Foundations of Materials Science and Engineering
6th Edition
ISBN: 9781259696558
Author: SMITH
Publisher: MCG
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Chapter 5.7, Problem 23AAP
To determine
The depth below the surface.
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Rank the magnitudes of the diffusion coefficients from greatest to least for the following systems:
N in Fe at 700°C
Cr in Fe at 700°C
N in Fe at 900°C
Cr in Fe at 900°C
Now justify this ranking. (Note: Both Fe and Cr have the BCC crystal structure, and the atomic radii for Fe, Cr, and N are 0.124, 0.125, and 0.065 nm, respectively. You may also want to refer to Section 5.4.)
Diffusion of carbon into BCC iron for 12 hours at a temperature of 500 °C results in a carbon concentration of 0.2 wt% at a depth 2 mm from the surface. How long would it take to get a concentration of 0.2 wt% at a depth 3 mm from the surface at 500 °C?
why diffusion coefficients of carbon in BCC and FCC in iron at temperature 912 c are difference? explain ?
Chapter 5 Solutions
Foundations of Materials Science and Engineering
Ch. 5.7 - Prob. 1KCPCh. 5.7 - Write an equation for the number of vacancies...Ch. 5.7 - Prob. 3KCPCh. 5.7 - Prob. 4KCPCh. 5.7 - Describe the substitutional and interstitial...Ch. 5.7 - Prob. 6KCPCh. 5.7 - What factors affect the diffusion rate in solid...Ch. 5.7 - Write the equation for Ficks second law of...Ch. 5.7 - Prob. 9KCPCh. 5.7 - Prob. 10KCP
Ch. 5.7 - (a) Calculate the equilibrium concentration of...Ch. 5.7 - Prob. 12AAPCh. 5.7 - Determine the diffusion flux of zinc atoms in a...Ch. 5.7 - The diffusion flux of copper solute atoms in...Ch. 5.7 - Prob. 15AAPCh. 5.7 - Prob. 16AAPCh. 5.7 - Prob. 17AAPCh. 5.7 - A gear made of 1020 steel (0.20 wt% C) is to be...Ch. 5.7 - Prob. 19AAPCh. 5.7 - The surface of a steel gear made of 1020 steel...Ch. 5.7 - Prob. 21AAPCh. 5.7 - If boron is diffused into a thick slice of silicon...Ch. 5.7 - Prob. 23AAPCh. 5.7 - Prob. 24AAPCh. 5.7 - Prob. 25AAPCh. 5.7 - Prob. 26AAPCh. 5.7 - Prob. 27AAPCh. 5.7 - Prob. 28AAPCh. 5.7 - Prob. 29AAPCh. 5.7 - Prob. 30AAPCh. 5.7 - The diffusivity of copper atoms in the aluminum...Ch. 5.7 - Prob. 32AAPCh. 5.7 - Prob. 33SEPCh. 5.7 - Prob. 34SEPCh. 5.7 - Prob. 37SEPCh. 5.7 - Prob. 38SEPCh. 5.7 - The activation energy of nickel atoms in FCC iron...Ch. 5.7 - Prob. 40SEPCh. 5.7 - The self-diffusion of iron atoms in BCC iron is...Ch. 5.7 - Would you expect the diffusion rate of copper...Ch. 5.7 - Would you expect the diffusion rate of copper...Ch. 5.7 - Prob. 44SEPCh. 5.7 - Prob. 45SEPCh. 5.7 - Prob. 46SEPCh. 5.7 - Prob. 47SEPCh. 5.7 - Prob. 48SEPCh. 5.7 - Prob. 49SEPCh. 5.7 - Prob. 50SEP
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- Diffusion of carbon into the surface of BCC steel at 600oC for 10 hours results in a carbon concentration of 0.2wt% at a depth of 1.5 mm below the surface. At what depth will the same concentration be obtained if the diffusion time is increased to 20 hours, leaving the temperature at 600oarrow_forwardA 0.001 in. BCC iron foil is used to separate a high hydrogen gas from a low hydrogen gas at 650 °C. 5 ×108 H atoms/cm3 are in equilibrium on one side of the foil, and 2 × 103 H atoms/cm3 are in equilibrium on the other side. Determine (a) the concentration gradient of hydrogen; and (b) the flux of hydrogen through the foil.arrow_forwardThe activation energy for the diffusion of atomic species A in metal B is 118 kJ/mol. Calculate the diffusion coefficient at 840°C, given that the value of D at 1140°C is 6.1 × 10-11 m2/s.arrow_forward
- What does(do) determine a diffusion coefficient (diffusivity)? (choose all)a. Concentration gradientb. Diffusing species and host metalc. Geometryd. Temperaturearrow_forwardA flat plug 30 mm thick having an area of 6×10-3 m2 is used to close an opening in a container. The gas O2 at 25 oC and 2 atm pressure is stored inside the container. Assume that the outside partial pressure of O2 is zero and the solubility of O2 is 0.9 m3 gas (at 0 oC and 1 atm) per m3 solid per atm pressure of O2 , and the diffusivity of O2 in the solid material is equal to 0.11×10-10 m2/s. i- Calculate the total leakage of O2 through the plug to the outside in kgmol/s at a steady state. ii- Using the information given in the Appendix (Table Q1), determine the most appropriate material to be used for constructing the plug; and state why?.arrow_forwardCalculate the value of the diffusion coefficient D (in m2/s) at 750°C for the diffusion of some species in a metal; assume that the values of D0 and Qd are 5.6 × 10-5 m2/s and 177 kJ/mol, respectively.arrow_forward
- 1. An FCC iron-carbon alloy initially containing 0.20 wt% C is carburized at an elevated temperature and in an atmosphere that gives a surface carbon concentration constant at 1.0 wt%. If after 49.5 h, the concentration of carbon is 0.35 wt% at a position 4.0 mm below the surface, determine the temperature at which the treatment was carried out. 2. Consider a metal single-crystal oriented such that the normal to the slip plane and the slip direction are at angles of 60° and 35°, respectively, with the tensile axis. If the critical resolved shear stress is 20.7 MPa, will an applied stress of 45 MPa cause the single crystal to yield? If not, what stress will be necessary?arrow_forwardCalculate w and ΔE when 1 mole of a liquid is vaporized at its boiling point (80.°C) and 1.00 atm pressure. ΔH for the vaporization of the liquid is 30.7 kJ/mol at 80.°C. Assume the volume of 1 mole of liquid is negligible as compared to the volume of 1 mole of gas at 80.°C and 1.00 atm.arrow_forwardYou are examining two materials with the same density. One has a BCC crystal structure, and one has a HCP crystal structure. Which do you expect will have more rapid diffusion?arrow_forward
- Calculate the diffusion coefficient for the interdiffusion of Zinc into Copper at 500 °C .arrow_forwardAn FCC iron-carbon alloy initially containing 0.20 wt% C is carburized at an elevated temperature and in an atmosphere that gives a surface carbon concentration constant at 1.0 wt%. If after 49.5 h, the concentration of carbon is 0.35 wt% at a position 4.0 mm below the surface, determine the temperature at which the treatment was carried out.arrow_forwardCompute diffusion coefficients for the interdiffusion of carbon in both (a) α-iron (BCC) and (b) γ-iron (FCC) at 1000˚C. Assume that D0 for the interdiffusion of carbon in α-iron and in γ-iron are 1.1 × 10-6 and 2.3 × 10-5 m2/s, respectively, and that Qd are 80 and 148 kJ/mol, respectively.arrow_forward
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