Product formed when below alcohol is oxidized in presence of K 2 Cr 2 O 7 has to be determined. Oxidation of alcohol: During oxidation of alcohol, the number of C-O bonds gets increased on product side and C-H bond gets decreased on reactant side. In the oxidation reaction, reaction takes place between carbon attached to hydrogen atom and carbon attached to OH group and finally C-O bond is formed leading to H 2 removal from the reactant. Oxidation of an alcohol gives different products depending upon the type of alcohols and reagents take part in a reaction. Oxidation of alcohols give carbonyl group in the product side. In a primary alcohol, among the two C-H bonds present, the first C-H bond gets oxidized into aldehyde group and then further it gets oxidized into carboxylic acid group. In case of the secondary alcohol, only the one C-H bond present is oxidized into ketones. For tertiary alcohol, there are no hydrogen atoms present and therefore, tertiary alcohols are not been able to be oxidized.

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Answer 1

Question

Chapter 12, Problem 12.66AP

a.

Interpretation Introduction

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Oxidation of alcohol:

During oxidation of alcohol, the number of C-O bonds gets increased on product side and C-H bond gets decreased on reactant side. In the oxidation reaction, reaction takes place between carbon attached to hydrogen atom and carbon attached to OH group and finally C-O bond is formed leading to H2 removal from the reactant. Oxidation of an alcohol gives different products depending upon the type of alcohols and reagents take part in a reaction. Oxidation of alcohols give carbonyl group in the product side. In a primary alcohol, among the two C-H bonds present, the first C-H bond gets oxidized into aldehyde group and then further it gets oxidized into carboxylic acid group. In case of the secondary alcohol, only the one C-H bond present is oxidized into ketones. For tertiary alcohol, there are no hydrogen atoms present and therefore, tertiary alcohols are not been able to be oxidized.

b.

Interpretation Introduction

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Concept introduction:

Refer to part ‘a.’.

c.

Interpretation Introduction

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Concept introduction:

Refer to part ‘a.’.

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Answer 2

Question

Chapter 12, Problem 12.66AP

a.

Interpretation Introduction

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Oxidation of alcohol:

During oxidation of alcohol, the number of C-O bonds gets increased on product side and C-H bond gets decreased on reactant side. In the oxidation reaction, reaction takes place between carbon attached to hydrogen atom and carbon attached to OH group and finally C-O bond is formed leading to H2 removal from the reactant. Oxidation of an alcohol gives different products depending upon the type of alcohols and reagents take part in a reaction. Oxidation of alcohols give carbonyl group in the product side. In a primary alcohol, among the two C-H bonds present, the first C-H bond gets oxidized into aldehyde group and then further it gets oxidized into carboxylic acid group. In case of the secondary alcohol, only the one C-H bond present is oxidized into ketones. For tertiary alcohol, there are no hydrogen atoms present and therefore, tertiary alcohols are not been able to be oxidized.

b.

Interpretation Introduction

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Concept introduction:

Refer to part ‘a.’.

c.

Interpretation Introduction

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Concept introduction:

Refer to part ‘a.’.

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Answer 3

Question

Chapter 12, Problem 12.66AP

a.

Interpretation Introduction

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Oxidation of alcohol:

During oxidation of alcohol, the number of C-O bonds gets increased on product side and C-H bond gets decreased on reactant side. In the oxidation reaction, reaction takes place between carbon attached to hydrogen atom and carbon attached to OH group and finally C-O bond is formed leading to H2 removal from the reactant. Oxidation of an alcohol gives different products depending upon the type of alcohols and reagents take part in a reaction. Oxidation of alcohols give carbonyl group in the product side. In a primary alcohol, among the two C-H bonds present, the first C-H bond gets oxidized into aldehyde group and then further it gets oxidized into carboxylic acid group. In case of the secondary alcohol, only the one C-H bond present is oxidized into ketones. For tertiary alcohol, there are no hydrogen atoms present and therefore, tertiary alcohols are not been able to be oxidized.

b.

Interpretation Introduction

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Concept introduction:

Refer to part ‘a.’.

c.

Interpretation Introduction

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Concept introduction:

Refer to part ‘a.’.

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Answer 4

Question

Chapter 12, Problem 12.66AP

a.

Interpretation Introduction

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Oxidation of alcohol:

During oxidation of alcohol, the number of C-O bonds gets increased on product side and C-H bond gets decreased on reactant side. In the oxidation reaction, reaction takes place between carbon attached to hydrogen atom and carbon attached to OH group and finally C-O bond is formed leading to H2 removal from the reactant. Oxidation of an alcohol gives different products depending upon the type of alcohols and reagents take part in a reaction. Oxidation of alcohols give carbonyl group in the product side. In a primary alcohol, among the two C-H bonds present, the first C-H bond gets oxidized into aldehyde group and then further it gets oxidized into carboxylic acid group. In case of the secondary alcohol, only the one C-H bond present is oxidized into ketones. For tertiary alcohol, there are no hydrogen atoms present and therefore, tertiary alcohols are not been able to be oxidized.

b.

Interpretation Introduction

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Concept introduction:

Refer to part ‘a.’.

c.

