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Concept explainers
(a)
Interpretation: The product formed on treatment of the given pair of compounds with
Concept introduction: Heck reaction is a type of coupling reaction in which a highly substituted
(b)
Interpretation:
The product formed on treatment of the given compound with
Concept introduction: Heck reaction is a type of coupling reaction in which a highly substituted alkene is formed in the presence of palladium nanomaterial based catalyst. The reaction is carried out in the presence of base like triethylamine.
(c)
Interpretation:
The product formed on treatment of the given compound with
Concept introduction: Heck reaction is a type of coupling reaction in which a highly substituted alkene is formed in the presence of palladium nanomaterial based catalyst. The reaction is carried out in the presence of base like triethylamine.
(d)
Interpretation:
The product formed on treatment of the given compound with
Concept introduction: Heck reaction is a type of coupling reaction in which a highly substituted alkene is formed in the presence of palladium nanomaterial based catalyst. The reaction is carried out in the presence of base like triethylamine.
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Chapter 26 Solutions
ORGANIC CHEMISTRY
- Draw the products formed when each amine is treated with [1] CH3I (excess); [2] Ag:0; [3] A. Indicate the major product when a mixture results. CH3 a. CH3(CH2)6NH2 d. C. NH2 CH3 NH2 H.arrow_forwardWhich molecule is hydrolyzed most slowly with aqueous NaOH? D. C. В. A.arrow_forwardDraw the product(s) formed when A is treated with each reagent.a. NaBH4, CH3OH b. LiAlH4, then H2O c. Ag2O, NH4OH d. CrO3, H2SO4, H2O e. PCCarrow_forward
- Draw the product formed when each compound is treated with two equivalents of CH;CH,CH,CHgMgBr followed by H,0. OCH3 a. b. C. CH;CH2 OCH2CH3arrow_forwardDraw the products formed when p-methylaniline (p-CH3C6H4NH2) istreated with following reagent. Part (b), then CH3COCl, AlCl3arrow_forwardWhat neutral nucleophile is needed to convert dihalide A to ticlopidine, an antiplatelet drug used to reduce the risk of strokes?arrow_forward
- What compound results when 2-pentanol is treated with HCl and ZnCl2? A. CH3CH2CH2CH2CH2CL B. CH3CH(Cl)CH2CH2CH3 C. CH3CH2CH2CH2CH2ZnCl D. CH3CH2CH2Ch2CO2Clarrow_forwardWhat product is formed when a solution of A and B is treated with mild base? This reaction is the rst step in the synthesis of rosuvastatin (sold as a calcium salt under the trade name Crestor), a drug used to treat patients with high cholesterol.arrow_forwardThe analgesic naproxen can be prepared by a stepwise reaction sequence from ester A. Using enolate alkylation in one step, what reagents are needed to convert A to naproxen? Draw the structure of each intermediate. Explain why a racemic product is formed.arrow_forward
- 16.43 Draw the products of each reaction. a. b. d. HO C. H Lore L sob Br₂ FeBr3 e. NO₂ Br HNO3 H₂SO4 CI AICI 3 Cl₂ FeCl3 SO3 H₂SO4arrow_forwardDraw the product formed when (CH3CH₂CH₂CH₂)2CuLi is treated with 17.38 each compound. In some cases, no reaction occurs. a. b. & جن d. CI . OCH₂ .then H₂O then H₂Oarrow_forwardAnswer the following questions about benzphetamine, a habit-forming diet pill sold under the trade name Didrex. a. Label the stereogenic center(s). b. What amide(s) can be reduced to form benzphetamine? c. What carbonyl compound and amine can be used to make benzphetamine by reductive amination? Draw all possible methods. d. What products are formed by Hofmann elimination from benzphetamine? Label the major product. benzphetaminearrow_forward
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