(a)
Interpretation:
The expected products of the given acid catalysed reaction are to be stated.
Concept introduction:
When
(b)
Interpretation:
The expected products of the given acid catalysed reaction are to be stated.
Concept introduction:
When aldehydes or ketones react with a secondary amine, formation of enamine takes place. The nitrogen analog of an enol is known as enamine. From the resonating structures of enamine, it is clear that it nucleophilic in nature.
(c)
Interpretation:
The expected products of the given acid catalysed reaction are to be stated.
Concept introduction:
When aldehydes or ketones react with a primary amine, formation of a carbinolamine takes place. Then, dehydration takes place to give
(d)
Interpretation:
The expected products of the given acid catalysed reaction are to be stated.
Concept introduction:
When aldehydes or ketones react with a secondary amine, formation of enamine takes place. The nitrogen analog of an enol is known as enamine. From the resonating structures of enamine, it is clear that it nucleophilic in nature.
Want to see the full answer?
Check out a sample textbook solutionChapter 22 Solutions
Organic Chemistry (9th Edition)
- (a) How will you carry out the following conversions?(i) Acetylene to Acetic acid (ii) Toluene to m-nitrobenzoic acid(iii) Ethanol to Acetone(b) Give reasons :(i) Chloroacetic acid is stronger than acetic acid.(ii) pH of reaction should be carefully controlled while preparing ammonia derivatives of carbonyl compounds.arrow_forwardShow the product formed as a result of the reaction between propanoic acid and benzylalcohol in an acidic environment by writing down the reaction mechanism.arrow_forwardShow the product formed as a result of the reaction between propanoic acid and benzylalcohol in an acidic environment by writing the reaction mechanism together.arrow_forward
- 2) Another method for the above reaction starts with 4-aminophenol hydrochloride (the conjugate acid of 4-aminophenol). The treatment of this the hydrochloride salt with sodium ethanoate (acetate) buffer produces 4-aminophenol which is then able to react with ethanoic anhydride as per our method. i. Why is 4-aminophenol hydrochloride not suitable for direct reaction with ethanoic anhydride? ii. Draw a mechanism (i.e. curly arrows) showing the deprotonation of 4-aminophenol hydrochloride by sodium ethanoate to form 4-aminophenol (the free base).arrow_forward(a) Account for the following :(i) CH3CHO is more reactive than CH3COCH3 towards reaction with HCN.(ii) Carboxylic acid is a stronger acid than phenol.(b) Write the chemical equations to illustrate the following name reactions:(i) Wolff-Kishner reduction (ii) Aldol condensation (iii) Cannizzaro reactionarrow_forward1. i)Give the structure of the product from the reaction of propanal with 1M ethanol in dry acid . ( II)What happens when further 1M of ethanol is added to the abovearrow_forward
- (a) Write the reactions involved in the following:(i) Etard reaction (ii) Stephen reduction(b) How will you convert the following in not more than two steps:(i) Benzoic acid to Benzaldehyde (ii) Acetophenone to Benzoic acid(iii) Ethanoic acid to 2-Hydroxyethanoic acidarrow_forward(a) Describe the following giving chemical equations :(i) De-carboxylation reaction (ii) Friedel-Crafts reaction(b) How will you bring about the following conversions?(i) Benzoic acid to Benzaldehyde (ii) Benzene to m-Nitroacetophenone (iii) Ethanol to 3-Hydroxybutanalarrow_forwardExplain how you would test the relative reactivities of 1‐butanol vs. 2‐butanol in a nucleophilic substitution with sodium bromide.arrow_forward
- Propose a mechanism for the acid-catalyzed reaction of salicylic acid with aceticanhydride.(b) Explain why a single drop of sulfuric acid dramatically increases the reaction ratearrow_forwardWhich or which of the statements given below is correct. I) Maleic anhydride is a carboxylic acid derivative and its reaction with water is a reduction reaction. II) Fumaric acid and maleic acid are stereoisomers of each other III) Since fumaric acid has a more stable structure than maleic acid, its boiling point is higher. A. Solo I B. I and III C. II and III D. I, II, III E. Solo IIIarrow_forwardPrimary amines can also be prepared by the reaction of an alkyl halide with azide ion, followed by catalytic hydrogenation. What advantage do this method and the Gabriel synthesis have over the synthesis of a primaryamine using an alkyl halide and ammonia?arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage LearningOrganic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
- Macroscale and Microscale Organic ExperimentsChemistryISBN:9781305577190Author:Kenneth L. Williamson, Katherine M. MastersPublisher:Brooks Cole