(a) Interpretation: The curved-arrow mechanism for the reaction of a methyl amine with methyl arcylate is to be stated. Concept introduction: Conjugate addition reactions are those reactions in which a nucleophile attacks at the double bond of an α , β − unsaturated carbonyl compound. This reaction is thermodynamically stable. The nucleophile attacks at the double bond because the intermediate formed is resonance stabilized.

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Answer 1

Question

Chapter 22, Problem 22.47P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the reaction of a methyl amine with methyl arcylate is to be stated.

Concept introduction:

Conjugate addition reactions are those reactions in which a nucleophile attacks at the double bond of an α,β− unsaturated carbonyl compound. This reaction is thermodynamically stable. The nucleophile attacks at the double bond because the intermediate formed is resonance stabilized.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the reaction of phenyl thiolate with α,β− unsaturated carbonyl compound is to be stated.

Concept introduction:

Conjugate addition reactions are those reactions in which a nucleophile attacks at the double bond of an α,β− unsaturated carbonyl compound. This reaction is thermodynamically stable. The nucleophile attacks at the double bond because the intermediate formed is resonance stabilized.

Interpretation Introduction

(c)

Interpretation:

The curved-arrow mechanism for the reaction of a dimethyl amine with diethyl maleate is to be stated.

Concept introduction:

Conjugate addition reactions are those reactions in which a nucleophile attacks at the double bond of an α,β− unsaturated carbonyl compound. This reaction is thermodynamically stable. The nucleophile attacks at the double bond because the intermediate formed is resonance stabilized.

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Students have asked these similar questions

(A) Provide the major organic product for the reaction below (B) Would the product be optically active of optically in active?

Consider the following reaction scheme: (i) Identify compound E. (ii) Draw a curved arrow mechanism that accounts for the formation of E [note: please make sure the mechanism takes into account stereochemical considerations]

(a) What reagents would be used for the conversion of alkene A into the target? (b) What reaction is involved in the conversion of alcohol B into alkene A? Suggest a reagent that might affect this transformation. (c) Give a retrosynthetic analysis showing the disconnection of B, the synthons produced that lead to the synthetic equivalents given (draw their structures).

Answer 2

Question

Chapter 22, Problem 22.47P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the reaction of a methyl amine with methyl arcylate is to be stated.

Concept introduction:

Conjugate addition reactions are those reactions in which a nucleophile attacks at the double bond of an α,β− unsaturated carbonyl compound. This reaction is thermodynamically stable. The nucleophile attacks at the double bond because the intermediate formed is resonance stabilized.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the reaction of phenyl thiolate with α,β− unsaturated carbonyl compound is to be stated.

Concept introduction:

Conjugate addition reactions are those reactions in which a nucleophile attacks at the double bond of an α,β− unsaturated carbonyl compound. This reaction is thermodynamically stable. The nucleophile attacks at the double bond because the intermediate formed is resonance stabilized.

Interpretation Introduction

(c)

Interpretation:

The curved-arrow mechanism for the reaction of a dimethyl amine with diethyl maleate is to be stated.

Concept introduction:

Conjugate addition reactions are those reactions in which a nucleophile attacks at the double bond of an α,β− unsaturated carbonyl compound. This reaction is thermodynamically stable. The nucleophile attacks at the double bond because the intermediate formed is resonance stabilized.

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Answer 3

Question

Chapter 22, Problem 22.47P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the reaction of a methyl amine with methyl arcylate is to be stated.

Concept introduction:

Conjugate addition reactions are those reactions in which a nucleophile attacks at the double bond of an α,β− unsaturated carbonyl compound. This reaction is thermodynamically stable. The nucleophile attacks at the double bond because the intermediate formed is resonance stabilized.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the reaction of phenyl thiolate with α,β− unsaturated carbonyl compound is to be stated.

Concept introduction:

Conjugate addition reactions are those reactions in which a nucleophile attacks at the double bond of an α,β− unsaturated carbonyl compound. This reaction is thermodynamically stable. The nucleophile attacks at the double bond because the intermediate formed is resonance stabilized.

Interpretation Introduction

(c)

Interpretation:

The curved-arrow mechanism for the reaction of a dimethyl amine with diethyl maleate is to be stated.

Concept introduction:

Conjugate addition reactions are those reactions in which a nucleophile attacks at the double bond of an α,β− unsaturated carbonyl compound. This reaction is thermodynamically stable. The nucleophile attacks at the double bond because the intermediate formed is resonance stabilized.

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Answer 4

Question

Chapter 22, Problem 22.47P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the reaction of a methyl amine with methyl arcylate is to be stated.

Concept introduction:

Conjugate addition reactions are those reactions in which a nucleophile attacks at the double bond of an α,β− unsaturated carbonyl compound. This reaction is thermodynamically stable. The nucleophile attacks at the double bond because the intermediate formed is resonance stabilized.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the reaction of phenyl thiolate with α,β− unsaturated carbonyl compound is to be stated.

