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(a)
Interpretation:
A sequence of reactions used in the conversion of
Concept introduction:
Carbohydrates are a class of organic compounds. They can be present in the form of open chains or ringsThey are usually an
The six-membered ring form of carbohydrates is termed as pyranose. The five-membered ring form of carbohydrates is termed as furanose.
The pyranoses can be classified as
(b)
Interpretation:
A sequence of reactions used in the conversion of D-glucopyranose to
Concept introduction:
Carbohydrates are a class of organic compounds. They can be present in the form of open chains or rings.
They are usually an aldehyde or ketone with additional hydroxyl groups. They have the general molecular formula,
The 6 membered ring form of carbohydrates is termed as pyranose. This ring contains 5 carbon atoms and 1 an oxygen atom.
The pyranoses can be classified as
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Chapter 24 Solutions
EBK ORGANIC CHEMISTRY
- Draw the structural formulas of the following compounds:(a) 2,4-Dinitroacetophenone(b) 2,4-Dihydroxycyclopentanone(c) 2-Methoxy-2-methylpropane(d) 2,3,4-Trimethylpentan-3-olarrow_forwardPredict the products obtained from the reaction of triolein with the following reagents.(a) NaOH in water (b) H2 and a nickel catalystarrow_forwardWhat is the product of the starting material D-glyceraldehyde which will (1) produce aldaric acid upon reacting with HNO3 + H2O, NaOCH2, NH2OH, and (CH3CO)2O + NaOCOCH3 (2) produce tartaric acid upon reacting with HNO3 + H2O, NaOCH3, NH2OH, and (CH3CO)2O + NaOCOCH3arrow_forward
- Use a sheet of paper to answer the following question. Take a picture of your answers and attach to this assignment. From what aldehyde or ketone could each of the following be prepared by reduction with NaBH4 or LiAlH4? OH (a) OH (b) OH I (c) OHarrow_forwardDraw line structures of the following compounds and the product you would obtain from the reduction of each.(a) Isopropyl methyl ketone (b) p-Hydroxybenzaldehyde(c) 2-Methylcyclopentanonearrow_forward(a) Explain how NaBH4 in CH3OH can reduce hemiacetal A to butane-1,4-diol (HOCH2CH2CH2CH2OH). (b) What product is formed when A is treated with Ph3P = CHCH2CH(CH3)2? (c) The drug isotretinoin is formed by reaction of X and Y. What is the structure of isotretinoin? Although isotretinoin (trade name Accutane or Roaccutane) is used for the treatment of severe acne, it is dispensed under strict controls because it also causes birth defects.arrow_forward
- Quinapril (trade name Accupril) is used to treat high blood pressure and congestive heart failure. One step in the synthesis of quinapril involves reaction of the racemic alkyl bromide A with a single enantiomer of the amino ester B. (a) What two products are formed in this reaction? (b) Given the structure of quinapril, which one of these two products is needed to synthesize the drug?arrow_forwardQuinapril (trade name Accupril) is used to treat high blood pressure and congestive heart failure. One step in the synthesis of quinapril involves reaction of the racemic alkyl bromide A with a single enantiomer of the amino ester B. (a) What two products are formed in this reaction? (b) Given the structure of quinapril, which one of these two products is needed tosynthesize the drug?arrow_forwardDraw the structure of each of the following molecules. (a) 5-phenylpentanamide; (b) (2S,3S)-2,3-dimethoxyhexanediamide; (c) N-phenylcyclobutanecarboxamidearrow_forward
- Predict the products of self-condensation of the following esters.(a) methyl propanoate + NaOCH3 (b) ethyl phenylacetate + NaOCH2CH3arrow_forward1. Draw structures for the following: (a) N,N-dimethylpentanamide (b) Acetamide(c) 2,3-dimethylpentanamide (d) N-ethylbenzamidearrow_forwardGiven that C6H11COOH has a pKa = 4.8 and C6H11N+H3 has a pKa = 10.7, (a) What pH would you make the water layer to cause the carboxylic acid to dissolve in the water layer and the amine to dissolve in the ether layer? (b) What pH would you make the water layer to cause the carboxylic acid to dissolve in the ether layer and the amine to dissolve in the water layer?arrow_forward
- Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage LearningIntroduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage LearningOrganic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
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