(a) Interpretation: Among the given compounds the most acidic compound is to be stated. Concept introduction: Brønsted bases are those species which accept a proton. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound. It also depends on the charge, inductive effects, the role of atom present.

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Answer 1

Question

Chapter 22, Problem 22.64AP

Interpretation Introduction

(a)

Interpretation:

Among the given compounds the most acidic compound is to be stated.

Concept introduction:

Brønsted bases are those species which accept a proton. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound. It also depends on the charge, inductive effects, the role of atom present.

Interpretation Introduction

(b)

Interpretation:

Among the given compounds the most acidic compound is to be stated.

Concept introduction:

Brønsted bases are those species which accept a proton. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound. It also depends on the charge, inductive effects, the role of atom present, resonance, orbitals.

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Given the structures, arrange the following in order of decreasing basicity.

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Answer 2

Question

Chapter 22, Problem 22.64AP

Interpretation Introduction

(a)

Interpretation:

Among the given compounds the most acidic compound is to be stated.

Concept introduction:

Brønsted bases are those species which accept a proton. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound. It also depends on the charge, inductive effects, the role of atom present.

Interpretation Introduction

(b)

Interpretation:

Among the given compounds the most acidic compound is to be stated.

Concept introduction:

Brønsted bases are those species which accept a proton. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound. It also depends on the charge, inductive effects, the role of atom present, resonance, orbitals.

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Answer 3

Question

Chapter 22, Problem 22.64AP

Interpretation Introduction

(a)

Interpretation:

Among the given compounds the most acidic compound is to be stated.

Concept introduction:

Brønsted bases are those species which accept a proton. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound. It also depends on the charge, inductive effects, the role of atom present.

Interpretation Introduction

(b)

Interpretation:

Among the given compounds the most acidic compound is to be stated.

Concept introduction:

Brønsted bases are those species which accept a proton. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound. It also depends on the charge, inductive effects, the role of atom present, resonance, orbitals.

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Answer 4

Question

Chapter 22, Problem 22.64AP

Interpretation Introduction

(a)

Interpretation:

Among the given compounds the most acidic compound is to be stated.

Concept introduction:

Brønsted bases are those species which accept a proton. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound. It also depends on the charge, inductive effects, the role of atom present.

Interpretation Introduction

(b)

Interpretation:

Among the given compounds the most acidic compound is to be stated.

Concept introduction:

Brønsted bases are those species which accept a proton. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound. It also depends on the charge, inductive effects, the role of atom present, resonance, orbitals.

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Answer 5

Chapter 22, Problem 22.64AP

Interpretation Introduction

(a)

Interpretation:

Among the given compounds the most acidic compound is to be stated.

Concept introduction:

Brønsted bases are those species which accept a proton. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound. It also depends on the charge, inductive effects, the role of atom present.

Interpretation Introduction

(b)

Interpretation:

Among the given compounds the most acidic compound is to be stated.

Concept introduction:

Brønsted bases are those species which accept a proton. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound. It also depends on the charge, inductive effects, the role of atom present, resonance, orbitals.

Answer 6

Chapter 22, Problem 22.64AP

Interpretation Introduction

(a)

Interpretation:

Among the given compounds the most acidic compound is to be stated.

Concept introduction:

Brønsted bases are those species which accept a proton. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound. It also depends on the charge, inductive effects, the role of atom present.

Answer 7

Chapter 22, Problem 22.64AP

Interpretation Introduction

(a)

Interpretation:

Among the given compounds the most acidic compound is to be stated.

Concept introduction:

Brønsted bases are those species which accept a proton. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound. It also depends on the charge, inductive effects, the role of atom present.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Among the given compounds the most acidic compound is to be stated.

Concept introduction:

Brønsted bases are those species which accept a proton. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound. It also depends on the charge, inductive effects, the role of atom present, resonance, orbitals.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Among the given compounds the most acidic compound is to be stated.

Concept introduction:

Brønsted bases are those species which accept a proton. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound. It also depends on the charge, inductive effects, the role of atom present, resonance, orbitals.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 22 - Prob. 22.1P Ch. 22 - Prob. 22.2P Ch. 22 - Prob. 22.3P Ch. 22 - Prob. 22.4P Ch. 22 - Prob. 22.5P Ch. 22 - Prob. 22.6P Ch. 22 - Prob. 22.7P Ch. 22 - Prob. 22.8P Ch. 22 - Prob. 22.9P Ch. 22 - Prob. 22.10P

Solution Summary: The author explains that the most acidic compound is B due to more stable conjugate base.

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Chapter 22 Solutions