Concept explainers
(a)
Interpretation:
The curved arrow mechanism for the formation of acetone and
Concept introduction:
In Aldol condensation reaction, the base abstracts an acidic proton from the
(b)
Interpretation:
The curved arrow mechanism for the given reaction is to be stated.
Concept introduction:
In Aldol condensation reaction, the base abstracts an acidic proton from the
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EBK ORGANIC CHEMISTRY
- What reactant can be used to make this compound by an intramolecular aldol reaction? (A) (B) (C) (D) لسل Harrow_forward(a) 11. (b) What is the major product of the elimiation below? |||-- EtONa EtOH (C) (d)arrow_forwardShow how the following ketones might be synthesized from the indicated acids, usingany necessary reagents.(b) methyl cyclohexyl ketone from cyclohexanecarboxylic acidarrow_forward
- Reaction benzaldehyde with (CH3CN) in presence of base called ? (a) Dopner reaction (b)Crossed Claisen condensation (C) Cope reaction (d) Aldol condensation 10:00 PMarrow_forwardWhich of the following compounds would you expect to undergo aldol self-condensation? Show the product of each successful reaction. (a) Trimethyl acetaldehyde (d) 3-Pentanone(b ) Cyclobutanone (e) Decanal(c) Benzophenone (diphenyl ketone) (f) 3-Phenyl-2-propenalarrow_forward(iv) The intramolecular aldol reaction of Z and subsequent dehydration gives a,ß-unsaturated ketone AA. Draw the structure of AA and provide detailed reaction mechanisms for the transformation. N NaOH EtOH AAarrow_forward
- Show how you would synthesize octanal from each compound. You may use any necessary reagents.(a) octan-1-olarrow_forwardShow how you would synthesize octan-2-one from each compound. You may use any necessary reagents.(a) heptanalarrow_forwardExplain the mechanism of the following reactions :(i) Addition of Grignard’s reagent to the carbonyl group of a compound forming an adduct followed by hydrolysis.(ii) Acid catalysed dehydration of an alcohol forming an alkene.(iii) Acid catalysed hydration of an alkene forming an alcohol.arrow_forward
- Show how the following transformations may be accomplished in good yield. You may use any additional reagents that are needed.(a) benzoic acid - phenyl cyclopentyl ketone (b) 1-bromohept-2-ene - oct-3-enalarrow_forward(a) 4 Choose the major product of the following elimination. (b) OH H₂SO4 heat (c) (d) 1 ptsarrow_forwardAddition of one equivalent of ammonia to 1-bromoheptane gives a mixture of heptan-1-amine,some dialkylamine, some trialkylamine, and even some tetraalkylammonium bromide.(a) Give a mechanism to show how this reaction takes place, as far as the dialkylamine.(b) How would you modify the procedure to get an acceptable yield of heptan-1-amine?arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning