(a) Interpretation: The given reaction is to be completed and the reasoning is to be explained. Concept Introduction: The α , β -unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 22, Problem 22.53P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

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Explain the following statements. You must use chemical equations to justify your explanation. (ii) (I) Phenol is more acidic than cyclohexanol.

Answer ALL parts of this question. (a) Using resonance structures, discuss the following statement; phenols are much stronger acids than aliphatic alcohols. (b) Give the structure of a stronger organic acid than phenol. (c) Rationalise the acidity of the latter organic acid by drawing two resonance structures of the conjugate base. (d) Eugenol is a natural product derived from the dried flower buds of the evergreen tree, Eugenia aromatica. Briefly describe a procedure with reagents required to extract eugenol as a single component from the mixture of compounds present in these flower buds. OH LOCH 3 eugenol

(a) (From benzene)

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 22, Problem 22.53P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

Expert Solution & Answer

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 22, Problem 22.53P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

Expert Solution & Answer

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See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 22, Problem 22.53P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

Expert Solution & Answer

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Answer 5

Chapter 22, Problem 22.53P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

Answer 6

Chapter 22, Problem 22.53P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

Answer 7

Chapter 22, Problem 22.53P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

Answer 10

Expert Solution & Answer

Answer 11

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Answer 12

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Answer 13

Ch. 22 - Prob. 22.1P Ch. 22 - Prob. 22.2P Ch. 22 - Prob. 22.3P Ch. 22 - Prob. 22.4P Ch. 22 - Prob. 22.5P Ch. 22 - Prob. 22.6P Ch. 22 - Prob. 22.7P Ch. 22 - Prob. 22.8P Ch. 22 - Prob. 22.9P Ch. 22 - Prob. 22.10P

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Chapter 22 Solutions