Organic Chemistry (9th Edition)
Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
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Diol
In chemistry there are so many chemical compounds that have a hydroxyl group but a chemical compound having two hydroxyl groups (-OH) is termed as a diol. It also implies the presence of two alcohols whereas polyols contain two or more than two hydroxyl …
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Chapter 2.3, Problem 2.7P

(a)

Interpretation Introduction

To determine: The compound that is more soluble in water between the given pair of compound.

Interpretation: The compound that is more soluble in water between the given pair of compound is to be predicted.

Concept introduction: The solubility of compounds in water depends upon the types of bonding between them.

Hydrogen bonding is the strongest intermolecular force present between the substances and Vander Waals is the weakest intermolecular force present between the substances.

(b)

Interpretation Introduction

To determine: The compound that is more soluble in water between the given pair of compound.

Interpretation: The compound that is more soluble in water between the given pair of compound is to be predicted.

Concept introduction: The solubility of compounds in water depends upon the types of bonding between them.

Hydrogen bonding is the strongest intermolecular force present between the substances and Vander Waals is the weakest intermolecular force present between the substances.

(c)

Interpretation Introduction

To determine: The compound that is more soluble in water between the given pair of compound.

Interpretation: The compound that is more soluble in water between the given pair of compound is to be predicted.

Concept introduction: The solubility of compounds in water depends upon the types of bonding between them.

Hydrogen bonding is the strongest intermolecular force present between the substances and Vander Waals is the weakest intermolecular force present between the substances.

(d)

Interpretation Introduction

To determine: The compound that is more soluble in water between the given pair of compound.

Interpretation: The compound that is more soluble in water between the given pair of compound is to be predicted.

Concept introduction: The solubility of compounds in water depends upon the types of bonding between them.

Hydrogen bonding is the strongest intermolecular forces present between the substances and Vander Waals is the weakest intermolecular forces present between the substances.

(e)

Interpretation Introduction

To determine: The compound that is more soluble in water between the given pair of compound.

Interpretation: The compound that is more soluble in water between the given pair of compound is to be predicted.

Concept introduction: The solubility of compounds in water depends upon the types of bonding between them.

Hydrogen bonding is the strongest intermolecular force present between the substances and Vander Waals is the weakest intermolecular force present between the substances.

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Molecule Type Boiling point (°C)  CH3CH2CH3  Alkane  -42 CH3CHO  Aldehyde +21 CH3CH2OH   Alcohol  +78 i. Why is the boiling point of the aldehyde greater than that of the alkane?ii. Why is the boiling point of alcohol the highest?iii. Explain why the solubility of aldehydes and alcohols falls as the molecules get bigger.
1. (a) Which compound would have the highest boiling point?     CH3CH2CH2OH     CH3CH2CH2Cl     CH3CH2CH2CH3     CH3CH2OCH3 2. (b) Which compound is expected to be most soluble in water?     CH3CH2CH2CH2OH     CH3CH2CH2CH2SH     CH3CH2CH2CH2Cl     CH3CH2CH2CH2CH3
i. Why is the boiling point of the aldehyde greater than that of the alkane? ii. Why is the boiling point of alcohol the highest? iii. Explain why the solubility of aldehydes and alcohols falls as the molecules get bigger.

Chapter 2 Solutions

Organic Chemistry (9th Edition)

Ch. 2.1A - Prob. 2.1PCh. 2.1B - The NF bond is more polar than the NH bond: but...Ch. 2.1B - For each of the following compounds 1. Draw the...Ch. 2.1B - Two isomers of 1,2-dichloroethene are known One...Ch. 2.2C - Prob. 2.5PCh. 2.2C - Prob. 2.6PCh. 2.3 - Prob. 2.7PCh. 2.4 - Calculate the pH of the following solutions a....Ch. 2.6A - Ammonia appears in Table 2-2 as both an acid and a...Ch. 2.7 - Write equations for the following acid-base...
Ch. 2.7 - Ethanol, methylamine. and acetic acid are all...Ch. 2.8 - Prob. 2.12PCh. 2.10 - Write equations for the following acid-base...Ch. 2.10 - Rank the following acids in decreasing order of...Ch. 2.11 - Prob. 2.15PCh. 2.11 - Prob. 2.16PCh. 2.11 - Consider each pair of bases and explain which one...Ch. 2.12 - Which is a stronger base ethoxide ion or acetate...Ch. 2.12 - Prob. 2.19PCh. 2.12 - Prob. 2.20PCh. 2.12 - Prob. 2.21PCh. 2.12 - Choose the more basic member of each pair of...Ch. 2.14 - Prob. 2.23PCh. 2.15D - Classify the following hydrocarbons and draw a...Ch. 2.16D - Prob. 2.25PCh. 2.17C - Draw a Lewis structure and classify each of the...Ch. 2.17C - Circle the functional groups in the following...Ch. 2 - The CN triple bond in acetonitrile has a dipole...Ch. 2 - Prob. 2.29SPCh. 2 - Sulfur dioxide has a dipole moment of 1.60 D....Ch. 2 - Which of the following pure compounds can form...Ch. 2 - Predict which member of each pair is more soluble...Ch. 2 - Prob. 2.33SPCh. 2 - Prob. 2.34SPCh. 2 - Predict which compound in each pair has the higher...Ch. 2 - All of the following compounds can react as acids...Ch. 2 - Rank the following species in order of increasing...Ch. 2 - Rank the following species in order of increasing...Ch. 2 - The Ka of phenylacetic acid is 5 2 105, and the...Ch. 2 - The following compound can become protonated on...Ch. 2 - The following compounds are listed in increasing...Ch. 2 - Prob. 2.42SPCh. 2 - Prob. 2.43SPCh. 2 - Compare the relative acidity of 1-molar aqueous...Ch. 2 - The following compounds can all react as acids. a....Ch. 2 - The following compounds can all react as bases. a....Ch. 2 - The following compounds can all react as acids. a....Ch. 2 - Prob. 2.48SPCh. 2 - Methyllithium (CH3Li) is often used as a base in...Ch. 2 - Label the reactants in these acid-base reactions...Ch. 2 - In each reaction, label the reactants as Lewis...Ch. 2 - Prob. 2.52SPCh. 2 - Each of these compounds can react as a nucleophile...Ch. 2 - Prob. 2.54SPCh. 2 - Give a definition and an example for each class of...Ch. 2 - Circle the functional groups in the following...Ch. 2 - Prob. 2.57SP
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