ORGANIC CHEMISTRY E-BOOK W/SMARTWORK5
ORGANIC CHEMISTRY E-BOOK W/SMARTWORK5
2nd Edition
ISBN: 9780393664034
Author: KARTY
Publisher: NORTON
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Chapter 22, Problem 22.63P
Interpretation Introduction

Interpretation:

Synthesis of the stilbene by using benzene and any carboxylic acid is to be determined.

Concept introduction:

SOCl2 is used for the conversion of acid into acyl chloride. By using this reaction bad leaving group (-OH) is converted into a good leaving group.

Friedel-crafts acylation is an electrophilic aromatic substitution reaction. In this reaction, acyl halide is reacted with benzene in the presence of Lewis acid AlCl3. In this reaction, a new C-C  bond is formed between electrophile and nucleophile.

The reducing agent NaBH4 in the presence of ethanol used for the reduction of aldehyde or ketone in alcohol. NaBH4 reduce carbonyl group into a hydroxyl group (-OH).

Elimination of water is taking place in the presence of H3PO4 and heat results in the formation of the alkene.

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Chapter 22 Solutions

ORGANIC CHEMISTRY E-BOOK W/SMARTWORK5

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