An Introduction to Thermal Physics
1st Edition
ISBN: 9780201380279
Author: Daniel V. Schroeder
Publisher: Addison Wesley
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Chapter 5.2, Problem 18P
To determine
The reason why the energy of the system tends to spontaneously decrease.
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Check out a sample textbook solutionChapter 5 Solutions
An Introduction to Thermal Physics
Ch. 5.1 - Prob. 1PCh. 5.1 - Consider the production of ammonia from nitrogen...Ch. 5.1 - Prob. 3PCh. 5.1 - Prob. 4PCh. 5.1 - Consider a fuel cell that uses methane (natural...Ch. 5.1 - Prob. 6PCh. 5.1 - The metabolism of a glucose molecule (see previous...Ch. 5.1 - Derive the thermodynamic identity for G (equation...Ch. 5.1 - Sketch a qualitatively accurate graph of G vs. T...Ch. 5.1 - Suppose you have a mole of water at 25C and...
Ch. 5.1 - Suppose that a hydrogen fuel cell, as described in...Ch. 5.1 - Prob. 12PCh. 5.1 - Prob. 13PCh. 5.1 - Prob. 14PCh. 5.1 - Prob. 15PCh. 5.1 - Prob. 16PCh. 5.1 - Prob. 17PCh. 5.2 - Prob. 18PCh. 5.2 - In the previous section 1 derived the formula...Ch. 5.2 - Prob. 20PCh. 5.2 - Is heat capacity (C) extensive or intensive? What...Ch. 5.2 - Prob. 22PCh. 5.2 - Prob. 23PCh. 5.3 - Go through the arithmetic to verify that diamond...Ch. 5.3 - Prob. 25PCh. 5.3 - How can diamond ever be more stable than graphite,...Ch. 5.3 - Prob. 27PCh. 5.3 - Calcium carbonate, CaCO3, has two common...Ch. 5.3 - Aluminum silicate, Al2SiO5, has three different...Ch. 5.3 - Sketch qualitatively accurate graphs of G vs. T...Ch. 5.3 - Sketch qualitatively accurate graphs of G vs. P...Ch. 5.3 - The density of ice is 917kg/m3. (a) Use the...Ch. 5.3 - An inventor proposes to make a heat engine using...Ch. 5.3 - Below 0.3 K the Slope of the 3He solid–liquid...Ch. 5.3 - Prob. 35PCh. 5.3 - Effect of altitude on boiling water. (a) Use the...Ch. 5.3 - Prob. 37PCh. 5.3 - Prob. 38PCh. 5.3 - Prob. 39PCh. 5.3 - The methods of this section can also be applied to...Ch. 5.3 - Suppose you have a liquid (say, water) in...Ch. 5.3 - Ordinarily, the partial pressure of water vapor in...Ch. 5.3 - Assume that the air you exhale is at 35C, with a...Ch. 5.3 - Prob. 44PCh. 5.3 - Prob. 46PCh. 5.3 - Prob. 47PCh. 5.3 - Prob. 48PCh. 5.3 - Prob. 49PCh. 5.3 - The compression factor of a fluid is defined as...Ch. 5.3 - Prob. 51PCh. 5.3 - Prob. 52PCh. 5.3 - Repeat the preceding problem for T/Tc=0.8.Ch. 5.3 - Prob. 54PCh. 5.3 - Prob. 55PCh. 5.4 - Prove that the entropy of mixing of an ideal...Ch. 5.4 - In this problem you will model the mixing energy...Ch. 5.4 - Suppose you cool a mixture of 50% nitrogen and 50%...Ch. 5.4 - Suppose you start with a liquid mixture of 60%...Ch. 5.4 - Suppose you need a tank of oxygen that is 95%...Ch. 5.4 - Prob. 62PCh. 5.4 - Everything in this section assumes that the total...Ch. 5.4 - Figure 5.32 shows the phase diagram of plagioclase...Ch. 5.4 - Prob. 65PCh. 5.4 - Prob. 66PCh. 5.4 - Prob. 67PCh. 5.4 - Plumbers solder is composed of 67% lead and 33%...Ch. 5.4 - What happens when you spread salt crystals over an...Ch. 5.4 - What happens when you add salt to the ice bath in...Ch. 5.4 - Figure 5.35 (left) shows the free energy curves at...Ch. 5.4 - Repeat the previous problem for the diagram in...Ch. 5.5 - If expression 5.68 is correct, it must be...Ch. 5.5 - Prob. 74PCh. 5.5 - Compare expression 5.68 for the Gibbs free energy...Ch. 5.5 - Seawater has a salinity of 3.5%, meaning that if...Ch. 5.5 - Osmotic pressure measurements can be used to...Ch. 5.5 - Because osmotic pressures can be quite large, you...Ch. 5.5 - Most pasta recipes instruct you to add a teaspoon...Ch. 5.5 - Use the Clausius–Clapeyron relation to derive...Ch. 5.5 - Prob. 81PCh. 5.5 - Use the result of the previous problem to...Ch. 5.6 - Prob. 83PCh. 5.6 - Prob. 84PCh. 5.6 - Prob. 85PCh. 5.6 - Prob. 86PCh. 5.6 - Sulfuric acid, H2SO4, readily dissociates into H+...Ch. 5.6 - Prob. 88PCh. 5.6 - Prob. 89PCh. 5.6 - When solid quartz dissolves in water, it combines...Ch. 5.6 - When carbon dioxide dissolves in water,...Ch. 5.6 - Prob. 92P
