(a) Interpretation: The conformational representation of β -D- allopyranose is to be drawn. Concept introduction: The compounds which are composed of carbon, hydrogen, and oxygen possessing the general formula, C x ( H 2 O ) y are known as carbohydrates. The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has a six-membered ring is known as pyranose and sugar molecule that has a five-membered ring is known as furanose.

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Answer 1

Question

Chapter 24, Problem 24.12P

Interpretation Introduction

(a)

Interpretation:

The conformational representation of β-D- allopyranose is to be drawn.

Concept introduction:

The compounds which are composed of carbon, hydrogen, and oxygen possessing the general formula, Cx(H2O)y are known as carbohydrates. The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has a six-membered ring is known as pyranose and sugar molecule that has a five-membered ring is known as furanose.

Interpretation Introduction

(b)

Interpretation:

The conformational representation of α-D- idofuranose is to be drawn.

Concept introduction:

The compounds which are composed of carbon, hydrogen, and oxygen possessing the general formula, Cx(H2O)y are known as carbohydrates. The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has a six-membered ring is known as pyranose and sugar molecule that has a five-membered ring is known as furanose.

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How many chiral centers are in B-d-glucopyranose and a-D-galactopyranose? How many stereoisomers of these two aldohexoses can theoretically be drawn?

A What of the following is true about the cyclic structure of scheme A? (a) Pyranose ring ; b) Furanose ring ; c) Alpha anomeric configuration ; d) a and c ; e) b and c

Without referring to the chapter, draw the chair conformations of(a) b-d-mannopyranose (the C2 epimer of glucose).

Answer 2

Question

Chapter 24, Problem 24.12P

Interpretation Introduction

(a)

Interpretation:

The conformational representation of β-D- allopyranose is to be drawn.

Concept introduction:

The compounds which are composed of carbon, hydrogen, and oxygen possessing the general formula, Cx(H2O)y are known as carbohydrates. The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has a six-membered ring is known as pyranose and sugar molecule that has a five-membered ring is known as furanose.

Interpretation Introduction

(b)

Interpretation:

The conformational representation of α-D- idofuranose is to be drawn.

Concept introduction:

The compounds which are composed of carbon, hydrogen, and oxygen possessing the general formula, Cx(H2O)y are known as carbohydrates. The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has a six-membered ring is known as pyranose and sugar molecule that has a five-membered ring is known as furanose.

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Answer 3

Question

Chapter 24, Problem 24.12P

Interpretation Introduction

(a)

Interpretation:

The conformational representation of β-D- allopyranose is to be drawn.

Concept introduction:

The compounds which are composed of carbon, hydrogen, and oxygen possessing the general formula, Cx(H2O)y are known as carbohydrates. The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has a six-membered ring is known as pyranose and sugar molecule that has a five-membered ring is known as furanose.

Interpretation Introduction

(b)

Interpretation:

The conformational representation of α-D- idofuranose is to be drawn.

Concept introduction:

The compounds which are composed of carbon, hydrogen, and oxygen possessing the general formula, Cx(H2O)y are known as carbohydrates. The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has a six-membered ring is known as pyranose and sugar molecule that has a five-membered ring is known as furanose.

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Answer 4

Question

Chapter 24, Problem 24.12P

Interpretation Introduction

(a)

Interpretation:

The conformational representation of β-D- allopyranose is to be drawn.

Concept introduction:

The compounds which are composed of carbon, hydrogen, and oxygen possessing the general formula, Cx(H2O)y are known as carbohydrates. The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has a six-membered ring is known as pyranose and sugar molecule that has a five-membered ring is known as furanose.

Interpretation Introduction

(b)

Interpretation:

The conformational representation of α-D- idofuranose is to be drawn.

Concept introduction:

The compounds which are composed of carbon, hydrogen, and oxygen possessing the general formula, Cx(H2O)y are known as carbohydrates. The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has a six-membered ring is known as pyranose and sugar molecule that has a five-membered ring is known as furanose.

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Answer 5

Chapter 24, Problem 24.12P

Interpretation Introduction

(a)

Interpretation:

The conformational representation of β-D- allopyranose is to be drawn.

Concept introduction:

The compounds which are composed of carbon, hydrogen, and oxygen possessing the general formula, Cx(H2O)y are known as carbohydrates. The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has a six-membered ring is known as pyranose and sugar molecule that has a five-membered ring is known as furanose.

Interpretation Introduction

(b)

Interpretation:

The conformational representation of α-D- idofuranose is to be drawn.

Concept introduction:

The compounds which are composed of carbon, hydrogen, and oxygen possessing the general formula, Cx(H2O)y are known as carbohydrates. The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has a six-membered ring is known as pyranose and sugar molecule that has a five-membered ring is known as furanose.

Answer 6

Chapter 24, Problem 24.12P

Interpretation Introduction

(a)

Interpretation:

The conformational representation of β-D- allopyranose is to be drawn.

Concept introduction:

The compounds which are composed of carbon, hydrogen, and oxygen possessing the general formula, Cx(H2O)y are known as carbohydrates. The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has a six-membered ring is known as pyranose and sugar molecule that has a five-membered ring is known as furanose.

Answer 7

Chapter 24, Problem 24.12P

Interpretation Introduction

(a)

Interpretation:

The conformational representation of β-D- allopyranose is to be drawn.

Concept introduction:

The compounds which are composed of carbon, hydrogen, and oxygen possessing the general formula, Cx(H2O)y are known as carbohydrates. The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has a six-membered ring is known as pyranose and sugar molecule that has a five-membered ring is known as furanose.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The conformational representation of α-D- idofuranose is to be drawn.

Concept introduction:

The compounds which are composed of carbon, hydrogen, and oxygen possessing the general formula, Cx(H2O)y are known as carbohydrates. The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has a six-membered ring is known as pyranose and sugar molecule that has a five-membered ring is known as furanose.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The conformational representation of α-D- idofuranose is to be drawn.

Concept introduction:

The compounds which are composed of carbon, hydrogen, and oxygen possessing the general formula, Cx(H2O)y are known as carbohydrates. The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has a six-membered ring is known as pyranose and sugar molecule that has a five-membered ring is known as furanose.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 24 - Prob. 24.1P Ch. 24 - Prob. 24.2P Ch. 24 - Prob. 24.3P Ch. 24 - Prob. 24.4P Ch. 24 - Prob. 24.5P Ch. 24 - Prob. 24.6P Ch. 24 - Prob. 24.7P Ch. 24 - Prob. 24.8P Ch. 24 - Prob. 24.9P Ch. 24 - Prob. 24.10P

Solution Summary: The author explains that the conformational representation of beta-D- allopyranose is shown in Figure 3.

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Chapter 24 Solutions