Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Chapter 9, Problem 9.72QE
Write all resonance structures of chlorobenzene, C6H5Cl, a molecule with the same cyclic structure as benzene. In all structures, keep the C–Cl bond as a single bond. Which resonance structures are the most important?
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Chapter 9 Solutions
Chemistry: Principles and Practice
Ch. 9 - Prob. 9.1QECh. 9 - Prob. 9.2QECh. 9 - Prob. 9.3QECh. 9 - What main factors control the magnitude of lattice...Ch. 9 - Prob. 9.5QECh. 9 - Prob. 9.6QECh. 9 - Prob. 9.7QECh. 9 - Prob. 9.8QECh. 9 - Prob. 9.9QECh. 9 - Prob. 9.10QE
Ch. 9 - Prob. 9.11QECh. 9 - Prob. 9.12QECh. 9 - Prob. 9.13QECh. 9 - Compare the trends in electronegativity and...Ch. 9 - Prob. 9.15QECh. 9 - Prob. 9.16QECh. 9 - Prob. 9.17QECh. 9 - What elements are most likely to form...Ch. 9 - Prob. 9.19QECh. 9 - Prob. 9.20QECh. 9 - Prob. 9.21QECh. 9 - Prob. 9.22QECh. 9 - Prob. 9.23QECh. 9 - Prob. 9.24QECh. 9 - Prob. 9.25QECh. 9 - Prob. 9.26QECh. 9 - Write the formulas of the ionic compounds that...Ch. 9 - Prob. 9.28QECh. 9 - Prob. 9.29QECh. 9 - Prob. 9.30QECh. 9 - Arrange the following series of compounds in order...Ch. 9 - Prob. 9.32QECh. 9 - Prob. 9.33QECh. 9 - Prob. 9.34QECh. 9 - Prob. 9.35QECh. 9 - Draw Lewis structures for the following species....Ch. 9 - Prob. 9.37QECh. 9 - Prob. 9.38QECh. 9 - Write the Lewis structure for the following...Ch. 9 - Prob. 9.40QECh. 9 - Prob. 9.41QECh. 9 - Draw a Lewis structure for each of the following...Ch. 9 - Write the Lewis structure for each compound, with...Ch. 9 - Prob. 9.44QECh. 9 - Prob. 9.45QECh. 9 - Write the Lewis structure for each species, with...Ch. 9 - Prob. 9.47QECh. 9 - Prob. 9.48QECh. 9 - Prob. 9.49QECh. 9 - Arrange the members of each of the following sets...Ch. 9 - Prob. 9.51QECh. 9 - Prob. 9.52QECh. 9 - Prob. 9.53QECh. 9 - For each pair of bonds, indicate the more polar...Ch. 9 - Which molecule has the most polar bond: N2, BrF,...Ch. 9 - Given the bonds C N, C H, C Br, and S O, (a)...Ch. 9 - Prob. 9.57QECh. 9 - Prob. 9.58QECh. 9 - Write the Lewis structures showing formal charge...Ch. 9 - Write the Lewis structures showing formal charge...Ch. 9 - Prob. 9.61QECh. 9 - The connectivity of HNO could be either HNO or...Ch. 9 - Prob. 9.63QECh. 9 - Prob. 9.64QECh. 9 - Write all possible resonance structures for the...Ch. 9 - Prob. 9.66QECh. 9 - Prob. 9.67QECh. 9 - Prob. 9.68QECh. 9 - Prob. 9.69QECh. 9 - Prob. 9.70QECh. 9 - Write all resonance structures of toluene,...Ch. 9 - Write all resonance structures of chlorobenzene,...Ch. 9 - Draw all resonance structures for...Ch. 9 - Prob. 9.74QECh. 9 - Prob. 9.75QECh. 9 - Prob. 9.76QECh. 9 - Write the Lewis structures for the following...Ch. 9 - Write the Lewis structures for the following...Ch. 9 - Prob. 9.79QECh. 9 - Prob. 9.80QECh. 9 - Prob. 9.81QECh. 9 - Prob. 9.82QECh. 9 - Write the Lewis structures of H2CNH and H3CNH2....Ch. 9 - Write the Lewis structures of HNNH and H2NNH2....Ch. 9 - Prob. 9.85QECh. 9 - Prob. 9.86QECh. 9 - Prob. 9.87QECh. 9 - Prob. 9.88QECh. 9 - Prob. 9.89QECh. 9 - Prob. 9.90QECh. 9 - Prob. 9.91QECh. 9 - Prob. 9.92QECh. 9 - Prob. 9.93QECh. 9 - Prob. 9.94QECh. 9 - Prob. 9.95QECh. 9 - Prob. 9.96QECh. 9 - Prob. 9.97QECh. 9 - Prob. 9.98QECh. 9 - The molecule nitrosyl chloride, NOCl, has a...Ch. 9 - Prob. 9.100QECh. 9 - Draw the Lewis structure of BrNO. Which is the...Ch. 9 - Prob. 9.102QECh. 9 - Calculate an approximate enthalpy change (Table...Ch. 9 - Prob. 9.104QECh. 9 - Prob. 9.105QECh. 9 - Prob. 9.106QECh. 9 - Prob. 9.107QE
