EP ORGANIC CHEMISTRY -MOD.MASTERING 18W
EP ORGANIC CHEMISTRY -MOD.MASTERING 18W
9th Edition
ISBN: 9780136781776
Author: Wade
Publisher: PEARSON CO
Question
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Chapter 20.10, Problem 20.17P

(a)

Interpretation Introduction

Interpretation:

The resonance forms of intermediates formed in solved problem 201 and how these resonance forms describe the occurrence of reaction under very mild condition are to be stated.

Concept introduction:

The resonance form of a substance related to the stability of the product, the more number of resonance forms increase the stability of a substance. The non-conjugated substances do not possess resonance structures. The presence of an alternation single and double bonds in a compound is known as conjugation.

(b)

Interpretation Introduction

Interpretation:

The mechanism for the acid-catalysed hydrolysis of ethyl formate is to be shown.

Concept introduction:

The synthesis of the compound relies upon the type of reactants and reagents that are used during the reactions. The energy of the product should be low because low energy of a compound increases the stability of a compound. The stability of a compound is the major factor that is responsible for the formation of a compound. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.

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From the picture and description can you is that a correct mechanism . can you draw the mechanism ? Phosphate Ester (Minor Product): In the mechanism, a nucleophilic attack by the phosphate ion (�2��4−H2PO4−) substitutes the hydroxyl group in the protonated cyclohexanol. This is a minor product due to steric hindrance. The phosphate group is relatively large and bulky, making the substitution reaction less favored. The size of the substituent may lead to a slower reaction rate and decreased likelihood of successful substitution. Ether (Minor Product): In the mechanism, substitution involves another cyclohexanol molecule attacking the hydroxyl group in the protonated cyclohexanol. Steric hindrance and the availability of a more favorable elimination pathway (dehydration) contribute to the ether being a minor product. The proximity of two cyclohexanol molecules for substitution is hindered by steric factors, making elimination more favorable.
Write five different EAS reactions at the top of the page.
. One of these reactions occurs rapidly while the other is so slow that substitution products are not observed. Determine which reaction is which and explain the difference in rate using structural drawing and a few words. Br + 'Br +

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EP ORGANIC CHEMISTRY -MOD.MASTERING 18W

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