Principles of Instrumental Analysis
Principles of Instrumental Analysis
7th Edition
ISBN: 9781305577213
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cengage Learning
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Chapter 32, Problem 32.20QAP
Interpretation Introduction

(a)

Interpretation:

The 100% 55Mn manganese is found naturally. The cross section of the nuclide which has electron capture is 13.3×10-24cm2. The manganese 56Mn which is a beta and gamma emitter is the product of the neutron capture. The half time of beta and gamma emitter is 2.50h.It was considered that the irradiation of sample for 1h at neutron flux 1.8×1012 neutrons/(cm2s) results in the background counting rate of 10cpm. The minimum mass of manganese that could be detected is to be determined.

Concept introduction:

The value of minimum mass is calculated as follows:

A=NϕσS

Or,

N=AϕσS

Where,

A = activity

Ø = neutron flux

σ = cross-section area

S = saturation factor

The saturation factor is represented as follows:

S=1e0.693t/t1/2

Interpretation Introduction

(b)

Interpretation:

The reason for the calculated value is less than tabulated value is to be determined.

Concept introduction:

The calculated value is statistically determined on the basis of the data provided. The tabulated value is obtained by the processing of data which is present in the formed table.

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