(a) Interpretation: Synthesis of the given compound beginning with melonic ester is to be shown. Concept introduction: A melonic ester synthesis results in an α- substituted carboxylic acid because it has two ester groups. Both ester groups are hydrolyzed to the carboxylic acid, but only one undergoes decarboxylation. Retro synthesis is undergone.

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Answer 1

Question

Chapter 21, Problem 21.70P

Interpretation Introduction

(a)

Interpretation:

Synthesis of the given compound beginning with melonic ester is to be shown.

Concept introduction:

A melonic ester synthesis results in an α- substituted carboxylic acid because it has two ester groups. Both ester groups are hydrolyzed to the carboxylic acid, but only one undergoes decarboxylation. Retro synthesis is undergone.

Interpretation Introduction

(b)

Interpretation:

Synthesis of the given compound beginning with melonic ester is to be shown.

Concept introduction:

A melonic ester synthesis results in an α- substituted carboxylic acid because it has two ester groups. Both ester groups are hydrolyzed to the carboxylic acid, but only one undergoes decarboxylation. Retro synthesis is undergone.

Interpretation Introduction

(c)

Interpretation:

Synthesis of the given compound beginning with melonic ester is to be shown.

Concept introduction:

A melonic ester synthesis results in an α- substituted carboxylic acid because it has two ester groups. Both ester groups are hydrolyzed to the carboxylic acid, but only one undergoes decarboxylation. Retro synthesis is undergone.

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Students have asked these similar questions

(SYN) Show how you would synthesize each of these compounds from benzene.

(SYN) Show how to synthesize each of the following compounds beginning with malonic ester.

(SYN) Show how to carry out each of the following syntheses by first converting the alcohol into a sulfonyl chloride.

Answer 2

Question

Chapter 21, Problem 21.70P

Interpretation Introduction

(a)

Interpretation:

Synthesis of the given compound beginning with melonic ester is to be shown.

Concept introduction:

A melonic ester synthesis results in an α- substituted carboxylic acid because it has two ester groups. Both ester groups are hydrolyzed to the carboxylic acid, but only one undergoes decarboxylation. Retro synthesis is undergone.

Interpretation Introduction

(b)

Interpretation:

Synthesis of the given compound beginning with melonic ester is to be shown.

Concept introduction:

A melonic ester synthesis results in an α- substituted carboxylic acid because it has two ester groups. Both ester groups are hydrolyzed to the carboxylic acid, but only one undergoes decarboxylation. Retro synthesis is undergone.

Interpretation Introduction

(c)

Interpretation:

Synthesis of the given compound beginning with melonic ester is to be shown.

Concept introduction:

A melonic ester synthesis results in an α- substituted carboxylic acid because it has two ester groups. Both ester groups are hydrolyzed to the carboxylic acid, but only one undergoes decarboxylation. Retro synthesis is undergone.

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Answer 3

Question

Chapter 21, Problem 21.70P

Interpretation Introduction

(a)

Interpretation:

Synthesis of the given compound beginning with melonic ester is to be shown.

Concept introduction:

A melonic ester synthesis results in an α- substituted carboxylic acid because it has two ester groups. Both ester groups are hydrolyzed to the carboxylic acid, but only one undergoes decarboxylation. Retro synthesis is undergone.

Interpretation Introduction

(b)

Interpretation:

Synthesis of the given compound beginning with melonic ester is to be shown.

Concept introduction:

A melonic ester synthesis results in an α- substituted carboxylic acid because it has two ester groups. Both ester groups are hydrolyzed to the carboxylic acid, but only one undergoes decarboxylation. Retro synthesis is undergone.

Interpretation Introduction

(c)

Interpretation:

Synthesis of the given compound beginning with melonic ester is to be shown.

Concept introduction:

A melonic ester synthesis results in an α- substituted carboxylic acid because it has two ester groups. Both ester groups are hydrolyzed to the carboxylic acid, but only one undergoes decarboxylation. Retro synthesis is undergone.

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Answer 4

Question

Chapter 21, Problem 21.70P

Interpretation Introduction

(a)

Interpretation:

Synthesis of the given compound beginning with melonic ester is to be shown.

