An Introduction to Thermal Physics
1st Edition
ISBN: 9780201380279
Author: Daniel V. Schroeder
Publisher: Addison Wesley
expand_more
expand_more
format_list_bulleted
Textbook Question
Chapter 5.3, Problem 26P
How can diamond ever be more stable than graphite, when it has less entropy? Explain how at, high pressure the conversion of graphite to diamond can increase the total entropy of the carbon plus its environment.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Explain how at high pressures the conversion of graphite to diamond can increase the total entropy of the carbon plus its environment.
The boiling point of compound X is 12° C and its enthalpy of vaporization is 24.6 KJ/mole. What is the entropy (in Joules/mole) of vaporization for this compound?(NOTE: express answer in the NEAREST WHOLE NUMBERS)
I attached the question and the answer
How does the negative sign appear in the first integral
And then what are they doing in the second part what’s env ?
Shouldn’t we just find the total change in entropy
Chapter 5 Solutions
An Introduction to Thermal Physics
Ch. 5.1 - Prob. 1PCh. 5.1 - Consider the production of ammonia from nitrogen...Ch. 5.1 - Prob. 3PCh. 5.1 - Prob. 4PCh. 5.1 - Consider a fuel cell that uses methane (natural...Ch. 5.1 - Prob. 6PCh. 5.1 - The metabolism of a glucose molecule (see previous...Ch. 5.1 - Derive the thermodynamic identity for G (equation...Ch. 5.1 - Sketch a qualitatively accurate graph of G vs. T...Ch. 5.1 - Suppose you have a mole of water at 25C and...
Ch. 5.1 - Suppose that a hydrogen fuel cell, as described in...Ch. 5.1 - Prob. 12PCh. 5.1 - Prob. 13PCh. 5.1 - Prob. 14PCh. 5.1 - Prob. 15PCh. 5.1 - Prob. 16PCh. 5.1 - Prob. 17PCh. 5.2 - Prob. 18PCh. 5.2 - In the previous section 1 derived the formula...Ch. 5.2 - Prob. 20PCh. 5.2 - Is heat capacity (C) extensive or intensive? What...Ch. 5.2 - Prob. 22PCh. 5.2 - Prob. 23PCh. 5.3 - Go through the arithmetic to verify that diamond...Ch. 5.3 - Prob. 25PCh. 5.3 - How can diamond ever be more stable than graphite,...Ch. 5.3 - Prob. 27PCh. 5.3 - Calcium carbonate, CaCO3, has two common...Ch. 5.3 - Aluminum silicate, Al2SiO5, has three different...Ch. 5.3 - Sketch qualitatively accurate graphs of G vs. T...Ch. 5.3 - Sketch qualitatively accurate graphs of G vs. P...Ch. 5.3 - The density of ice is 917kg/m3. (a) Use the...Ch. 5.3 - An inventor proposes to make a heat engine using...Ch. 5.3 - Below 0.3 K the Slope of the 3He solid–liquid...Ch. 5.3 - Prob. 35PCh. 5.3 - Effect of altitude on boiling water. (a) Use the...Ch. 5.3 - Prob. 37PCh. 5.3 - Prob. 38PCh. 5.3 - Prob. 39PCh. 5.3 - The methods of this section can also be applied to...Ch. 5.3 - Suppose you have a liquid (say, water) in...Ch. 5.3 - Ordinarily, the partial pressure of water vapor in...Ch. 5.3 - Assume that the air you exhale is at 