Concept explainers
(a)
Interpretation:
The product of aldol condensation reaction followed by dehydration of butyraldehyde is to be predicted.
Concept introduction:
Aldol condensation is defined as a condensation reaction that involves the nucleophilic addition of an enolate ion to another carbonyl group to form a
(b)
Interpretation:
The product of aldol condensation reaction followed by dehydration of acetophenone is to be predicted.
Concept introduction:
Aldol condensation is defined as a condensation reaction that involves the nucleophilic addition of an enolate ion to another carbonyl group to form a
(c)
Interpretation:
The product of aldol condensation reaction followed by dehydration of cyclohexanone is to be predicted.
Concept introduction:
Aldol condensation is defined as a condensation reaction that involves the nucleophilic addition of an enolate ion to another carbonyl group to form a
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Chapter 22 Solutions
Organic Chemistry (9th Edition)
- Give the product of the aldol condensation.arrow_forwardPredict the products of aldol condensation, followed by dehydration, of the followingketones and aldehydes. c) cyclohexanonearrow_forwardPredict the products of aldol condensation, followed by dehydration, of the followingketones and aldehydes.(a) butyraldehydearrow_forward
- For the Aldol Experiment: What functional groups must be present in an enol? alkene ketone halide alcoholarrow_forwardComplete the aldol condensation reaction of cyclohexanone and ethylacetoacetate.arrow_forwardWhich statement describes why aldol reactions with ketones are low yielding? A.Ketones do not have acidic protons. B.Ketones are too electron poor at the carbonyl carbon. C.Ketones can attack other ketones well but perform poorly in self-condensations. D.The product of a ketone addition to a ketone has considerable steric strain.arrow_forward
- Draw structures for the carbonyl electrophile and enolate nucleophile.arrow_forwardWhat is the product of this Aldol addition reactionarrow_forwardDraw out the machanism for the aldol condensation of (2E,6E)-2,6-bis(4-ethylbenzylidene)cyclohexanone. (the reaction between cyclohexanone and 4-methoxybenzaldehyde)arrow_forward
- Draw the structure of the aldol that will form when cyclohexanone reacts with one mole ofbenzaldehyde. What is the name of this compound?arrow_forwardfor the theroretical yield is the mol correct? also using the aldol condensation reaction in this portion are we using the aldol condensation reaction to synthesize acetophenone and para-methybenzaldehye. acetophenone 0.5 g, 4.2 mmol Para-methylbenzaldehyde 0.5 g, 4.2 mmol NaOH=0.18g = 4.5 mol Theroretical yield=0.93g =0.0519 mol Percent yield=76.8% Actual yield= 0.715 g Melting point observered= 93 degree Celsius Expected melting point =93-94.5 degree Celsiusarrow_forwardIn the reaction of cyclopentene with HCl, hydrogen acts as the a. nucleophile. b. intermediate. c. electrophile. d. carbonium ion.arrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning