(a) Interpretation: The product of the given reaction is to be predicted. The explanation for the corresponding reaction is to be stated. Concept introduction: Reformatsky reaction is type of organic synthesis reaction in which and an aldehyde or ketone condenses with α -haloester in the presence of zinc metal. An organometallic compound is formed in the reaction which further hydrolysis to give β -hydroxy-esters .

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Answer 1

Question

Chapter 22, Problem 22.44P

Interpretation Introduction

(a)

Interpretation:

The product of the given reaction is to be predicted. The explanation for the corresponding reaction is to be stated.

Concept introduction:

Reformatsky reaction is type of organic synthesis reaction in which and an aldehyde or ketone condenses with α-haloester in the presence of zinc metal. An organometallic compound is formed in the reaction which further hydrolysis to give β-hydroxy-esters.

Interpretation Introduction

(b)

Interpretation:

The products of the given reaction are to be predicted. The explanation for the corresponding reaction is to be stated.

Concept introduction:

The knoevenagel reaction is a modified form of the aldol condensation reaction. In this reaction, a nucleophile attacks the carbon atom of carbonyl group a compound to form a product which further undergoes dehydration reaction with the removal of a water molecule.

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(A) Provide the major organic product for the reaction below (B) Would the product be optically active of optically in active?

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Answer 2

Question

Chapter 22, Problem 22.44P

Interpretation Introduction

(a)

Interpretation:

The product of the given reaction is to be predicted. The explanation for the corresponding reaction is to be stated.

Concept introduction:

Reformatsky reaction is type of organic synthesis reaction in which and an aldehyde or ketone condenses with α-haloester in the presence of zinc metal. An organometallic compound is formed in the reaction which further hydrolysis to give β-hydroxy-esters.

Interpretation Introduction

(b)

Interpretation:

The products of the given reaction are to be predicted. The explanation for the corresponding reaction is to be stated.

Concept introduction:

The knoevenagel reaction is a modified form of the aldol condensation reaction. In this reaction, a nucleophile attacks the carbon atom of carbonyl group a compound to form a product which further undergoes dehydration reaction with the removal of a water molecule.

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Answer 3

Question

Chapter 22, Problem 22.44P

Interpretation Introduction

(a)

Interpretation:

The product of the given reaction is to be predicted. The explanation for the corresponding reaction is to be stated.

Concept introduction:

Reformatsky reaction is type of organic synthesis reaction in which and an aldehyde or ketone condenses with α-haloester in the presence of zinc metal. An organometallic compound is formed in the reaction which further hydrolysis to give β-hydroxy-esters.

Interpretation Introduction

(b)

Interpretation:

The products of the given reaction are to be predicted. The explanation for the corresponding reaction is to be stated.

Concept introduction:

The knoevenagel reaction is a modified form of the aldol condensation reaction. In this reaction, a nucleophile attacks the carbon atom of carbonyl group a compound to form a product which further undergoes dehydration reaction with the removal of a water molecule.

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Answer 4

Question

Chapter 22, Problem 22.44P

Interpretation Introduction

(a)

Interpretation:

The product of the given reaction is to be predicted. The explanation for the corresponding reaction is to be stated.

Concept introduction:

Reformatsky reaction is type of organic synthesis reaction in which and an aldehyde or ketone condenses with α-haloester in the presence of zinc metal. An organometallic compound is formed in the reaction which further hydrolysis to give β-hydroxy-esters.

Interpretation Introduction

(b)

Interpretation:

The products of the given reaction are to be predicted. The explanation for the corresponding reaction is to be stated.

Concept introduction:

The knoevenagel reaction is a modified form of the aldol condensation reaction. In this reaction, a nucleophile attacks the carbon atom of carbonyl group a compound to form a product which further undergoes dehydration reaction with the removal of a water molecule.

Expert Solution & Answer

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Answer 5

Chapter 22, Problem 22.44P

Interpretation Introduction

(a)

Interpretation:

The product of the given reaction is to be predicted. The explanation for the corresponding reaction is to be stated.

Concept introduction:

Reformatsky reaction is type of organic synthesis reaction in which and an aldehyde or ketone condenses with α-haloester in the presence of zinc metal. An organometallic compound is formed in the reaction which further hydrolysis to give β-hydroxy-esters.

Interpretation Introduction

(b)

Interpretation:

The products of the given reaction are to be predicted. The explanation for the corresponding reaction is to be stated.

Concept introduction:

The knoevenagel reaction is a modified form of the aldol condensation reaction. In this reaction, a nucleophile attacks the carbon atom of carbonyl group a compound to form a product which further undergoes dehydration reaction with the removal of a water molecule.

Answer 6

Chapter 22, Problem 22.44P

Interpretation Introduction

(a)

Interpretation:

The product of the given reaction is to be predicted. The explanation for the corresponding reaction is to be stated.

Concept introduction:

Reformatsky reaction is type of organic synthesis reaction in which and an aldehyde or ketone condenses with α-haloester in the presence of zinc metal. An organometallic compound is formed in the reaction which further hydrolysis to give β-hydroxy-esters.

Answer 7

Chapter 22, Problem 22.44P

Interpretation Introduction

(a)

Interpretation:

The product of the given reaction is to be predicted. The explanation for the corresponding reaction is to be stated.

Concept introduction:

Reformatsky reaction is type of organic synthesis reaction in which and an aldehyde or ketone condenses with α-haloester in the presence of zinc metal. An organometallic compound is formed in the reaction which further hydrolysis to give β-hydroxy-esters.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The products of the given reaction are to be predicted. The explanation for the corresponding reaction is to be stated.

Concept introduction:

The knoevenagel reaction is a modified form of the aldol condensation reaction. In this reaction, a nucleophile attacks the carbon atom of carbonyl group a compound to form a product which further undergoes dehydration reaction with the removal of a water molecule.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The products of the given reaction are to be predicted. The explanation for the corresponding reaction is to be stated.

Concept introduction:

The knoevenagel reaction is a modified form of the aldol condensation reaction. In this reaction, a nucleophile attacks the carbon atom of carbonyl group a compound to form a product which further undergoes dehydration reaction with the removal of a water molecule.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 22 - Prob. 22.1P Ch. 22 - Prob. 22.2P Ch. 22 - Prob. 22.3P Ch. 22 - Prob. 22.4P Ch. 22 - Prob. 22.5P Ch. 22 - Prob. 22.6P Ch. 22 - Prob. 22.7P Ch. 22 - Prob. 22.8P Ch. 22 - Prob. 22.9P Ch. 22 - Prob. 22.10P

Solution Summary: The author explains that the product of the given reaction is to be predicted and the explanation for the corresponding reaction.

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Chapter 22 Solutions