(a) Interpretation: The structure of 5-phenylpentanamide is to be drawn. Concept introduction: The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’. If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

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Answer 1

Question

Chapter F, Problem F.19P

Interpretation Introduction

(a)

Interpretation:

The structure of 5-phenylpentanamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(b)

Interpretation:

The structure of (2S, 3S)-2, 3-dimethoxyhexanediamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(c)

Interpretation:

The structure of N-phenylcyclobutanecarboxamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

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Give detailed Solution...Draw the following organic compound

A chiral amine A having the R conguration undergoes Hofmann elimination to form an alkene B as the major product. B is oxidatively cleaved with ozone, followed by CH3SCH3, to form CH2 = O and CH3CH2CH2CHO. What are the structures of A and B?

( give clear handwritten answer )give effiecient synthesis route for following with detailed meechanism.

Answer 2

Question

Chapter F, Problem F.19P

Interpretation Introduction

(a)

Interpretation:

The structure of 5-phenylpentanamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(b)

Interpretation:

The structure of (2S, 3S)-2, 3-dimethoxyhexanediamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(c)

Interpretation:

The structure of N-phenylcyclobutanecarboxamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

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Answer 3

Question

Chapter F, Problem F.19P

Interpretation Introduction

(a)

Interpretation:

The structure of 5-phenylpentanamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(b)

Interpretation:

The structure of (2S, 3S)-2, 3-dimethoxyhexanediamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(c)

Interpretation:

The structure of N-phenylcyclobutanecarboxamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

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Answer 4

Question

Chapter F, Problem F.19P

Interpretation Introduction

(a)

Interpretation:

The structure of 5-phenylpentanamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(b)

Interpretation:

The structure of (2S, 3S)-2, 3-dimethoxyhexanediamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(c)

Interpretation:

The structure of N-phenylcyclobutanecarboxamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

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Answer 5

Chapter F, Problem F.19P

Interpretation Introduction

(a)

Interpretation:

The structure of 5-phenylpentanamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(b)

Interpretation:

The structure of (2S, 3S)-2, 3-dimethoxyhexanediamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(c)

Interpretation:

The structure of N-phenylcyclobutanecarboxamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Answer 6

Chapter F, Problem F.19P

Interpretation Introduction

(a)

Interpretation:

The structure of 5-phenylpentanamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Answer 7

Chapter F, Problem F.19P

Interpretation Introduction

(a)

Interpretation:

The structure of 5-phenylpentanamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of (2S, 3S)-2, 3-dimethoxyhexanediamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of (2S, 3S)-2, 3-dimethoxyhexanediamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure of N-phenylcyclobutanecarboxamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure of N-phenylcyclobutanecarboxamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. F - Prob. F.1P Ch. F - Prob. F.2P Ch. F - Prob. F.3P Ch. F - Prob. F.4P Ch. F - Prob. F.5P Ch. F - Prob. F.6P Ch. F - Prob. F.7P Ch. F - Prob. F.8P Ch. F - Prob. F.9P Ch. F - Prob. F.10P

Solution Summary: The structure of 5-phenylpentanamide is to be drawn on the basis of its IUPAC name.

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Chapter F Solutions