nitrogen Acetylenearrow_forward
- Hypoglycin A, an amino acid derivative found in unripened lychee, is anacutely toxic compound that produces seizures, coma, and sometimesdeath in undernourished children when ingested on an empty stomach. (a) Draw the neutral, positively charged, and negatively charged forms of hypoglycin A. (b) Which form predominates at pH = 1, 6, and 11? (c) What is the structure of hypoclycin A at its isoelectric point?arrow_forwardFor an Electrophilic Aromatic substitution of Nitrobenzene and Aminobenzene predict the directing influences of the Nitro and Amino groups respectively on the incoming group. A. Nitro is strongly deactivating and meta directing ; Amino is strongly activating and ortho,para directing. B. Nitro is strongly deactivating and ortho,para directing; Amino is strongly deactivating and ortho, para directing. C. Nitro is strongly deactivating and para directing; Amino is strongly deactivating and ortho directing. D. Nitro is strongly deactivating and ortho,para directing; Amino is strongly activating and meta directing. E. Amino is strongly deactivating and ortho,para directing; Nitro is strongly activating and meta directing. F. Amino is strongly deactivating and meta directing ; Nitro is strongly activating and ortho,para directing.arrow_forwardRank each of the following sets of nitrogen bases in terms of basicity and explain your answerarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you