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Organic And Biological Chemistry

7th Edition
STOKER + 1 other
ISBN: 9781305081079

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Section
BuyFindarrow_forward

Organic And Biological Chemistry

7th Edition
STOKER + 1 other
ISBN: 9781305081079
Textbook Problem

Draw the structure of the aldehyde or ketone formed from oxidation of each of the following alcohols. Assume that reaction conditions are sufficiently mild that any aldehydes formed are not oxidized further to carboxylic acids.

Chapter 4, Problem 4.72EP, Draw the structure of the aldehyde or ketone formed from oxidation of each of the following , example  1

Chapter 4, Problem 4.72EP, Draw the structure of the aldehyde or ketone formed from oxidation of each of the following , example  2

Chapter 4, Problem 4.72EP, Draw the structure of the aldehyde or ketone formed from oxidation of each of the following , example  3

Chapter 4, Problem 4.72EP, Draw the structure of the aldehyde or ketone formed from oxidation of each of the following , example  4

(a)

Interpretation Introduction

Interpretation:

The structure of aldehyde or ketone that is formed from the given alcohol has to be drawn.

Concept Introduction:

Carbonyl compounds such as aldehydes and ketones can be synthesized by oxidation or reduction reaction.  When a primary alcohol undergoes oxidation reaction, the product obtained is carboxylic acid that is formed through the intermediate aldehyde.  When mild oxidizing agent is used, aldehyde can be obtained as product from primary alcohol.  When a secondary alcohol undergoes oxidation reaction, the product obtained is a ketone.  This cannot be further oxidized.  Tertiary alcohols do not undergo oxidation reaction.  Some of the mild oxidizing agents used are KMnO4 or K2Cr2O7.

Explanation

Given alcohol is,

The given alcohol is found to be primary alcohol.  This on mild oxidation gives aldehyde as the product...

(b)

Interpretation Introduction

Interpretation:

The structure of aldehyde or ketone that is formed from the given alcohol has to be drawn.

Concept Introduction:

Carbonyl compounds such as aldehydes and ketones can be synthesized by oxidation or reduction reaction.  When a primary alcohol undergoes oxidation reaction, the product obtained is carboxylic acid that is formed through the intermediate aldehyde.  When mild oxidizing agent is used, aldehyde can be obtained as product from primary alcohol.  When a secondary alcohol undergoes oxidation reaction, the product obtained is a ketone.  This cannot be further oxidized.  Tertiary alcohols do not undergo oxidation reaction.  Some of the mild oxidizing agents used are KMnO4 or K2Cr2O7.

(c)

Interpretation Introduction

Interpretation:

The structure of aldehyde or ketone that is formed from the given alcohol has to be drawn.

Concept Introduction:

Carbonyl compounds such as aldehydes and ketones can be synthesized by oxidation or reduction reaction.  When a primary alcohol undergoes oxidation reaction, the product obtained is carboxylic acid that is formed through the intermediate aldehyde.  When mild oxidizing agent is used, aldehyde can be obtained as product from primary alcohol.  When a secondary alcohol undergoes oxidation reaction, the product obtained is a ketone.  This cannot be further oxidized.  Tertiary alcohols do not undergo oxidation reaction.  Some of the mild oxidizing agents used are KMnO4 or K2Cr2O7.

(d)

Interpretation Introduction

Interpretation:

The structure of aldehyde or ketone that is formed from the given alcohol has to be drawn.

Concept Introduction:

Carbonyl compounds such as aldehydes and ketones can be synthesized by oxidation or reduction reaction.  When a primary alcohol undergoes oxidation reaction, the product obtained is carboxylic acid that is formed through the intermediate aldehyde.  When mild oxidizing agent is used, aldehyde can be obtained as product from primary alcohol.  When a secondary alcohol undergoes oxidation reaction, the product obtained is a ketone.  This cannot be further oxidized.  Tertiary alcohols do not undergo oxidation reaction.  Some of the mild oxidizing agents used are KMnO4 or K2Cr2O7.