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- Methylcyanoacrylate is the active ingredient in super glues. Its Lewis structure is In this molecule, which is the (a) weakest carbon-containing bond? (b) strongest carbon-containing bond? (c) most polar bond?arrow_forwardUsing the bond dissociation enthalpies in Table 8.8, estimate the enthalpy of combustion of gaseous methane, CH4, to give water vapor and carbon dioxide gas.arrow_forwardAspirin is made from salicylic acid, which has this Lewis structure: (a) Which is the longest carbon-carbon bond? (b) Which is the strongest carbon-oxygen bond? (c) Draw resonance structures for this molecule.arrow_forward
- Bond Enthalpy When atoms of the hypothetical element X are placed together, they rapidly undergo reaction to form the X2 molecule: X(g)+X(g)X2(g) a Would you predict that this reaction is exothermic or endothermic? Explain. b Is the bond enthalpy of X2 a positive or a negative quantity? Why? c Suppose H for the reaction is 500 kJ/mol. Estimate the bond enthalpy of the X2 molecule. d Another hypothetical molecular compound, Y2(g), has a bond enthalpy of 750 kJ/mol, and the molecular compound XY(g) has a bond enthalpy of 1500 kJ/mol. Using bond enthalpy information, calculate H for the following reaction. X2(g)+Y2(g)2XY(g) e Given the following information, as well as the information previously presented, predict whether or not the hypothetical ionic compound AX is likely to form. In this compound, A forms the A+ cation, and X forms the X anion. Be sure to justify your answer. Reaction: A(g)+12X2(g)AX(s)The first ionization energy of A(g) is 400 kJ/mol. The electron affinity of X(g) is 525 kJ/mol. The lattice energy of AX(s) is 100 kJ/mol. f If you predicted that no ionic compound would form from the reaction in Part e, what minimum amount of AX(s) lattice energy might lead to compound formation?arrow_forwardGiven the bonds C N, C H, C Br, and S O, (a) which atom in each is the more electronegative? (b) which of these bonds is the most polar?arrow_forwardThree resonance forms can be drawn for the molecule N2O. Which resonance form is likely to more closely resemble the structure of this molecule? (a) (b) (c)arrow_forward
- The equation for the combustion of gaseous methanol is 2 CH3OH(g) + 3 O2(g) 2 CO2(g) + 4 H2O(g) (a) Using the bond dissociation enthalpies in Table 8.8, estimate the enthalpy change for this reaction. What is the enthalpy of combustion of one mole of gaseous methanol? (b) Compare your answer in part (a) with the value of tHcalculated using enthalpies of formation data.arrow_forwardWrite the Lewis structure for nitrosyl fluoride, FNO. Using only a periodic table, identify (a) which is the longer bond. (b) which is the stronger bond. (c) which is the more polar bond.arrow_forwardDraw all resonance structures for methylisocyanate, CH3NCO, a toxic gas used in the manufacturing of pesticides. Which resonance structures are the most important?arrow_forward
- Draw a Lewis structure for each of the following molecules or ions. (a) CS2 (b) BF4 (c) HNO2 (where the bonding is in the order HONO) (d) OSCl2 (where S is the central atom)arrow_forwardNitrosyl azide, N4O, is a pale yellow solid first synthesized in 1993. Write the Lewis structure for nitrosyl azide.arrow_forward
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