Inorganic Chemistry
5th Edition
ISBN: 9780321811059
Author: Gary L. Miessler, Paul J. Fischer, Donald A. Tarr
Publisher: Prentice Hall
expand_more
expand_more
format_list_bulleted
Textbook Question
Chapter 4.4, Problem 4.9E
Using the x, y, and z coordinates for each atom in
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Use symmetry properties to determine whether or not the integral ∫pxzpzdτ is necessarily zero in a molecule with symmetry D3h.
Using its x, y, and z coordinates, construct the 15 x 15 matrix that describes the application of the S4 symmetry operation to square planar [PtCl 4]2-
What is the character of this matrix?
What are the symmetry species of the normal mode of vibration of CIO2?
Chapter 4 Solutions
Inorganic Chemistry
Ch. 4.1 - Prob. 4.1ECh. 4.1 - Find all the symmetry elements in the following...Ch. 4.2 - Use the procedure described previously to verify...Ch. 4.3 - Prob. 4.4ECh. 4.3 - Verify the transformation matrices for the E and...Ch. 4.3 - Prepare a representation flowchart according to...Ch. 4.4 - Which point groups are possible for chiral...Ch. 4.4 - Write the corresponding 99 transformation matrices...Ch. 4.4 - Using the x, y, and z coordinates for each atom in...Ch. 4.4 - Reduce the following representations to their...
Ch. 4.4 - Prob. 4.11ECh. 4.4 - Analysis of the x, y, and z coordinates of each...Ch. 4.4 - Determine the number of IR-active CO stretching...Ch. 4.4 - Prob. 4.14ECh. 4 - Determine the point groups for a. Ethane...Ch. 4 - Determine the point groups for a. Ethylene b....Ch. 4 - Determine the point groups for a. Acetylene b....Ch. 4 - Determine the point groups for a. Naphthalene b....Ch. 4 - Determine the point groups for a. 1,1’ ...Ch. 4 - Determine the point groups for a. Cyclohexane...Ch. 4 - Determine the point groups for a. A sheet of...Ch. 4 - Determine the point groups for a. A flat oval...Ch. 4 - Determine the point groups for a. A triangular...Ch. 4 - Determine the point groups for the examples of...Ch. 4 - Determine the point groups of the molecules in the...Ch. 4 - Determine the point groups of the molecules and...Ch. 4 - Determine the point groups of the following atomic...Ch. 4 - a. Show that a cube has the same symmetry elements...Ch. 4 - Suppose an octahedron can have either yellow or...Ch. 4 - What point groups are represented by the symbols...Ch. 4 - Prob. 4.17PCh. 4 - Determine the point groups for the following flags...Ch. 4 - Prepare a representation flowchart according to...Ch. 4 - For trans-1,2-dichloroethylene, which has C2h...Ch. 4 - Ethylene has D2h symmetry. a. List all the...Ch. 4 - Using the D2d character table, a. Determine the...Ch. 4 - Reduce the following representations to...Ch. 4 - For D4h symmetry use sketches to show that dxy...Ch. 4 - Prob. 4.25PCh. 4 - XeOF4 has one of the more interesting structures...Ch. 4 - Repeat the procedure from the previous problem,...Ch. 4 - For the following molecules, determine the number...Ch. 4 - Prob. 4.29PCh. 4 - The structure of 1,1,2,2-tetraiododisilane is...Ch. 4 - Both cis and trans isomers of IO2F4 have been...Ch. 4 - White elemental phosphorus consists of tetrahedral...Ch. 4 - Complexes of the general formula Fe(CO)5x( PR3)x...Ch. 4 - Prob. 4.35PCh. 4 - Prob. 4.36PCh. 4 - Prob. 4.37PCh. 4 - Prob. 4.38PCh. 4 - Determine the point groups of the following...Ch. 4 - Prob. 4.40PCh. 4 - Determine the point groups of the following: a....Ch. 4 - Use the Internet to search for molecules with the...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Which of the fol lowing molecules can have (a) a pure rotational spectrum and (b) a rotational Raman spectrum: (i) HCI, Iii) N2O, (i ii) O3, (iv) SF4, (v) XeF4?arrow_forwardThe average spacing between the rotational lines of the P and R branches of 12C21H2 and 12C22H2 is 2.352 cm−1 and 1.696 cm−1, respectively. Estimate the CC and CH bond lengths.arrow_forwardWhat are the symmetry elements of 2-butene assuming CH3 is spherical?arrow_forward
- What is the full term symbol of the ground electronic state of Li2+?arrow_forwardHow many vibrational modes does an SO3 molecule have a) in the plane of the nuclei, b) perpendicular to the molecular plane? c) Classify them by their symmetry type.arrow_forwardEstimate the value of Erot for the lowest rotational energy state of N2, which has a bond length 0.110 nm.arrow_forward
- For which of the following diatomic molecules is the high temperature expression valid for rotation when T=50.0K (1) DF (2) CO (3) 79 Br35 Cl (4) F2 (5) I2arrow_forwardXeF4 is a square planar molecule that has 9 vibrationalmodes. How many degrees of freedom does this molecule have?arrow_forwardWhat are the symmetry species of the vibrations of a) SF6, b) BF3 that are both IR and Raman active?arrow_forward
- How many normal modes of vibration are there for the following molecules:(a) HI, (b) CO2, (c) HCN, (d) H2O, (e) NH3, (f) CH4, (g) SF6?arrow_forwardDescribe the [3,3] sigmatographic rearrangement as a simmetry of the orbital.arrow_forwardClassify the irreducible representations into translational, rotational, and vibrational modes.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage LearningPhysical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,
Gerade and Ungerade Molecular Orbitals. (SYMMETRY OF MOLECULAR ORBITALS); Author: Edmerls;https://www.youtube.com/watch?v=dPY-lT5LN60;License: Standard YouTube License, CC-BY
Symmetry and chemical bonding part – 5 Molecular orbital formation (CHE); Author: Vidya-mitra;https://www.youtube.com/watch?v=g-42GmpBu0I;License: Standard Youtube License