Interpretation Introduction

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Concept introduction:

Refer to part ‘a.’.

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Answer 5

Chapter 12, Problem 12.66AP

a.

Interpretation Introduction

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Oxidation of alcohol:

During oxidation of alcohol, the number of C-O bonds gets increased on product side and C-H bond gets decreased on reactant side. In the oxidation reaction, reaction takes place between carbon attached to hydrogen atom and carbon attached to OH group and finally C-O bond is formed leading to H2 removal from the reactant. Oxidation of an alcohol gives different products depending upon the type of alcohols and reagents take part in a reaction. Oxidation of alcohols give carbonyl group in the product side. In a primary alcohol, among the two C-H bonds present, the first C-H bond gets oxidized into aldehyde group and then further it gets oxidized into carboxylic acid group. In case of the secondary alcohol, only the one C-H bond present is oxidized into ketones. For tertiary alcohol, there are no hydrogen atoms present and therefore, tertiary alcohols are not been able to be oxidized.

b.

Interpretation Introduction

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Concept introduction:

Refer to part ‘a.’.

c.

Interpretation Introduction

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Concept introduction:

Refer to part ‘a.’.

Answer 6

Chapter 12, Problem 12.66AP

a.

Interpretation Introduction

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Oxidation of alcohol:

During oxidation of alcohol, the number of C-O bonds gets increased on product side and C-H bond gets decreased on reactant side. In the oxidation reaction, reaction takes place between carbon attached to hydrogen atom and carbon attached to OH group and finally C-O bond is formed leading to H2 removal from the reactant. Oxidation of an alcohol gives different products depending upon the type of alcohols and reagents take part in a reaction. Oxidation of alcohols give carbonyl group in the product side. In a primary alcohol, among the two C-H bonds present, the first C-H bond gets oxidized into aldehyde group and then further it gets oxidized into carboxylic acid group. In case of the secondary alcohol, only the one C-H bond present is oxidized into ketones. For tertiary alcohol, there are no hydrogen atoms present and therefore, tertiary alcohols are not been able to be oxidized.

Answer 7

Chapter 12, Problem 12.66AP

a.

Interpretation Introduction

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Oxidation of alcohol:

During oxidation of alcohol, the number of C-O bonds gets increased on product side and C-H bond gets decreased on reactant side. In the oxidation reaction, reaction takes place between carbon attached to hydrogen atom and carbon attached to OH group and finally C-O bond is formed leading to H2 removal from the reactant. Oxidation of an alcohol gives different products depending upon the type of alcohols and reagents take part in a reaction. Oxidation of alcohols give carbonyl group in the product side. In a primary alcohol, among the two C-H bonds present, the first C-H bond gets oxidized into aldehyde group and then further it gets oxidized into carboxylic acid group. In case of the secondary alcohol, only the one C-H bond present is oxidized into ketones. For tertiary alcohol, there are no hydrogen atoms present and therefore, tertiary alcohols are not been able to be oxidized.

Answer 8

b.

Interpretation Introduction

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Concept introduction:

Refer to part ‘a.’.

Answer 9

b.

Interpretation Introduction

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Concept introduction:

Refer to part ‘a.’.

Answer 10

c.

Interpretation Introduction

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Concept introduction:

Refer to part ‘a.’.

Answer 11

c.

Interpretation Introduction

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Concept introduction:

Refer to part ‘a.’.

Answer 12

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Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 12.1 - a. Label the hydroxyl groups, thiols, halogens,...Ch. 12.1 - Draw out each compound to clearly show what groups...Ch. 12.2 - Classify each alcohol as 1, 2, or 3.Ch. 12.2 - Classify each hydroxyl group in sorbitol as 1, 2,...Ch. 12.2 - Which compound in each pair has the higher boiling...Ch. 12.2 - Label each compound as water soluble or water...Ch. 12.2 - Give the IUPAC name for each compound.Ch. 12.2 - Give the structure corresponding to each name. a....Ch. 12.3 - Name each ether. a. CH3OCH2CH2CH2CH3 b....Ch. 12.3 - Prob. 12.10P

Solution Summary: The author explains that the product formed when below alcohol is oxidized in presence of K 2 Cr 2 O 7 has to be determined.

Concept explainers

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Concept introduction:

Refer to part ‘a.’.

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Concept introduction:

Refer to part ‘a.’.

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Chapter 12 Solutions

Solution Summary: The author explains that the product formed when below alcohol is oxidized in presence of K 2 Cr 2 O 7 has to be determined.

Concept explainers

Interpretation: Product formed when below alcohol is oxidized in presence of K2Cr2O7 has to be determined. Concept introduction: Refer to part ‘a.’.

Interpretation: Product formed when below alcohol is oxidized in presence of K2Cr2O7 has to be determined. Concept introduction: Refer to part ‘a.’.

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Chapter 12 Solutions

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Concept introduction:

Refer to part ‘a.’.

Interpretation:

Product formed when below alcohol is oxidized in presence of K₂Cr₂O₇ has to be determined.

Concept introduction:

Refer to part ‘a.’.