35C, with a...Ch. 5.3 - Prob. 44PCh. 5.3 - Prob. 46PCh. 5.3 - Prob. 47PCh. 5.3 - Prob. 48PCh. 5.3 - Prob. 49PCh. 5.3 - The compression factor of a fluid is defined as...Ch. 5.3 - Prob. 51PCh. 5.3 - Prob. 52PCh. 5.3 - Repeat the preceding problem for T/Tc=0.8.Ch. 5.3 - Prob. 54PCh. 5.3 - Prob. 55PCh. 5.4 - Prove that the entropy of mixing of an ideal...Ch. 5.4 - In this problem you will model the mixing energy...Ch. 5.4 - Suppose you cool a mixture of 50% nitrogen and 50%...Ch. 5.4 - Suppose you start with a liquid mixture of 60%...Ch. 5.4 - Suppose you need a tank of oxygen that is 95%...Ch. 5.4 - Prob. 62PCh. 5.4 - Everything in this section assumes that the total...Ch. 5.4 - Figure 5.32 shows the phase diagram of plagioclase...Ch. 5.4 - Prob. 65PCh. 5.4 - Prob. 66PCh. 5.4 - Prob. 67PCh. 5.4 - Plumbers solder is composed of 67% lead and 33%...Ch. 5.4 - What happens when you spread salt crystals over an...Ch. 5.4 - What happens when you add salt to the ice bath in...Ch. 5.4 - Figure 5.35 (left) shows the free energy curves at...Ch. 5.4 - Repeat the previous problem for the diagram in...Ch. 5.5 - If expression 5.68 is correct, it must be...Ch. 5.5 - Prob. 74PCh. 5.5 - Compare expression 5.68 for the Gibbs free energy...Ch. 5.5 - Seawater has a salinity of 3.5%, meaning that if...Ch. 5.5 - Osmotic pressure measurements can be used to...Ch. 5.5 - Because osmotic pressures can be quite large, you...Ch. 5.5 - Most pasta recipes instruct you to add a teaspoon...Ch. 5.5 - Use the Clausius–Clapeyron relation to derive...Ch. 5.5 - Prob. 81PCh. 5.5 - Use the result of the previous problem to...Ch. 5.6 - Prob. 83PCh. 5.6 - Prob. 84PCh. 5.6 - Prob. 85PCh. 5.6 - Prob. 86PCh. 5.6 - Sulfuric acid, H2SO4, readily dissociates into H+...Ch. 5.6 - Prob. 88PCh. 5.6 - Prob. 89PCh. 5.6 - When solid quartz dissolves in water, it combines...Ch. 5.6 - When carbon dioxide dissolves in water,...Ch. 5.6 - Prob. 92P
Additional Science Textbook Solutions
Find more solutions based on key concepts
Geological Time. Geological time scales are often written in ways that can mask their significance. For each of...
Life in the Universe (4th Edition)
Does the constellation that was highest in the sky at midnight a month ago now rise earlier or later than it ro...
Lecture- Tutorials for Introductory Astronomy
13. The perturbations of Uranus led to what greater discovery?
Conceptual Physical Science (6th Edition)
What vertical launch speed is necessary to get a rocket to an altitude of 1100 km?
Essential University Physics: Volume 1 (3rd Edition)
30.46 CP CALC A Coaxial Cable. A small solid conductor with radius a is supported by insulating, nonmagnetic d...
University Physics with Modern Physics (14th Edition)
Youre sizing a new electric transmission line, and you can save money with thinner wire. The potential differen...