Concept introduction:

A melonic ester synthesis results in an α- substituted carboxylic acid because it has two ester groups. Both ester groups are hydrolyzed to the carboxylic acid, but only one undergoes decarboxylation. Retro synthesis is undergone.

Interpretation Introduction

(b)

Interpretation:

Synthesis of the given compound beginning with melonic ester is to be shown.

Concept introduction:

A melonic ester synthesis results in an α- substituted carboxylic acid because it has two ester groups. Both ester groups are hydrolyzed to the carboxylic acid, but only one undergoes decarboxylation. Retro synthesis is undergone.

Interpretation Introduction

(c)

Interpretation:

Synthesis of the given compound beginning with melonic ester is to be shown.

Concept introduction:

A melonic ester synthesis results in an α- substituted carboxylic acid because it has two ester groups. Both ester groups are hydrolyzed to the carboxylic acid, but only one undergoes decarboxylation. Retro synthesis is undergone.

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Answer 5

Chapter 21, Problem 21.70P

Interpretation Introduction

(a)

Interpretation:

Synthesis of the given compound beginning with melonic ester is to be shown.

Concept introduction:

A melonic ester synthesis results in an α- substituted carboxylic acid because it has two ester groups. Both ester groups are hydrolyzed to the carboxylic acid, but only one undergoes decarboxylation. Retro synthesis is undergone.

Interpretation Introduction

(b)

Interpretation:

Synthesis of the given compound beginning with melonic ester is to be shown.

Concept introduction:

A melonic ester synthesis results in an α- substituted carboxylic acid because it has two ester groups. Both ester groups are hydrolyzed to the carboxylic acid, but only one undergoes decarboxylation. Retro synthesis is undergone.

Interpretation Introduction

(c)

Interpretation:

Synthesis of the given compound beginning with melonic ester is to be shown.

Concept introduction:

A melonic ester synthesis results in an α- substituted carboxylic acid because it has two ester groups. Both ester groups are hydrolyzed to the carboxylic acid, but only one undergoes decarboxylation. Retro synthesis is undergone.

Answer 6

Chapter 21, Problem 21.70P

Interpretation Introduction

(a)

Interpretation:

Synthesis of the given compound beginning with melonic ester is to be shown.

Concept introduction:

A melonic ester synthesis results in an α- substituted carboxylic acid because it has two ester groups. Both ester groups are hydrolyzed to the carboxylic acid, but only one undergoes decarboxylation. Retro synthesis is undergone.

Answer 7

Chapter 21, Problem 21.70P

Interpretation Introduction

(a)

Interpretation:

Synthesis of the given compound beginning with melonic ester is to be shown.

Concept introduction:

A melonic ester synthesis results in an α- substituted carboxylic acid because it has two ester groups. Both ester groups are hydrolyzed to the carboxylic acid, but only one undergoes decarboxylation. Retro synthesis is undergone.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Synthesis of the given compound beginning with melonic ester is to be shown.

Concept introduction:

A melonic ester synthesis results in an α- substituted carboxylic acid because it has two ester groups. Both ester groups are hydrolyzed to the carboxylic acid, but only one undergoes decarboxylation. Retro synthesis is undergone.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Synthesis of the given compound beginning with melonic ester is to be shown.

Concept introduction:

A melonic ester synthesis results in an α- substituted carboxylic acid because it has two ester groups. Both ester groups are hydrolyzed to the carboxylic acid, but only one undergoes decarboxylation. Retro synthesis is undergone.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Synthesis of the given compound beginning with melonic ester is to be shown.

Concept introduction:

A melonic ester synthesis results in an α- substituted carboxylic acid because it has two ester groups. Both ester groups are hydrolyzed to the carboxylic acid, but only one undergoes decarboxylation. Retro synthesis is undergone.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Synthesis of the given compound beginning with melonic ester is to be shown.

Concept introduction:

A melonic ester synthesis results in an α- substituted carboxylic acid because it has two ester groups. Both ester groups are hydrolyzed to the carboxylic acid, but only one undergoes decarboxylation. Retro synthesis is undergone.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2P Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4P Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6P Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8P Ch. 21 - Prob. 21.9P Ch. 21 - Prob. 21.10P

Solution Summary: The author explains that a melonic ester synthesis results in an - substituted carboxylic acid.

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