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(a)
Interpretation:
The product formed when
Concept introduction:
Decarboxylation reaction occurs when a
(b)
Interpretation:
The product formed when malonic acid is heated in acidic medium is shown below.
Concept introduction:
Decarboxylation reaction occurs when a
(c)
Interpretation:
The product formed when carbonic acid derivative is heated in acidic medium is to be stated.
Concept introduction:
Decarboxylation reaction occurs when a
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Chapter 20 Solutions
EBK ORGANIC CHEMISTRY
- Draw line structures of the following compounds and the product you would obtain from the reduction of each.(a) Isopropyl methyl ketone (b) p-Hydroxybenzaldehyde(c) 2-Methylcyclopentanonearrow_forwardPredict the products formed when cyclohexanone reacts with the following reagents.(a) CH3NH2, Harrow_forwardProvide IUPAC names for the following compounds. (a) -OH (b)arrow_forward
- Which is the major isolated organic product of the reaction shown? (A) (B) Pd(PPH3)4 KOHarrow_forwardFor each pair of compounds, predict which compound has a higher boiling point. then explain why that compound has a higher boiling point. (a) isopropyl bromide and n-butyl bromide (b) isopropyl chloride and tert-butyl bromide (c) 1-bromobutane and 1-chlorobutanearrow_forward6) Which is the organic product for the following reaction? (a) (b) (c) (d) LOH OH COOH OH OH COOH COOH KMnO4 H₂O (e) None of the above products will be formedarrow_forward
- Predict the major product when each reagent reacts with ethylene oxide.(a) NaOCH2CH3 (sodium ethoxide) (b) NaNH2 (sodium amide)arrow_forwardThe odor of ripe bananas and many other fruits is due to the presence of esters. For example: Banana oil (isopentyl acetate) (a) Write the name (common or IUPAC) of the ester responsible for the fragrance of the following: pineapple, orange, apple, peach, & lavender (b) Choose one fragrant from (a) and name the alcohol and the carboxylic acid needed to synthesize this ester. (c) Show the detailed mechanism of the Fischer Esterification reaction that will be involved in the synthesis of the fragrant you have chosen in part (a).arrow_forwardWhich of the following would successfully perform the shown reaction? (A) (B) (C) (D) OH 1) NaH 2) EtBr NEt3 Mgº ether MeO OMe [TSOH] H ? PCCarrow_forward
- Predict the products formed when cyclohexanone reacts with the following reagents. (k) sodium cyanide (l) acidic hydrolysis of the product from (k)arrow_forwardAre the following halogenated or non- halogented?(a) Cyclohexyl hydrogen sulfate(b) p-Toluenesulfonic acidarrow_forwardCompound X (C4H9Br) reacts by heating with NaOH in H2O to form Y. The compound Y then undergoes acid catalysed hydration by H2SO4 in 180°C to form 2-methyl prop-1-ene. (e) Determine the structure of X and Y. (f) Predict a MAJOR product when compound Y reacts with H2SO4 in 140°C. (g) Draw a structural isomer of X. Name the isomer using IUPAC nomenclature. (h) Describe a chemical test to distinguish between compound Y and 1-butanol.arrow_forward
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