Essential University Physics (3rd Edition)
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, physics and related others by exploring similar questions and additional content below.Similar questions
- Assume a sample of an ideal gas is at room temperature. What action will necessarily make the entropy of the sample increase? (a) Transfer energy into it by heat, (b) Transfer energy into it irreversibly by heat, (c) Do work on it. (d) Increase either its temperature or its volume, without letting the other variable decrease, (e) None of those choices is correct.arrow_forwardHow many possible arrangements are there for a deck of 52 palying cards? (for simplicity, consider only the order of the cards, not whether they are turned upside- down, etc.) Suppose you start with a sorted deck and shuffle it repeatedly, so that all arrangements become "accessible". How much entropy do you create in the process?arrow_forwardPlease explain how (dH/dS)N,P = T and what the value of (dS/dN)H,P is for a monoatomic ideal gas.arrow_forward
- Air is expanded from 2000 kPa and 500C to 100 kPaand 50C. Assuming constant specific heats, determine thechange in the specific entropy of air.arrow_forward(II) Suppose that you repeatedly shake six coins in your handand drop them on the floor. Construct a table showing thenumber of microstates that correspond to each macrostate.What is the probability of obtaining (a) three heads andthree tails, and (b) six heads?arrow_forwardGibb’s free energy is defined as G≡H-TS and H ≡ U+PV. Show that dU=TdS-PdV, dH=TdS+VdP and dG=VdP-SdT. 2. If non-PV work is done (P and T constant), dU= TdS-PdV +dwother. Knowing that dH=dU+PdV+VdP and dG= dH-SdT-TdS, show that dG=dwother. We often call free energy the chemical work for a reaction!arrow_forward
- 70 moles of a certain substance (MW = 45 g/mol), when heated at constant pressure from 60 ⁰C to 75 ⁰C, results to 170 J/K change in entropy. Determine the specific heat capacity of the substance (in J/g-K).arrow_forwardBy how much does the entropy of 1.0 kg of water change when heated from 263.15 K up to 283.15 K at a pressure of 1 bar? (The solution is 1.5 kJ/K)arrow_forwardAn ideal gas at temperature T is stored in the left half of an insulating container of volume V using a partition of negligible volume (see below). What is the entropy change per mole of the gas in each of the following cases? (a) The partition is suddenly removed and the gas quickly fills the entire container. (b) A tiny hole is punctured in the partition and after a long period, the gas reaches an equilibrium state such that there is no net flow through the hole. (c) The partition is moved very slowly and adiabatically all the way to the light wall so that the gas finally fills the entire container.arrow_forward
- A great deal of effort, time, and money has been spent in the quest for a so-called perpetual-motion machine, which is defined as a hypothetical machine that operates or produces useful work indefinitely and/or a hypothetical machine that produces mole work or energy than it consumes. Explain, in terms of the first law of thermodynamics, why or why not such a machine is likely to be constructed.arrow_forwardA cylinder contains 500 g of helium at 120 atm and 20 . The valve is leaky, and all the gas slowly escapes isothermally into the atmosphere. Use the results of the preceding problem to determine the resulting change in entropy of the universe.arrow_forwardAn ideal gas at 300 K is compressed isothermally to one-fifth its original volume. Determine the entropy change per mole of the gas.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Physics for Scientists and Engineers: Foundations...PhysicsISBN:9781133939146Author:Katz, Debora M.Publisher:Cengage LearningCollege PhysicsPhysicsISBN:9781938168000Author:Paul Peter Urone, Roger HinrichsPublisher:OpenStax CollegePhysics for Scientists and Engineers, Technology ...PhysicsISBN:9781305116399Author:Raymond A. Serway, John W. JewettPublisher:Cengage Learning
- An Introduction to Physical SciencePhysicsISBN:9781305079137Author:James Shipman, Jerry D. Wilson, Charles A. Higgins, Omar TorresPublisher:Cengage Learning
Physics for Scientists and Engineers: Foundations...
Physics
ISBN:9781133939146
Author:Katz, Debora M.
Publisher:Cengage Learning
College Physics
Physics
ISBN:9781938168000
Author:Paul Peter Urone, Roger Hinrichs
Publisher:OpenStax College
Physics for Scientists and Engineers, Technology ...
Physics
ISBN:9781305116399
Author:Raymond A. Serway, John W. Jewett
Publisher:Cengage Learning
An Introduction to Physical Science
Physics
ISBN:9781305079137
Author:James Shipman, Jerry D. Wilson, Charles A. Higgins, Omar Torres
Publisher:Cengage Learning
The Laws of Thermodynamics, Entropy, and Gibbs Free Energy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=8N1BxHgsoOw;License: Standard YouTube License, CC-BY