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Concept explainers
(a)
Interpretation:
The structure of the product formed when
Concept introduction:
An ester is formed by the reaction of carboxylic with alcohol in the presence of an acid catalyst. This reaction is known as esterification.
Esters end with a suffix,
(b)
Interpretation:
The structure of the product formed when adipic acid is heated in a large excess of
Concept introduction:
An ester is formed by the reaction of carboxylic with alcohol in the presence of an acid catalyst. This reaction is known as esterification.
Esters end with a suffix,
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Chapter 20 Solutions
EBK ORGANIC CHEMISTRY
- Biphenyl has the following structure.(a) Is biphenyl a (fused) polynuclear aromatic hydrocarbon?(b) How many pi electrons are there in the two aromatic rings of biphenyl? How does this number compare with that for naphthalene?(c) The heat of hydrogenation for biphenyl is about 418 kJ>mol (100 kcal>mol). Calculate theresonance energy of biphenyl.(d) Compare the resonance energy of biphenyl with that of naphthalene and with that of two benzene rings. Explain thedifference in the resonance energies of naphthalene and biphenyl.arrow_forward(b) Toluene reacts with and bromine in different conditions of reaction. Write the chemical equation for both reaction. Name the type of reaction for both reaction.arrow_forwardGive the structural formulae and name the functional groups of the following compounds. (a) 3-chlorobut-1-ene Name the functional group: (b) butanedioic acid Name the functional group: (c) propanamide Name the functional group: (d) 3-methylbutanal Name the functional group:arrow_forward
- 2.) what is the chemical reaction of butadiene sulfone and maleic anhydride are heated together.arrow_forwardWrite a condensed structural formula for each of the following:(a) an acid with the formula C4H8O2, (b) a cyclicketone with the formula C5H8O, (c) a dihydroxy compoundwith the formula C3H8O2, (d) a cyclic ester with theformula C5H8O2.arrow_forward3B. Will phenyl magnesium bromide react with formic acid to form an ester? If so, write the reaction. If not, explain why.arrow_forward
- 5. Give the structural formulae and name the functional groups of the following compounds. (a) 3-chlorobut-1-ene (b) butanedioic acid Name the functional group: (c) propanamide Name the functional group: (d) 3-methylbutanal Name the functional group: Name the functional group:arrow_forwardWhen the conjugate acid of aniline, C6H5NH3+, reacts with the acetate ion, the following reaction takes place: C6H5NH3+(aq)+CH3COO(aq)C6H5NH2(aq)+CH3COOH(aq) If Kafor C6H5NH3+ is 1.35105 and Kafor CH3COOH is 1.86105 , what is K for the reaction?arrow_forwardLipoic acid is required by many microorganisms for proper growth. As a disulfide, it functions in the living system by catalyzing certain oxidation reactions and is reduced in the process. Write the structure of the reduction product.arrow_forward
- Draw the structure of each of the following molecules. (a) pentanoic anhydride; (b) hexanoic propanoic anhydride; (c) ethanoic 3-methylpentanoic anhydridearrow_forwardGive an IUPAC and common name for each of the following naturally occurring carboxylic acids: (a) CH3CH(OH)CO2H (lactic acid); (b) HOCH2CH2C(OH)(CH3)CH2CO2H (mevalonic acid).arrow_forwardCompounds B and C are hydrocarbons with the structural formulae as shown below. CH, „CH, в (a) Name compounds B and C according to the IUPAC nomenclature. (b) Both B and C can undergo oxidation reaction with the same oxidizing agent. Write chemical equations involved and explain the differences between these two reactions. (c) Name one reaction that converts B to methylcyclohexane.arrow_forward
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningChemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
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