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Sect-4.4 P-3QQSect-4.4 P-4QQSect-4.4 P-5QQSect-4.5 P-1QQSect-4.5 P-2QQSect-4.5 P-3QQSect-4.5 P-4QQSect-4.5 P-5QQSect-4.6 P-1QQSect-4.6 P-2QQSect-4.6 P-3QQSect-4.7 P-1QQSect-4.7 P-2QQSect-4.8 P-1QQSect-4.8 P-2QQSect-4.9 P-1QQSect-4.9 P-2QQSect-4.10 P-1QQSect-4.10 P-2QQSect-4.10 P-3QQSect-4.10 P-4QQSect-4.11 P-1QQSect-4.11 P-2QQSect-4.11 P-3QQSect-4.11 P-4QQSect-4.11 P-5QQSect-4.12 P-1QQSect-4.12 P-2QQCh-4 P-4.1EPCh-4 P-4.2EPCh-4 P-4.3EPCh-4 P-4.4EPCh-4 P-4.5EPCh-4 P-4.6EPCh-4 P-4.7EPCh-4 P-4.8EPCh-4 P-4.9EPCh-4 P-4.10EPCh-4 P-4.11EPCh-4 P-4.12EPCh-4 P-4.13EPCh-4 P-4.14EPCh-4 P-4.15EPCh-4 P-4.16EPCh-4 P-4.17EPCh-4 P-4.18EPCh-4 P-4.19EPCh-4 P-4.20EPCh-4 P-4.21EPCh-4 P-4.22EPCh-4 P-4.23EPCh-4 P-4.24EPCh-4 P-4.25EPCh-4 P-4.26EPCh-4 P-4.27EPCh-4 P-4.28EPCh-4 P-4.29EPCh-4 P-4.30EPCh-4 P-4.31EPCh-4 P-4.32EPCh-4 P-4.33EPCh-4 P-4.34EPCh-4 P-4.35EPCh-4 P-4.36EPCh-4 P-4.37EPCh-4 P-4.38EPCh-4 P-4.39EPCh-4 P-4.40EPCh-4 P-4.41EPCh-4 P-4.42EPCh-4 P-4.43EPCh-4 P-4.44EPCh-4 P-4.45EPCh-4 P-4.46EPCh-4 P-4.47EPCh-4 P-4.48EPCh-4 P-4.49EPCh-4 P-4.50EPCh-4 P-4.51EPCh-4 P-4.52EPCh-4 P-4.53EPCh-4 P-4.54EPCh-4 P-4.55EPCh-4 P-4.56EPCh-4 P-4.57EPCh-4 P-4.58EPCh-4 P-4.59EPCh-4 P-4.60EPCh-4 P-4.61EPCh-4 P-4.62EPCh-4 P-4.63EPCh-4 P-4.64EPCh-4 P-4.65EPCh-4 P-4.66EPCh-4 P-4.67EPCh-4 P-4.68EPCh-4 P-4.69EPCh-4 P-4.70EPCh-4 P-4.71EPCh-4 P-4.72EPCh-4 P-4.73EPCh-4 P-4.74EPCh-4 P-4.75EPCh-4 P-4.76EPCh-4 P-4.77EPCh-4 P-4.78EPCh-4 P-4.79EPCh-4 P-4.80EPCh-4 P-4.81EPCh-4 P-4.82EPCh-4 P-4.83EPCh-4 P-4.84EPCh-4 P-4.85EPCh-4 P-4.86EPCh-4 P-4.87EPCh-4 P-4.88EPCh-4 P-4.89EPCh-4 P-4.90EPCh-4 P-4.91EPCh-4 P-4.92EPCh-4 P-4.93EPCh-4 P-4.94EPCh-4 P-4.95EPCh-4 P-4.96EPCh-4 P-4.97EPCh-4 P-4.98EPCh-4 P-4.99EPCh-4 P-4.100EPCh-4 P-4.101EPCh-4 P-4.102EPCh-4 P-4.103EPCh-4 P-4.104EPCh-4 P-4.105EPCh-4 P-4.106EPCh-4 P-4.107EPCh-4 P-4.108EPCh-4 P-4.109EPCh-4 P-4.110EPCh-4 P-4.111EPCh-4 P-4.112EPCh-4 P-4.113EPCh-4 P-4.114EPCh-4 P-4.115EPCh-4 P-4.116EPCh-4 P-4.117EPCh-4 P-4.118EP

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