Concept explainers
(a)
Interpretation:
Synthesis of the given compound beginning with pentan-2-one is to be suggested.
Concept introduction:
The carbon–carbon bond-forming reaction results in heteroatoms having a specific relative positioning along the carbon backbone. If the heteroatoms in a target have 1, 2-, 1, 3-, 1, 4-, or 1, 5- relative positioning, and the synthesis calls for a carbon–carbon bond-forming reaction, then consider using a corresponding reaction from Table 19-1. In a retrosynthetic analysis, therefore, apply a transform that takes our target molecule back to reactants. Disconnect the appropriate C-C bond to take back to the reactants, and from retrosynthetic analysis, we can draw the synthesis of the target molecule.
(b)
Interpretation:
Synthesis of the given compound beginning with pentan-2-one is to be suggested.
Concept introduction:
The carbon–carbon bond-forming reaction results in heteroatoms having a specific relative positioning along the carbon backbone. If the heteroatoms in a target have 1, 2-, 1, 3-, 1, 4-, or 1, 5- relative positioning and the synthesis calls for a carbon–carbon bond-forming reaction, then consider using a corresponding reaction from Table 19-1. In a retrosynthetic analysis, therefore, apply a transform that takes our target molecule back to reactants. Disconnect the appropriate C-C bond to take back to reactants, and from the retrosynthetic analysis, we can draw the synthesis of the target molecule.
(c)
Interpretation:
Synthesis of the given compound beginning with pentan-2-one is to be suggested.
Concept introduction:
The carbon–carbon bond-forming reaction results in heteroatoms having a specific relative positioning along the carbon backbone. If the heteroatoms in a target have 1, 2-, 1, 3-, 1, 4-, or 1, 5- relative positioning and the synthesis calls for a carbon–carbon bond-forming reaction, then consider using a corresponding reaction from Table 19-1. In a retrosynthetic analysis, therefore, apply a transform that takes our target molecule back to reactants. Disconnect the appropriate C-C bond to take back to reactants. And from the retrosynthetic analysis we can draw the synthesis of the target molecule.
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ORGANIC CHEMISTRY E-BOOK W/SMARTWORK5
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- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning