Whether the Wolff-Kishner reduction and Clemmensen reduction should be carried out on a ketone or aldehyde that contains the nitrile group (R-C ≡ N ) is to be determined. Concept introduction: Nitrile (R-C ≡ N ) can be hydrolyzed to an amide under either acidic or basic condition. The Wolff-Kishner reduction is carried out in basic condition in water, and Clemmensen reduction is carried out in acidic condition in water.

Question

Want to see the full answer?

Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19, Problem 19.3YT

Interpretation Introduction

Interpretation:

Whether the Wolff-Kishner reduction and Clemmensen reduction should be carried out on a ketone or aldehyde that contains the nitrile group (R-C≡N) is to be determined.

Concept introduction:

Nitrile (R-C≡N) can be hydrolyzed to an amide under either acidic or basic condition.

The Wolff-Kishner reduction is carried out in basic condition in water, and Clemmensen reduction is carried out in acidic condition in water.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Select the appropriate reagent and TWO possible substrates for the following reductive amination.

What is the main reaction mechanism for this reductive amination?

What kinds of halides cannot be used to alkylate an amine? Why not? a.Tertiary halides form alkenes on elimination. b.Aryl halides unless activated by electron-withdrawing groups c.Halides with beta-alkyl groups are sterically hindered. d. all of the above

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19, Problem 19.3YT

Interpretation Introduction

Interpretation:

Whether the Wolff-Kishner reduction and Clemmensen reduction should be carried out on a ketone or aldehyde that contains the nitrile group (R-C≡N) is to be determined.

Concept introduction:

Nitrile (R-C≡N) can be hydrolyzed to an amide under either acidic or basic condition.

The Wolff-Kishner reduction is carried out in basic condition in water, and Clemmensen reduction is carried out in acidic condition in water.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19, Problem 19.3YT

Interpretation Introduction

Interpretation:

Whether the Wolff-Kishner reduction and Clemmensen reduction should be carried out on a ketone or aldehyde that contains the nitrile group (R-C≡N) is to be determined.

Concept introduction:

Nitrile (R-C≡N) can be hydrolyzed to an amide under either acidic or basic condition.

The Wolff-Kishner reduction is carried out in basic condition in water, and Clemmensen reduction is carried out in acidic condition in water.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19, Problem 19.3YT

Interpretation Introduction