Concept introduction:

Conjugate addition reactions are those reactions in which a nucleophile attacks at the double bond of an α,β− unsaturated carbonyl compound. This reaction is thermodynamically stable. The nucleophile attacks at the double bond because the intermediate formed is resonance stabilized.

Interpretation Introduction

(c)

Interpretation:

The curved-arrow mechanism for the reaction of a dimethyl amine with diethyl maleate is to be stated.

Concept introduction:

Conjugate addition reactions are those reactions in which a nucleophile attacks at the double bond of an α,β− unsaturated carbonyl compound. This reaction is thermodynamically stable. The nucleophile attacks at the double bond because the intermediate formed is resonance stabilized.

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Answer 5

Chapter 22, Problem 22.47P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the reaction of a methyl amine with methyl arcylate is to be stated.

Concept introduction:

Conjugate addition reactions are those reactions in which a nucleophile attacks at the double bond of an α,β− unsaturated carbonyl compound. This reaction is thermodynamically stable. The nucleophile attacks at the double bond because the intermediate formed is resonance stabilized.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the reaction of phenyl thiolate with α,β− unsaturated carbonyl compound is to be stated.

Concept introduction:

Conjugate addition reactions are those reactions in which a nucleophile attacks at the double bond of an α,β− unsaturated carbonyl compound. This reaction is thermodynamically stable. The nucleophile attacks at the double bond because the intermediate formed is resonance stabilized.

Interpretation Introduction

(c)

Interpretation:

The curved-arrow mechanism for the reaction of a dimethyl amine with diethyl maleate is to be stated.

Concept introduction:

Conjugate addition reactions are those reactions in which a nucleophile attacks at the double bond of an α,β− unsaturated carbonyl compound. This reaction is thermodynamically stable. The nucleophile attacks at the double bond because the intermediate formed is resonance stabilized.

Answer 6

Chapter 22, Problem 22.47P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the reaction of a methyl amine with methyl arcylate is to be stated.

Concept introduction:

Conjugate addition reactions are those reactions in which a nucleophile attacks at the double bond of an α,β− unsaturated carbonyl compound. This reaction is thermodynamically stable. The nucleophile attacks at the double bond because the intermediate formed is resonance stabilized.

Answer 7

Chapter 22, Problem 22.47P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the reaction of a methyl amine with methyl arcylate is to be stated.

Concept introduction:

Conjugate addition reactions are those reactions in which a nucleophile attacks at the double bond of an α,β− unsaturated carbonyl compound. This reaction is thermodynamically stable. The nucleophile attacks at the double bond because the intermediate formed is resonance stabilized.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the reaction of phenyl thiolate with α,β− unsaturated carbonyl compound is to be stated.

Concept introduction:

Conjugate addition reactions are those reactions in which a nucleophile attacks at the double bond of an α,β− unsaturated carbonyl compound. This reaction is thermodynamically stable. The nucleophile attacks at the double bond because the intermediate formed is resonance stabilized.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the reaction of phenyl thiolate with α,β− unsaturated carbonyl compound is to be stated.

Concept introduction:

Conjugate addition reactions are those reactions in which a nucleophile attacks at the double bond of an α,β− unsaturated carbonyl compound. This reaction is thermodynamically stable. The nucleophile attacks at the double bond because the intermediate formed is resonance stabilized.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The curved-arrow mechanism for the reaction of a dimethyl amine with diethyl maleate is to be stated.

Concept introduction:

Conjugate addition reactions are those reactions in which a nucleophile attacks at the double bond of an α,β− unsaturated carbonyl compound. This reaction is thermodynamically stable. The nucleophile attacks at the double bond because the intermediate formed is resonance stabilized.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The curved-arrow mechanism for the reaction of a dimethyl amine with diethyl maleate is to be stated.

Concept introduction:

Conjugate addition reactions are those reactions in which a nucleophile attacks at the double bond of an α,β− unsaturated carbonyl compound. This reaction is thermodynamically stable. The nucleophile attacks at the double bond because the intermediate formed is resonance stabilized.

Answer 12

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Answer 14

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Answer 15

Ch. 22 - Prob. 22.1P Ch. 22 - Prob. 22.2P Ch. 22 - Prob. 22.3P Ch. 22 - Prob. 22.4P Ch. 22 - Prob. 22.5P Ch. 22 - Prob. 22.6P Ch. 22 - Prob. 22.7P Ch. 22 - Prob. 22.8P Ch. 22 - Prob. 22.9P Ch. 22 - Prob. 22.10P

Solution Summary: The author explains the curved-arrow mechanism for the reaction of a methyl amine with an unsaturated carbonyl compound.

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