Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Chapter 3, Problem 4E
Consider the incomplete orbital representation of
a. Identify which lobes are hybrid orbitals (identify the type) and which lobes arep orbitals.
b. Use dotted lines to show any
c. Use up or down arrows to show electron occupation of each hybrid orbital or bond.
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How many pi bonds?
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2) a) Consider the following molecule . Given what you have learned about hybridization theory, draw an image or images explaining the bonding situation in this molecule. I want you to draw out all of the orbitals, hybrid orbitals and how they overlap to form the bonds in the molecule. Indicate the % s or p character in the given atomic and hybrid orbitals. Which C-C bond or bonds are the longest? In a paragraph or so explain the image or images you just drew.
b) Lastly, consider the molecule below. Indicate the Molecular formula, the molar mass, label the hybridization of each atom except for hydrogen, indicate any chiral centers with a *, which bond or bonds are the shortest, identify by name of each functional group with an arrow pointing to the group.
Can someone help me this this? The question is: Determine the orbital in which the indicated non-bonding electrons reside. Candidates include atomic orbitals (s and p), hybrid orbitals (sp, sp2, and sp3), and molecular orbitals (s, s*, p, p*). Here is the picture for it
Chapter 3 Solutions
Organic Chemistry: A Guided Inquiry
Ch. 3 - Prob. 1CTQCh. 3 - What neutral atom is represented by the electron...Ch. 3 - Prob. 3CTQCh. 3 - Consider any one of the four identical hybrid...Ch. 3 - Prob. 5CTQCh. 3 - Prob. 6CTQCh. 3 - Prob. 7CTQCh. 3 - Prob. 8CTQCh. 3 - Prob. 9CTQCh. 3 - Prob. 10CTQ
Ch. 3 - On the left side of Figure 3.6, label the areas...Ch. 3 - Prob. 12CTQCh. 3 - Prob. 13CTQCh. 3 - Prob. 14CTQCh. 3 - Prob. 15CTQCh. 3 - Now consider the fully formed molecule on the...Ch. 3 - Prob. 1ECh. 3 - Explain why the two molecules below cannot...Ch. 3 - Prob. 3ECh. 3 - Consider the incomplete orbital representation of...Ch. 3 - Consider the following orbital representation of...Ch. 3 - Summarize how one determines the hybridization...Ch. 3 - Explain what is wrong with each of the following...Ch. 3 - Prob. 8ECh. 3 - Prob. 9ECh. 3 - Complete the following tables, and memorize their...Ch. 3 - Draw orbital representations of bonding in water...Ch. 3 - Draw electron configuration diagrams for carbon in...Ch. 3 - Prob. 13E
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Now consider the fully formed molecule on the right side of Figure 3.7. a. Draw a Lewis structure of this molecule. b. Identify orbital representations of the two bonds and three bonds in Figure 3.7, andmatch these with representations of bonds on the Lewis structure you just drew.arrow_forwardConsider acetyl salicylic acid, better known as aspirin. Its structure is (a) How many sigma and pi bonds are there in aspirin? (b) What are the approximate values of the angles marked (in blue) A, B, and C? (c) What is the hybridization of each atom marked (in red) 1, 2, and 3?arrow_forwardTrue or false: Boron contains 2s22p1 valence electrons, so only one p orbital is needed to form molecular orbitals.arrow_forward
- Draw the dot structure for: a) ClO3-1 b) ICl2-1 c) What is the shape of ClO3-1? d) What is the shape of ICl2-1? e) What is the hybridization (sp, sp2, sp3, etc) about each central atom in parts a and b above?arrow_forwarda) Consider a molecule of acetone cyanohydrin, shown below. What is the hybridization and molecular geometry at CA, CB, and O? (b) For Carbon B (CB) and nitrogen (N), draw orbital energy diagrams showing the orbitals involved in bonding after hybridization. Be sure to fill the orbitals appropriately with valence electrons. c) In your diagrams in part (b), which orbitals are involved in sigma and pi bonding? Orbitals Involved in Sigma Bonding Orbitals Involved in Pi Bonding 2p sp sp2 sp3 2p sp sp2 sp3 (d) In a sample containing many molecules of acetone cyanohydrin (and no other substances), what type(s) of intermolecular forces could be present? Choose all that apply. Covalent Bonds Hydrogen Bonds Dipole-Dipole Forces London Dispersion Forcesarrow_forwardwhich one of the figures below has every sp3 hybridized atom circled?arrow_forward
- Every atomic orbital, every molecular orbital has a particular name, such as s orbital, p orbital, d orbital, s orbital, p orbital, s* orbital, p* orbital, etc. a. What are the names of the atomic orbitals in 5d above? b.What is the name of the molecular orbital in 5f abovearrow_forwardI have a question regarding hybrid vs atomic orbitals: 1) What would be the hybridizations of C and O in the molecule H2CO? It asks to draw an electron orbital diagram (with arrows) of all the electrons in C before and after hybridization. 2) Draw a diagram of the H2CO molecule showing the overlap of orbitals between the C and O atoms that make up the sigma (σ) and pi (π) bonds. Which orbitals make up the σ bond? Which ones form the π bond?arrow_forwardOut of p-orbital and sp-hybrid orbital which has greater directional character and Why?arrow_forward
- Select the hybridization of SbH5 : a. sp3d2 b. sp3d c. sp3 d. sp2 e. sparrow_forward(a) How many valence electron are in Be2+? (b) How many valence electrons of Be2+ are in bonding molecular orbitals?arrow_forwardIn sp²-hybridized orbitals, how many p-orbitals remain to form multiple bonds?arrow_forward
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