Inorganic Chemistry
Inorganic Chemistry
5th Edition
ISBN: 9780321811059
Author: Gary L. Miessler, Paul J. Fischer, Donald A. Tarr
Publisher: Prentice Hall
Question
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Chapter 4.3, Problem 4.4E

(a)

Interpretation Introduction

Interpretation: The given multiplication of matrix needs to be performed.

  [513423123]×[211123543]

Concept Introduction: A matrix is represented as an ordered array of numbers as follows:

  [3721] or, [201]

In order to multiply two matrices, in first matrix the number in vertical columns should be equal to the number of horizontal rows in the second matrix. To perform the multiplication, the product of each row in the first matrix needs to be added term by term on the each column of the second matrix. The resulting number after addition is placed in the product matrix with row obtained from the row of the first matrix and column obtained from the column of the second matrix.

The mathematical representation is as follows:

  Cij=Aik×Bkj

Here, Cij is product matrix with i row and j column.

  Aik is initial matrix A with i row and k column.

  Bkj is initial matrix B with k row and j column.

(b)

Interpretation Introduction

Interpretation: The given multiplication of matrix needs to be performed.

  [112011100]×[213]

Concept Introduction: A matrix is represented as an ordered array of numbers as follows:

  [3721] or, [201]

In order to multiply two matrices, in first matrix the number in vertical columns should be equal to the number of horizontal rows in the second matrix. To perform the multiplication, the product of each row in the first matrix needs to be added term by term on the each column of the second matrix. The resulting number after addition is placed in the product matrix with row obtained from the row of the first matrix and column obtained from the column of the second matrix.

The mathematical representation is as follows:

  Cij=Aik×Bkj

Here, Cij is product matrix with i row and j column.

  Aik is initial matrix A with i row and k column.

  Bkj is initial matrix B with k row and j column.

(c)

Interpretation Introduction

Interpretation: The given multiplication of matrix needs to be performed.

  [123]×[112211321]

Concept Introduction: A matrix is represented as an ordered array of numbers as follows:

  [3721] or, [201]

In order to multiply two matrices, in first matrix the number in vertical columns should be equal to the number of horizontal rows in the second matrix. To perform the multiplication, the product of each row in the first matrix needs to be added term by term on the each column of the second matrix. The resulting number after addition is placed in the product matrix with row obtained from the row of the first matrix and column obtained from the column of the second matrix.

The mathematical representation is as follows:

  Cij=Aik×Bkj

Here, Cij is product matrix with i row and j column.

  Aik is initial matrix A with i row and k column.

  Bkj is initial matrix B with k row and j column.

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Chapter 4 Solutions

Inorganic Chemistry

Ch. 4.4 - Prob. 4.11ECh. 4.4 - Analysis of the x, y, and z coordinates of each...Ch. 4.4 - Determine the number of IR-active CO stretching...Ch. 4.4 - Prob. 4.14ECh. 4 - Determine the point groups for a. Ethane...Ch. 4 - Determine the point groups for a. Ethylene b....Ch. 4 - Determine the point groups for a. Acetylene b....Ch. 4 - Determine the point groups for a. Naphthalene b....Ch. 4 - Determine the point groups for a. 1,1’ ...Ch. 4 - Determine the point groups for a. Cyclohexane...Ch. 4 - Determine the point groups for a. A sheet of...Ch. 4 - Determine the point groups for a. A flat oval...Ch. 4 - Determine the point groups for a. A triangular...Ch. 4 - Determine the point groups for the examples of...Ch. 4 - Determine the point groups of the molecules in the...Ch. 4 - Determine the point groups of the molecules and...Ch. 4 - Determine the point groups of the following atomic...Ch. 4 - a. Show that a cube has the same symmetry elements...Ch. 4 - Suppose an octahedron can have either yellow or...Ch. 4 - What point groups are represented by the symbols...Ch. 4 - Prob. 4.17PCh. 4 - Determine the point groups for the following flags...Ch. 4 - Prepare a representation flowchart according to...Ch. 4 - For trans-1,2-dichloroethylene, which has C2h...Ch. 4 - Ethylene has D2h symmetry. a. List all the...Ch. 4 - Using the D2d character table, a. Determine the...Ch. 4 - Reduce the following representations to...Ch. 4 - For D4h symmetry use sketches to show that dxy...Ch. 4 - Prob. 4.25PCh. 4 - XeOF4 has one of the more interesting structures...Ch. 4 - Repeat the procedure from the previous problem,...Ch. 4 - For the following molecules, determine the number...Ch. 4 - Prob. 4.29PCh. 4 - The structure of 1,1,2,2-tetraiododisilane is...Ch. 4 - Both cis and trans isomers of IO2F4 have been...Ch. 4 - White elemental phosphorus consists of tetrahedral...Ch. 4 - Complexes of the general formula Fe(CO)5x( PR3)x...Ch. 4 - Prob. 4.35PCh. 4 - Prob. 4.36PCh. 4 - Prob. 4.37PCh. 4 - Prob. 4.38PCh. 4 - Determine the point groups of the following...Ch. 4 - Prob. 4.40PCh. 4 - Determine the point groups of the following: a....Ch. 4 - Use the Internet to search for molecules with the...
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