An Introduction to Thermal Physics
1st Edition
ISBN: 9780201380279
Author: Daniel V. Schroeder
Publisher: Addison Wesley
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Textbook Question
Chapter 5.3, Problem 30P
Sketch qualitatively accurate graphs of G vs. T for the three phases of
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Chapter 5 Solutions
An Introduction to Thermal Physics
Ch. 5.1 - Prob. 1PCh. 5.1 - Consider the production of ammonia from nitrogen...Ch. 5.1 - Prob. 3PCh. 5.1 - Prob. 4PCh. 5.1 - Consider a fuel cell that uses methane (natural...Ch. 5.1 - Prob. 6PCh. 5.1 - The metabolism of a glucose molecule (see previous...Ch. 5.1 - Derive the thermodynamic identity for G (equation...Ch. 5.1 - Sketch a qualitatively accurate graph of G vs. T...Ch. 5.1 - Suppose you have a mole of water at 25C and...
Ch. 5.1 - Suppose that a hydrogen fuel cell, as described in...Ch. 5.1 - Prob. 12PCh. 5.1 - Prob. 13PCh. 5.1 - Prob. 14PCh. 5.1 - Prob. 15PCh. 5.1 - Prob. 16PCh. 5.1 - Prob. 17PCh. 5.2 - Prob. 18PCh. 5.2 - In the previous section 1 derived the formula...Ch. 5.2 - Prob. 20PCh. 5.2 - Is heat capacity (C) extensive or intensive? What...Ch. 5.2 - Prob. 22PCh. 5.2 - Prob. 23PCh. 5.3 - Go through the arithmetic to verify that diamond...Ch. 5.3 - Prob. 25PCh. 5.3 - How can diamond ever be more stable than graphite,...Ch. 5.3 - Prob. 27PCh. 5.3 - Calcium carbonate, CaCO3, has two common...Ch. 5.3 - Aluminum silicate, Al2SiO5, has three different...Ch. 5.3 - Sketch qualitatively accurate graphs of G vs. T...Ch. 5.3 - Sketch qualitatively accurate graphs of G vs. P...Ch. 5.3 - The density of ice is 917kg/m3. (a) Use the...Ch. 5.3 - An inventor proposes to make a heat engine using...Ch. 5.3 - Below 0.3 K the Slope of the 3He solid–liquid...Ch. 5.3 - Prob. 35PCh. 5.3 - Effect of altitude on boiling water. (a) Use the...Ch. 5.3 - Prob. 37PCh. 5.3 - Prob. 38PCh. 5.3 - Prob. 39PCh. 5.3 - The methods of this section can also be applied to...Ch. 5.3 - Suppose you have a liquid (say, water) in...Ch. 5.3 - Ordinarily, the partial pressure of water vapor in...Ch. 5.3 - Assume that the air you exhale is at 35C, with a...Ch. 5.3 - Prob. 44PCh. 5.3 - Prob. 46PCh. 5.3 - Prob. 47PCh. 5.3 - Prob. 48PCh. 5.3 - Prob. 49PCh. 5.3 - The compression factor of a fluid is defined as...Ch. 5.3 - Prob. 51PCh. 5.3 - Prob. 52PCh. 5.3 - Repeat the preceding problem for T/Tc=0.8.Ch. 5.3 - Prob. 54PCh. 5.3 - Prob. 55PCh. 5.4 - Prove that the entropy of mixing of an ideal...Ch. 5.4 - In this problem you will model the mixing energy...Ch. 5.4 - Suppose you cool a mixture of 50% nitrogen and 50%...Ch. 5.4 - Suppose you start with a liquid mixture of 60%...Ch. 5.4 - Suppose you need a tank of oxygen that is 95%...Ch. 5.4 - Prob. 62PCh. 5.4 - Everything in this section assumes that the total...Ch. 5.4 - Figure 5.32 shows the phase diagram of plagioclase...Ch. 5.4 - Prob. 65PCh. 5.4 - Prob. 66PCh. 5.4 - Prob. 67PCh. 5.4 - Plumbers solder is composed of 67% lead and 33%...Ch. 5.4 - What happens when you spread salt crystals over an...Ch. 5.4 - What happens when you add salt to the ice bath in...Ch. 5.4 - Figure 5.35 (left) shows the free energy curves at...Ch. 5.4 - Repeat the previous problem for the diagram in...Ch. 5.5 - If expression 5.68 is correct, it must