Concept explainers
Interpretation: The order of decreasing basicity of the given nitrogen compounds is to be stated. The structures of their conjugate acids are to be drawn. Their
Concept introduction: When an acid donates a proton, the species formed is known as conjugate base and when the base accepts a proton, the species formed is known as conjugate acid.
The strength of an acid is decided by the stability of its conjugate base. The stability depends on the delocalization of the charge through resonance.
To determine: The order of decreasing basicity of the given nitrogen compounds, the structures of their conjugate acids, their
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Organic Chemistry (9th Edition)
- Which of the following reactions favor formation of the products? (For the pKa values necessary to solve this problem, see Appendix I. Recall that the equilibrium favors formation of the weaker acidarrow_forwardFollowing is a structural formula for guanidine, the compound by which migratory birds excrete excess metabolic nitrogen. The hydrochloride salt of this compound is a white crystalline powder, freely soluble in water and ethanol. Q. Does proton transfer to guanidine occur preferentially to one of its -NH2 groups (cation A) or to its =NH group (cation B)? Explain.arrow_forwardexplain in great detail why the pKa values are what they are and compare them among the three compounds. The conjugate acids that are protonated are drawn in red for each compound. Which one based on the pKa is most acidic and what does that tell you about how basic their lone pairs are?arrow_forward
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- Write the equilibrium-constant expressions and obtainnumerical values for each constant in. (a) the basic dissociation of aniline, C6H5NH2. (b) the acidic dissociation of hypochlorous acid,HClO. (c) the acidic dissociation of methyl ammoniumhydrochloride, CH3NH3Cl. (d) the basic dissociation of NaNO2. (e) the dissociation of H3AsO3to H3O+and AsO33-. (f) the reaction of C2O42-with H2O to give H2C2O4and OH-. show solutionarrow_forwardConsider the following compounds that vary from nearly nonacidic to strongly acidic. Draw the conjugate bases of these compounds, and explain why the acidity increases so dramatically with substitution by nitro groups.CH4 CH3NO2 CH2(NO2)2 CH(NO2)3 pKa ≅ 50 pKa = 10.2 pKa = 3.6 pKa = 0.17arrow_forwardGive the clear handwritten answer and complete the reactionarrow_forward
- Which of the two compounds shown below is acidic? Why?arrow_forwardPrimary amines can be prepared from amides by Hoffman's reaction. Write a general equation for the reaction and give reagents with reaction conditions for this reaction. What property of amines is responsible for them being basic. Suggest one way of Increasing the basicity of an amine and give a specific example of its application.arrow_forwardRank the following compounds in terms of increasing acidity (least acidic first). Explain your ranking. Making sure to say which hydrogen in each molecule is the most acidic, and discuss the relative stability of the conjugate bases.arrow_forward
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