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Organic And Biological Chemistry

7th Edition
STOKER + 1 other
ISBN: 9781305081079

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Chapter
Section
BuyFindarrow_forward

Organic And Biological Chemistry

7th Edition
STOKER + 1 other
ISBN: 9781305081079
Textbook Problem

Draw the structures of the thioesters formed as a result of each of the following reactions between carboxylic acids and thiols.

Chapter 5, Problem 5.136EP, Draw the structures of the thioesters formed as a result of each of the following reactions between , example  1

Chapter 5, Problem 5.136EP, Draw the structures of the thioesters formed as a result of each of the following reactions between , example  2

Chapter 5, Problem 5.136EP, Draw the structures of the thioesters formed as a result of each of the following reactions between , example  3

Chapter 5, Problem 5.136EP, Draw the structures of the thioesters formed as a result of each of the following reactions between , example  4

(a)

Interpretation Introduction

Interpretation:

The structure of thioester formed when reaction takes place between carboxylic acid given and the thiol given has to be drawn.

Concept Introduction:

Thioesters are prepared by condensation of carboxylic acid with a thiol.  A molecule of water is lost on this reaction.  The reaction that takes place in producing thioesters is known as thioesterification reaction.

Thioesterification reaction is the one in which the carboxylic acid is condensed with a thiol in presence of strong acid catalyst to produce thioester.  The general reaction scheme can be given as,

Organic And Biological Chemistry, Chapter 5, Problem 5.136EP , additional homework tip  1

Explanation

Thioesterification reaction is the one in which a carboxylic acid is condensed with a thiol to form thioester in presence of strong acid catalyst.  The general scheme for thioesterification can be given as,

Given carboxylic acid and thiol structure is,

(b)

Interpretation Introduction

Interpretation:

The structure of thioester formed when reaction takes place between carboxylic acid given and the thiol given has to be drawn.

Concept Introduction:

Thioesters are prepared by condensation of carboxylic acid with a thiol.  A molecule of water is lost on this reaction.  The reaction that takes place in producing thioesters is known as thioesterification reaction.

Thioesterification reaction is the one in which the carboxylic acid is condensed with a thiol in presence of strong acid catalyst to produce thioester.  The general reaction scheme can be given as,

Organic And Biological Chemistry, Chapter 5, Problem 5.136EP , additional homework tip  2

(c)

Interpretation Introduction

Interpretation:

The structure of thioester formed when reaction takes place between carboxylic acid given and the thiol given has to be drawn.

Concept Introduction:

Thioesters are prepared by condensation of carboxylic acid with a thiol.  A molecule of water is lost on this reaction.  The reaction that takes place in producing thioesters is known as thioesterification reaction.

Thioesterification reaction is the one in which the carboxylic acid is condensed with a thiol in presence of strong acid catalyst to produce thioester.  The general reaction scheme can be given as,

Organic And Biological Chemistry, Chapter 5, Problem 5.136EP , additional homework tip  3

(d)

Interpretation Introduction

Interpretation:

The structure of thioester formed when reaction takes place between carboxylic acid given and the thiol given has to be drawn.

Concept Introduction:

Thioesters are prepared by condensation of carboxylic acid with a thiol.  A molecule of water is lost on this reaction.  The reaction that takes place in producing thioesters is known as thioesterification reaction.

Thioesterification reaction is the one in which the carboxylic acid is condensed with a thiol in presence of strong acid catalyst to produce thioester.  The general reaction scheme can be given as,

Organic And Biological Chemistry, Chapter 5, Problem 5.136EP , additional homework tip  4

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