be...Ch. 5.5 - Prob. 74PCh. 5.5 - Compare expression 5.68 for the Gibbs free energy...Ch. 5.5 - Seawater has a salinity of 3.5%, meaning that if...Ch. 5.5 - Osmotic pressure measurements can be used to...Ch. 5.5 - Because osmotic pressures can be quite large, you...Ch. 5.5 - Most pasta recipes instruct you to add a teaspoon...Ch. 5.5 - Use the Clausius–Clapeyron relation to derive...Ch. 5.5 - Prob. 81PCh. 5.5 - Use the result of the previous problem to...Ch. 5.6 - Prob. 83PCh. 5.6 - Prob. 84PCh. 5.6 - Prob. 85PCh. 5.6 - Prob. 86PCh. 5.6 - Sulfuric acid, H2SO4, readily dissociates into H+...Ch. 5.6 - Prob. 88PCh. 5.6 - Prob. 89PCh. 5.6 - When solid quartz dissolves in water, it combines...Ch. 5.6 - When carbon dioxide dissolves in water,...Ch. 5.6 - Prob. 92P
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- In a student experiment, a constant-volume gas thermometer is calibrated in liquid nitrogen (−196°C) and in boiling methyl alcohol (64.7°C). The separate pressures are 0.344 atm and 1.556 atm. Hint: Use the linear relationship P = A + BT, where A and B are constants. (a) What value of absolute zero does the calibration yield?? °C(b) What pressure would be found at the freezing point of water? ?atm(c) What pressure would be found at the boiling point of water? ?atmarrow_forwardAccording to the Ideal Gas Law, PV = kT, where P is pressure, V is volume, T is temperature (in kelvins), and k is a constant of proportionality. A tank contains 400 cubic inches of nitrogen at a pressure of 130 pounds per square inch and a temperature of 300 K. (a) Determine k.k = (b) Write P as a function of V and T and describe the level curves.P = (c) Setting P = c, the level curves are of the form V =arrow_forwardOn a hot summer day, the density of air at atmospheric pressure at 35 °C is 1.1455 kg/m3. What is the number of moles contained in 1 m3 of ideal gas at this temperature and pressure? Avogadro’s number of air molecules has a mass of 2.85×10-2kg. what is the mass of 1 m3 of air? Does the value calculated in part (B) agree with the stated density of air at this temperature?arrow_forward
- How many molecules are present in a sample of an ideal gas that occupies a volume of 1.70 cm3, is at a temperature of 20°C, and is at atmospheric pressure? How many molecules of the gas are present if the volume and temperature are the same as in part (a), but the pressure is now 2.80 ✕ 10−11 Pa (an extremely good vacuum)?arrow_forwardCharles’ law states that for a fixed mass of gas under constant pressure, the volume V and temperature T of the gas (in kelvins) satisfy the equation V = kT, where k is constant. Find an equation relating dV>dt to dT>dt.arrow_forwardAvagadro's number (6.023 × 1023) is a pure (unitless) number which serves as a good standard for measuring the number of molecules in ideal gases at STP. A)What is the volume, in cubic kilometers, of Avogadro’s number of sand grains, if each grain is a cube with an edge length of 1.3 mm and the cubes are densely packed (with no air between them). B) How long, in kilometers, would a beach have to be for this sand to cover it to a depth of 10.0 m? Assume a beach is 100.0 m wide, and you can neglect the air spaces between the grains.arrow_forward
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