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- Check Your Understanding There is a second solution to the system of equations solved in this example (because the energy equation is quadratic): v1.f=-2.5m/s , v2.f=0 . This solution is unacceptable on physical grounds; what’s with it?arrow_forwardTwo blocks of masses m and 3m are placed on a frictionless, horizontal surface. A light spring is attached to the more massive block, and the blocks are pushed together with the spring between them (Fig. P8.7). A cord initially holding the blocks together is burned; after that happens, the block of mass 3m moves to the right with a speed of 2.00 m/s. (a) What is the velocity of the block of mass m? (b) Find the systems original elastic potential energy, taking m = 0.350 kg. (c) Is the original energy in the spring or in the cord? (d) Explain your answer to part (c). (e) Is the momentum of the system conserved in the bursting-apart process? Explain how that is possible considering (f) there are large forces acting and (g) there is no motion beforehand and plenty of motion afterward? Figure P8.7arrow_forwardA block is placed on top of a vertical spring, and the spring compresses. Figure P8.24 depicts a moment in time when the spring is compressed by an amount h. a. To calculate the change in the gravitational and elastic potential energies, what must be included in the system? b. Find an expression for the change in the systems potential energy in terms of the parameters shown in Figure P8.24. c. If m = 0.865 kg and k = 125 N/m, find the change in the systems potential energy when the blocks displacement is h = 0.0650 m, relative to its initial position. FIGURE P8.24arrow_forward
- A 20.0-kg cannonball is fired from a cannon with muzzle speed of 1 000 m/s at an angle of 37.0 with the horizontal. A second ball is fired at an angle of 90.0. Use the isolated system model to find (a) the maximum height reached by each ball and (b) the total mechanical energy of the ballEarth system at the maximum height for each ball. Let y = 0 at the cannon.arrow_forwardA 5.00-kg block is set into motion up an inclined plane with an initial speed of i = 8.00 m/s (Fig. P8.23). The block comes to rest after traveling d = 3.00 m along the plane, which is inclined at an angle of = 30.0 to the horizontal. For this motion, determine (a) the change in the blocks kinetic energy, (b) the change in the potential energy of the block-Earth system, and (c) the friction force exerted on the block (assumed to be constant). (d) What is the coefficient of kinetic friction?arrow_forwardEzra (m = 25.0 kg) has a tire swing and wants to swing as high as possible. He thinks that his best option is to run as fast as he can and jump onto the tire at full speed. The tire has a mass of 10.0 kg and hangs 3.75 m straight down from a tree branch. Ezra stands back 10.0 m and accelerates to a speed of 3.50 m /s before jumping onto the tire swing. a. How fast are Ezra and the tire moving immediately after he jumps onto the swing? b. How high does the tire travel above its initial height?arrow_forward
- Bullet 2 has twice the mass of bullet 1. Both are fired so that they have the same speed. If the kinetic energy of bullet 1 is K, is the kinetic energy of bullet 2 (a) 0.25K, (b) 0.5K, (c) 0.71K. (d) K, or (e) 2K?arrow_forwardFind the kinetic energy of the stone in the preceding example when it has fallen 5.0 m.arrow_forwardA glider of mass m is free to slide along a horizontal air track. It is pushed against a launcher at one end of the track. Model the launcher as a light spring of force constant k compressed by a distance x. The glider is released from rest. (a) Show that the glider attains a speed of v = x(k/m)1/2. (b) Show that the magnitude of the impulse imparted to the glider is given by the expression I = x(km)1/2. (c) Is more work done on a cart with a large or a small mass?arrow_forward
- Consider the following scenario. A car for which friction is not negligible accelerates from rest down a hill, running out of gasoline after a short distance (see below). The driver lets the car coast farther down the hill, then up and over a small crest. He then coasts down that hill into a gas station, where he brakes to a stop and fills that tank with gasoline. Identify the forms of energy the car has, and how they are changed and transferred in this series of events.arrow_forwardDescribe a system for which momentum is conserved but mechanical energy is not. Now the reverse: Describe a system for which kinetic energy is conserved but momentum is not.arrow_forwardDuring a stress test of the cardiovascular system, a patient walks and runs on a treadmill, (a) Is the energy expended by the patient equivalent to the energy of walking and running on the ground? Explain, (b) What effect, if any, does tilting the treadmill upward have? Discuss.arrow_forward
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