Concept explainers
(a)
To determine: The amount of charge separation in the given
Interpretation: The amount of charge separation in the given
Concept introduction: The polarity of an individual bond is measured as its bond dipole moment. A quantity that describes two opposite charges separated by a distance is the dipole moment. The dipole moment is calculated by the formula,
(b)
To determine: The relative importance of the given two resonance contributors.
Interpretation: The relative importance of the given two resonance contributors is to be evaluated.
Concept introduction: The delocalization of electrons due to the presence of lone pair of electrons and double bond is called resonance. The resonance structure is more stable if there are more resonating structures. In resonance forms of any compound, the connectivity of atoms is same but the distribution of electrons is different. Resonance helps to explain the structure and reactivity of organic molecules.
Want to see the full answer?
Check out a sample textbook solutionChapter 2 Solutions
Organic Chemistry (9th Edition)
- (a) Is 2-pyridone aromatic?(b) Use resonance forms to explain your answer to (a). Also explain why the protons atd 7.31 and d 7.26 are more deshielded than the other two (d 6.15 and d 6.57)arrow_forwardWrite the Ka2 reaction of sulfuric acid (H2SO4) and the Kb2 reaction of disodium oxalate (Na2C2O4) and find their numerical values.arrow_forwardThe C‚N triple bond in acetonitrile has a dipole moment of about 3.6 D and a bond length of about 1.16 Å. Calculate the amount of charge separation in this bond. How important is the charge-separated resonance form in the structure of acetonitrile?arrow_forward
- Une or more valid answers. Explain the answers. The localization or resonance energy: a) Justify the increased stability of molecules that have unlocated electrons b) It is a consequence of the mobility of the electrons that form the “sigma” bonds c) It occurs in compounds with conjugated double bonds, but not in aromatic compounds d) It is shown by the experimental values of the enthalpies of formation.arrow_forwardThe Hammett analyses have been done on two substrates which obtain a rho value of 3.8. from the correlation with positive sigma constants (A) while the other set of substituents (B). has a rho value of -2 using the regular sigma values: part a) identify which rho value matches the substituents using resonance as an argument.arrow_forwardTLC relies on differences in non-covalent forces. Explain the role of these non-covalent interactions in determining the Rf value obtained.arrow_forward
- For each band below found in the 3700-3200 cm-1 region, draw an approximate shape for the expected bond A.) Alcohol B.) 1° Aminearrow_forwardIs it justifiable to neglect the hydrolysis of PO43- in the calculation for Ka3? Explain your reasoning.arrow_forward5- In each part, choose the structure that best adapts to the infrared spectrumarrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage LearningOrganic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage LearningMacroscale and Microscale Organic ExperimentsChemistryISBN:9781305577190Author:Kenneth L. Williamson, Katherine M. MastersPublisher:Brooks Cole