(a) Interpretation: The product formed on reaction of 1 − bromo − 2 − butanone with pyridine is to be stated. Concept introduction: The nucleophilic substitution reactions are the reactions in which nucleophile attacks the electrophilic centre and eliminates another group. These reactions depend upon the nucleophilicity and concentration of the nucleophile. The S N 2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously. The S N 1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

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Answer 1

Question

Chapter 22, Problem 22.17P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of 1−bromo−2−butanone with pyridine is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks the electrophilic centre and eliminates another group. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of α−bromoacetophenone with sodium acetate is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

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(A) Provide the major organic product for the reaction below (B) Would the product be optically active of optically in active?

Suggest reactivity of compound A, B and C in increasing order of E2 reaction

Answer 2

Question

Chapter 22, Problem 22.17P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of 1−bromo−2−butanone with pyridine is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks the electrophilic centre and eliminates another group. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of α−bromoacetophenone with sodium acetate is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

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Answer 3

Question

Chapter 22, Problem 22.17P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of 1−bromo−2−butanone with pyridine is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks the electrophilic centre and eliminates another group. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of α−bromoacetophenone with sodium acetate is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

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Answer 4

Question

Chapter 22, Problem 22.17P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of 1−bromo−2−butanone with pyridine is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks the electrophilic centre and eliminates another group. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of α−bromoacetophenone with sodium acetate is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

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Answer 5

Chapter 22, Problem 22.17P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of 1−bromo−2−butanone with pyridine is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks the electrophilic centre and eliminates another group. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of α−bromoacetophenone with sodium acetate is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

Answer 6

Chapter 22, Problem 22.17P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of 1−bromo−2−butanone with pyridine is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks the electrophilic centre and eliminates another group. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

Answer 7

Chapter 22, Problem 22.17P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of 1−bromo−2−butanone with pyridine is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks the electrophilic centre and eliminates another group. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of α−bromoacetophenone with sodium acetate is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of α−bromoacetophenone with sodium acetate is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 22 - Prob. 22.1P Ch. 22 - Prob. 22.2P Ch. 22 - Prob. 22.3P Ch. 22 - Prob. 22.4P Ch. 22 - Prob. 22.5P Ch. 22 - Prob. 22.6P Ch. 22 - Prob. 22.7P Ch. 22 - Prob. 22.8P Ch. 22 - Prob. 22.9P Ch. 22 - Prob. 22.10P

Solution Summary: The author explains that the product formed on reaction of 1-bromo-2- butanone with pyridine is to be stated.

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Chapter 22 Solutions