Principles of General, Organic, Biological Chemistry
Principles of General, Organic, Biological Chemistry
2nd Edition
ISBN: 9780073511191
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 10, Problem 10.67AP

a.

Interpretation Introduction

Interpretation:

The structures of two cycloalkanes that are constitutional isomers with molecular formula C7H14 have to be drawn.

Concept Introduction:

Isomers:

The organic compound contains same molecular formula and different arrangement of atoms is termed as isomers.  The isomers have different physical and chemical properties.

Constitutional Isomer:

Constitutional isomer has same molecular formula but they have different connectivity to each other. It is also known as structural isomers.

b.

Interpretation Introduction

Interpretation

The structure of ether and an alcohol that are constitutional isomers with molecular formula C5H12O have to be drawn.

Concept Introduction:

Refer part a.

c.

Interpretation Introduction

Interpretation:

The two constitutional isomers of molecular formula C3H7Cl have to be drawn.

Concept Introduction:

Refer part a.

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The melting points and boiling points of two isomeric alkanes are as follows: CH3(CH2)6CH3, mp = -57 °C and bp = 126 °C; (CH3)3CC(CH3)3, mp = 102 °C and bp = 106 °C. (a) Explain why one isomer has a lower melting point but higher boiling point. (b) Explain why there is a small difference in the boiling points of the two compounds, but a huge difference in their melting points.
The melting points and boiling points of two isomeric alkanes are asfollows: CH3(CH2)6CH3, mp = −57 °C and bp = 126 °C; (CH3)3CC(CH3)3,mp = 102 °C and bp = 106 °C. Explain why one isomer has a lower melting point but higher boiling point.
Name and draw structural formulas for all cycloalkanes with molecular formula C5H10. Include cis and trans isomers as well as constitutional isomers.

Chapter 10 Solutions

Principles of General, Organic, Biological Chemistry

Ch. 10.4 - Convert the ball-and-stick model of the local...Ch. 10.5 - How many hydrogen atoms are present in each...Ch. 10.5 - Prob. 10.13PCh. 10.5 - Prob. 10.14PCh. 10.5 - Prob. 10.15PCh. 10.5 - Prob. 10.16PCh. 10.6 - Give the IUPAC name for each compound.Ch. 10.6 - Prob. 10.18PCh. 10.6 - Prob. 10.19PCh. 10.6 - Prob. 10.20PCh. 10.7 - Prob. 10.21PCh. 10.7 - Prob. 10.22PCh. 10.9 - Answer the following questions about pentane...Ch. 10.9 - Prob. 10.24PCh. 10.9 - Prob. 10.25PCh. 10.10 - Prob. 10.26PCh. 10 - Prob. 10.27UKCCh. 10 - Prob. 10.28UKCCh. 10 - Prob. 10.29UKCCh. 10 - Prob. 10.30UKCCh. 10 - Prob. 10.31UKCCh. 10 - The largest known cycloalkane with a single ring...Ch. 10 - Draw three constitutional isomers having molecular...Ch. 10 - Draw four constitutional isomers having molecular...Ch. 10 - Answer the following questions about the alkane...Ch. 10 - Answer the questions in Problem 10.35 for the...Ch. 10 - Prob. 10.37UKCCh. 10 - Procaine (trade name Novocain) is a local...Ch. 10 - Prob. 10.39APCh. 10 - Prob. 10.40APCh. 10 - Complete each structure by filling in all Hs and...Ch. 10 - Prob. 10.42APCh. 10 - Prob. 10.43APCh. 10 - Prob. 10.44APCh. 10 - Prob. 10.45APCh. 10 - Prob. 10.46APCh. 10 - Convert each compound to a condensed structure.Ch. 10 - Prob. 10.48APCh. 10 - Prob. 10.49APCh. 10 - Prob. 10.50APCh. 10 - Prob. 10.51APCh. 10 - Prob. 10.52APCh. 10 - Albuterol (trade names: Proventil and Ventolin) is...Ch. 10 - Prob. 10.54APCh. 10 - Prob. 10.55APCh. 10 - Prob. 10.56APCh. 10 - Prob. 10.57APCh. 10 - Prob. 10.58APCh. 10 - Prob. 10.59APCh. 10 - Prob. 10.60APCh. 10 - Prob. 10.61APCh. 10 - Prob. 10.62APCh. 10 - Prob. 10.63APCh. 10 - Prob. 10.64APCh. 10 - Prob. 10.65APCh. 10 - Prob. 10.66APCh. 10 - Prob. 10.67APCh. 10 - Prob. 10.68APCh. 10 - Prob. 10.69APCh. 10 - Prob. 10.70APCh. 10 - Give the IUPAC name for each compound.Ch. 10 - Prob. 10.72APCh. 10 - Prob. 10.73APCh. 10 - Prob. 10.74APCh. 10 - Prob. 10.75APCh. 10 - Prob. 10.76APCh. 10 - Give the structure corresponding to each IUPAC...Ch. 10 - Prob. 10.78APCh. 10 - Prob. 10.79APCh. 10 - Each of the following IUPAC names is incorrect....Ch. 10 - Prob. 10.81APCh. 10 - Prob. 10.82APCh. 10 - Prob. 10.83APCh. 10 - Prob. 10.84APCh. 10 - Prob. 10.85APCh. 10 - Prob. 10.86APCh. 10 - Write a balanced equation for the incomplete...Ch. 10 - Prob. 10.88APCh. 10 - Prob. 10.89APCh. 10 - Prob. 10.90APCh. 10 - Prob. 10.91APCh. 10 - Prob. 10.92APCh. 10 - Answer the following questions for the cycloalkane...Ch. 10 - Prob. 10.94APCh. 10 - Prob. 10.95CPCh. 10 - Prob. 10.96CP
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