(a) Interpretation: Starting material required for the formation of the given compound by Dieckmann condensation is to be stated. Concept Introduction: Dieckmann condensation is the intramolecular Claisen condensation that results in the formation of five or six membered rings. In this reaction, one full equivalent of base is required to drag the reaction towards completion.

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Answer 1

Question

Chapter 22, Problem 22.31P

Interpretation Introduction

(a)

Interpretation:

Starting material required for the formation of the given compound by Dieckmann condensation is to be stated.

Concept Introduction:

Dieckmann condensation is the intramolecular Claisen condensation that results in the formation of five or six membered rings. In this reaction, one full equivalent of base is required to drag the reaction towards completion.

Interpretation Introduction

(b)

Interpretation:

Starting material required for the formation of the given compound by Dieckmann condensation is to be stated.

Concept Introduction:

Dieckmann condensation is the intramolecular Claisen condensation that results in the formation of five or six membered rings. In this reaction one full equivalent of base is required to drag the reaction towards completion.

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3. The following compound has been synthesised in the lab. (a) Give two synthesis methods for the preparation of the compound. (b) Between the two synthesis method given in (a), explain which method is better.

(b) A student wanted to synthesize methyl tert-butyl ether. He attempted the synthesis by adding sodium methoxide to tert-butyl chloride, but he obtained none of the desired product (1) (ii) Use an equation to show the product formed in this reaction Propose a suitable William ether synthetic route for methyl tert-butyl ether tach l.

9. (a) Provide the reagent necessary to carry out the following chemical transformations. (1) (ii)

Answer 2

Question

Chapter 22, Problem 22.31P

Interpretation Introduction

(a)

Interpretation:

Starting material required for the formation of the given compound by Dieckmann condensation is to be stated.

Concept Introduction:

Dieckmann condensation is the intramolecular Claisen condensation that results in the formation of five or six membered rings. In this reaction, one full equivalent of base is required to drag the reaction towards completion.

Interpretation Introduction

(b)

Interpretation:

Starting material required for the formation of the given compound by Dieckmann condensation is to be stated.

Concept Introduction:

Dieckmann condensation is the intramolecular Claisen condensation that results in the formation of five or six membered rings. In this reaction one full equivalent of base is required to drag the reaction towards completion.

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Answer 3

Question

Chapter 22, Problem 22.31P

Interpretation Introduction

(a)

Interpretation:

Starting material required for the formation of the given compound by Dieckmann condensation is to be stated.

Concept Introduction:

Dieckmann condensation is the intramolecular Claisen condensation that results in the formation of five or six membered rings. In this reaction, one full equivalent of base is required to drag the reaction towards completion.

Interpretation Introduction

(b)

Interpretation:

Starting material required for the formation of the given compound by Dieckmann condensation is to be stated.

Concept Introduction:

Dieckmann condensation is the intramolecular Claisen condensation that results in the formation of five or six membered rings. In this reaction one full equivalent of base is required to drag the reaction towards completion.

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Answer 4

Question

Chapter 22, Problem 22.31P

Interpretation Introduction

(a)

Interpretation:

Starting material required for the formation of the given compound by Dieckmann condensation is to be stated.

Concept Introduction:

Dieckmann condensation is the intramolecular Claisen condensation that results in the formation of five or six membered rings. In this reaction, one full equivalent of base is required to drag the reaction towards completion.

Interpretation Introduction

(b)

Interpretation:

Starting material required for the formation of the given compound by Dieckmann condensation is to be stated.

Concept Introduction:

Dieckmann condensation is the intramolecular Claisen condensation that results in the formation of five or six membered rings. In this reaction one full equivalent of base is required to drag the reaction towards completion.

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Answer 5

Chapter 22, Problem 22.31P

Interpretation Introduction

(a)

Interpretation:

Starting material required for the formation of the given compound by Dieckmann condensation is to be stated.

Concept Introduction:

Dieckmann condensation is the intramolecular Claisen condensation that results in the formation of five or six membered rings. In this reaction, one full equivalent of base is required to drag the reaction towards completion.

Interpretation Introduction

(b)

Interpretation:

Starting material required for the formation of the given compound by Dieckmann condensation is to be stated.

Concept Introduction:

Dieckmann condensation is the intramolecular Claisen condensation that results in the formation of five or six membered rings. In this reaction one full equivalent of base is required to drag the reaction towards completion.

Answer 6

Chapter 22, Problem 22.31P

Interpretation Introduction

(a)

Interpretation:

Starting material required for the formation of the given compound by Dieckmann condensation is to be stated.

Concept Introduction:

Dieckmann condensation is the intramolecular Claisen condensation that results in the formation of five or six membered rings. In this reaction, one full equivalent of base is required to drag the reaction towards completion.

Answer 7

Chapter 22, Problem 22.31P

Interpretation Introduction

(a)

Interpretation:

Starting material required for the formation of the given compound by Dieckmann condensation is to be stated.

Concept Introduction:

Dieckmann condensation is the intramolecular Claisen condensation that results in the formation of five or six membered rings. In this reaction, one full equivalent of base is required to drag the reaction towards completion.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Starting material required for the formation of the given compound by Dieckmann condensation is to be stated.

Concept Introduction:

Dieckmann condensation is the intramolecular Claisen condensation that results in the formation of five or six membered rings. In this reaction one full equivalent of base is required to drag the reaction towards completion.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Starting material required for the formation of the given compound by Dieckmann condensation is to be stated.

Concept Introduction:

Dieckmann condensation is the intramolecular Claisen condensation that results in the formation of five or six membered rings. In this reaction one full equivalent of base is required to drag the reaction towards completion.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 22 - Prob. 22.1P Ch. 22 - Prob. 22.2P Ch. 22 - Prob. 22.3P Ch. 22 - Prob. 22.4P Ch. 22 - Prob. 22.5P Ch. 22 - Prob. 22.6P Ch. 22 - Prob. 22.7P Ch. 22 - Prob. 22.8P Ch. 22 - Prob. 22.9P Ch. 22 - Prob. 22.10P

Solution Summary: The author explains that Dieckmann condensation is the intramolecular Claisen condensation that results in the formation of five or six membered rings.

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Chapter 22 Solutions