Essential University Physics
Essential University Physics
4th Edition
ISBN: 9780134988566
Author: Wolfson, Richard
Publisher: Pearson Education,
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Chapter 37, Problem 46P
To determine

The stability of salt under compression.

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(a) In an HCl molecule, take the Cl atom to be the isotope 35Cl. The equilibrium separation of the H and Cl atoms is 0.127 46 nm. The atomic mass of the H atom is 1.007 825 u and that of the 35Cl atom is 34.968 853 u. Calculate the longest wavelength in the rotational spectrum of this molecule. (b) What If? Repeat the calculation in part (a), but take the Cl atom to be the isotope 37Cl, which has atomic mass 36.965 903 u. The equilibrium separation distance is the same as in part (a). (c) Naturally occurring chlorine contains approximately three parts of 35Cl to one part of 37Cl. Because of the two different Cl masses, each line in the microwave rotational spectrum of HCl is split into a doublet as shown. Calculate the separation in wavelength between the doublet lines for the longest wavelength.
However, the molecule we can encounter everyday continuously vibrates and interact with the surrounding causing its bond vector to vary slightly. According to a new spectroscopy analysis, the adjacent bond vectors was found to be A = 0.82i + 0.99j + 0.84k B = 1.09i + -1.01j + -0.97k What is the angle (in degrees) between the bonds based on this new data?
A 1H 19F molecule, with a bond length of 91.68 pm, absorbed on the surface and rotates in twodimensions. A) What is the smallest quantum energy that can be absorbed by this molecule in afirst rotational excitation?B) Calculate the zero-point energy for this molecule

Chapter 37 Solutions

Essential University Physics

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