Alkyl groups are activating, so both of the trisubstituted benzenes shown undergo chlorination much faster than benzene. The 1, 2, 3-trisubstituted compound, however, undergoes chlorination faster than the 1, 2, 4-trisubstituted compound. The reason for it is to be explained. Concept introduction: The electron donating groups activates whereas the electron withdrawing groups deactivates the aromatic ring. The electron donating groups are ortho-para directing, which means electrophilic aromatic substitution preferably occurs at ortho-para position.

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Answer 1

Question

Chapter 23, Problem 23.45P

Interpretation Introduction

Interpretation:

Alkyl groups are activating, so both of the trisubstituted benzenes shown undergo chlorination much faster than benzene. The 1, 2, 3-trisubstituted compound, however, undergoes chlorination faster than the 1, 2, 4-trisubstituted compound. The reason for it is to be explained.

Concept introduction:

The electron donating groups activates whereas the electron withdrawing groups deactivates the aromatic ring. The electron donating groups are ortho-para directing, which means electrophilic aromatic substitution preferably occurs at ortho-para position.

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Answer 2

Question

Chapter 23, Problem 23.45P

Interpretation Introduction

Interpretation:

Alkyl groups are activating, so both of the trisubstituted benzenes shown undergo chlorination much faster than benzene. The 1, 2, 3-trisubstituted compound, however, undergoes chlorination faster than the 1, 2, 4-trisubstituted compound. The reason for it is to be explained.

Concept introduction:

The electron donating groups activates whereas the electron withdrawing groups deactivates the aromatic ring. The electron donating groups are ortho-para directing, which means electrophilic aromatic substitution preferably occurs at ortho-para position.

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Answer 3

Question

Chapter 23, Problem 23.45P

Interpretation Introduction

Interpretation:

Alkyl groups are activating, so both of the trisubstituted benzenes shown undergo chlorination much faster than benzene. The 1, 2, 3-trisubstituted compound, however, undergoes chlorination faster than the 1, 2, 4-trisubstituted compound. The reason for it is to be explained.

Concept introduction:

The electron donating groups activates whereas the electron withdrawing groups deactivates the aromatic ring. The electron donating groups are ortho-para directing, which means electrophilic aromatic substitution preferably occurs at ortho-para position.

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Answer 4

Question

Chapter 23, Problem 23.45P

Interpretation Introduction

Interpretation:

Alkyl groups are activating, so both of the trisubstituted benzenes shown undergo chlorination much faster than benzene. The 1, 2, 3-trisubstituted compound, however, undergoes chlorination faster than the 1, 2, 4-trisubstituted compound. The reason for it is to be explained.

Concept introduction:

The electron donating groups activates whereas the electron withdrawing groups deactivates the aromatic ring. The electron donating groups are ortho-para directing, which means electrophilic aromatic substitution preferably occurs at ortho-para position.

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Answer 5

Chapter 23, Problem 23.45P

Interpretation Introduction

Interpretation:

Alkyl groups are activating, so both of the trisubstituted benzenes shown undergo chlorination much faster than benzene. The 1, 2, 3-trisubstituted compound, however, undergoes chlorination faster than the 1, 2, 4-trisubstituted compound. The reason for it is to be explained.

Concept introduction:

The electron donating groups activates whereas the electron withdrawing groups deactivates the aromatic ring. The electron donating groups are ortho-para directing, which means electrophilic aromatic substitution preferably occurs at ortho-para position.

Answer 6

Chapter 23, Problem 23.45P

Interpretation Introduction

Interpretation:

Alkyl groups are activating, so both of the trisubstituted benzenes shown undergo chlorination much faster than benzene. The 1, 2, 3-trisubstituted compound, however, undergoes chlorination faster than the 1, 2, 4-trisubstituted compound. The reason for it is to be explained.

Concept introduction:

The electron donating groups activates whereas the electron withdrawing groups deactivates the aromatic ring. The electron donating groups are ortho-para directing, which means electrophilic aromatic substitution preferably occurs at ortho-para position.

Answer 7

Chapter 23, Problem 23.45P

Interpretation Introduction

Interpretation:

Alkyl groups are activating, so both of the trisubstituted benzenes shown undergo chlorination much faster than benzene. The 1, 2, 3-trisubstituted compound, however, undergoes chlorination faster than the 1, 2, 4-trisubstituted compound. The reason for it is to be explained.

Concept introduction:

The electron donating groups activates whereas the electron withdrawing groups deactivates the aromatic ring. The electron donating groups are ortho-para directing, which means electrophilic aromatic substitution preferably occurs at ortho-para position.

Answer 8

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Answer 9

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Answer 11

Ch. 23 - Prob. 23.1P Ch. 23 - Prob. 23.2P Ch. 23 - Prob. 23.3P Ch. 23 - Prob. 23.4P Ch. 23 - Prob. 23.5P Ch. 23 - Prob. 23.6P Ch. 23 - Prob. 23.7P Ch. 23 - Prob. 23.8P Ch. 23 - Prob. 23.9P Ch. 23 - Prob. 23.10P

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Chapter 23 Solutions