The synthesis of the given product from suitable Michael donor and acceptor. Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized. Concept introduction: When the double bond of an α , β − unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α , β − unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

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Answer 1

Question

Chapter 22.18, Problem 22.56P

(a)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(b)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(c)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(d)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(e)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(f)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

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Show how the following products can be synthesized via a Michael reaction.

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Provide the Major product for the following reactions

Answer 2

Question

Chapter 22.18, Problem 22.56P

(a)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(b)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(c)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(d)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(e)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(f)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

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Answer 3

Question

Chapter 22.18, Problem 22.56P

(a)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(b)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(c)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(d)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(e)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(f)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

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Answer 4

Question

Chapter 22.18, Problem 22.56P

(a)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(b)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(c)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(d)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(e)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(f)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

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Answer 5

Chapter 22.18, Problem 22.56P

(a)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(b)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(c)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(d)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(e)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(f)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 6

Chapter 22.18, Problem 22.56P

(a)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 7

Chapter 22.18, Problem 22.56P

(a)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 8

(b)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 9

(b)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 10

(c)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 11

(c)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 12

(d)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 13

(d)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 14

(e)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 15

(e)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 16

(f)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 17

(f)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 18

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Answer 19

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Answer 20

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Answer 21

Ch. 22.2A - Prob. 22.2P Ch. 22.4 - Without looking back, propose a mechanism for the...Ch. 22.4 - Prob. 22.8P Ch. 22.4 - Prob. 22.9P Ch. 22.5A - Prob. 22.10P Ch. 22.5A - Prob. 22.11P Ch. 22.5B - Prob. 22.12P Ch. 22.5B - Predict the products of the following reactions....Ch. 22.5B - Which compounds will give positive iodoform tests?...Ch. 22.5C - Propose a mechanism for the acid-catalyzed...

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