Synthetic approach to synthesize an aromatic halogenation reaction in one step. Concept introduction: This is a type of aromatic halogenation reaction. In this reaction Bromine, Br 2, does not react with benzene under normal conditions, but bromination produces bomobenzene in the presence of Fe or FeBr 3 where FeBr 3 acts as a Lewis acid. The product of an aromatic halogenation, an aryl halide, could be the desired target in the synthesis. An aryl halide could be a useful synthetic intermediate such as in the production of a Grignard reagent. PBr 3 can be used to convert the OH group into a good leaving group.

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Answer 1

Question

Chapter 22, Problem 22.3P

Interpretation Introduction

Interpretation:

Synthetic approach to synthesize an aromatic halogenation reaction in one step.

Concept introduction:

This is a type of aromatic halogenation reaction. In this reaction Bromine, Br_2, does not react with benzene under normal conditions, but bromination produces bomobenzene in the presence of Fe or FeBr₃ where FeBr₃ acts as a Lewis acid. The product of an aromatic halogenation, an aryl halide, could be the desired target in the synthesis. An aryl halide could be a useful synthetic intermediate such as in the production of a Grignard reagent.

PBr₃ can be used to convert the OH group into a good leaving group.

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Answer 2

Question

Chapter 22, Problem 22.3P

Interpretation Introduction

Interpretation:

Synthetic approach to synthesize an aromatic halogenation reaction in one step.

Concept introduction:

This is a type of aromatic halogenation reaction. In this reaction Bromine, Br_2, does not react with benzene under normal conditions, but bromination produces bomobenzene in the presence of Fe or FeBr₃ where FeBr₃ acts as a Lewis acid. The product of an aromatic halogenation, an aryl halide, could be the desired target in the synthesis. An aryl halide could be a useful synthetic intermediate such as in the production of a Grignard reagent.

PBr₃ can be used to convert the OH group into a good leaving group.

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Answer 3

Question

Chapter 22, Problem 22.3P

Interpretation Introduction

Interpretation:

Synthetic approach to synthesize an aromatic halogenation reaction in one step.

Concept introduction:

This is a type of aromatic halogenation reaction. In this reaction Bromine, Br_2, does not react with benzene under normal conditions, but bromination produces bomobenzene in the presence of Fe or FeBr₃ where FeBr₃ acts as a Lewis acid. The product of an aromatic halogenation, an aryl halide, could be the desired target in the synthesis. An aryl halide could be a useful synthetic intermediate such as in the production of a Grignard reagent.

PBr₃ can be used to convert the OH group into a good leaving group.

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Answer 4

Question

Chapter 22, Problem 22.3P

Interpretation Introduction

Interpretation:

Synthetic approach to synthesize an aromatic halogenation reaction in one step.

Concept introduction:

This is a type of aromatic halogenation reaction. In this reaction Bromine, Br_2, does not react with benzene under normal conditions, but bromination produces bomobenzene in the presence of Fe or FeBr₃ where FeBr₃ acts as a Lewis acid. The product of an aromatic halogenation, an aryl halide, could be the desired target in the synthesis. An aryl halide could be a useful synthetic intermediate such as in the production of a Grignard reagent.

PBr₃ can be used to convert the OH group into a good leaving group.

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Answer 5

Chapter 22, Problem 22.3P

Interpretation Introduction

Interpretation:

Synthetic approach to synthesize an aromatic halogenation reaction in one step.

Concept introduction:

This is a type of aromatic halogenation reaction. In this reaction Bromine, Br_2, does not react with benzene under normal conditions, but bromination produces bomobenzene in the presence of Fe or FeBr₃ where FeBr₃ acts as a Lewis acid. The product of an aromatic halogenation, an aryl halide, could be the desired target in the synthesis. An aryl halide could be a useful synthetic intermediate such as in the production of a Grignard reagent.

PBr₃ can be used to convert the OH group into a good leaving group.

Answer 6

Chapter 22, Problem 22.3P

Interpretation Introduction

Interpretation:

Synthetic approach to synthesize an aromatic halogenation reaction in one step.

Concept introduction:

This is a type of aromatic halogenation reaction. In this reaction Bromine, Br_2, does not react with benzene under normal conditions, but bromination produces bomobenzene in the presence of Fe or FeBr₃ where FeBr₃ acts as a Lewis acid. The product of an aromatic halogenation, an aryl halide, could be the desired target in the synthesis. An aryl halide could be a useful synthetic intermediate such as in the production of a Grignard reagent.

PBr₃ can be used to convert the OH group into a good leaving group.

Answer 7

Chapter 22, Problem 22.3P

Interpretation Introduction

Interpretation:

Synthetic approach to synthesize an aromatic halogenation reaction in one step.

Concept introduction:

This is a type of aromatic halogenation reaction. In this reaction Bromine, Br_2, does not react with benzene under normal conditions, but bromination produces bomobenzene in the presence of Fe or FeBr₃ where FeBr₃ acts as a Lewis acid. The product of an aromatic halogenation, an aryl halide, could be the desired target in the synthesis. An aryl halide could be a useful synthetic intermediate such as in the production of a Grignard reagent.

PBr₃ can be used to convert the OH group into a good leaving group.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 22 - Prob. 22.1P Ch. 22 - Prob. 22.2P Ch. 22 - Prob. 22.3P Ch. 22 - Prob. 22.4P Ch. 22 - Prob. 22.5P Ch. 22 - Prob. 22.6P Ch. 22 - Prob. 22.7P Ch. 22 - Prob. 22.8P Ch. 22 - Prob. 22.9P Ch. 22 - Prob. 22.10P

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Chapter 22 Solutions