1 Structure And Bonding 2 Polar Covalent Bonds; Acids And Bases 3 Organic Compounds: Alkanes And Their Stereochemistry 4 Organic Compounds: Cycloalkanes And Their Stereochemistry 5 Stereochemistry At Tetrahedral Centers 6 An Overview Of Organic Reactions 7 Alkenes: Structure And Reactivity 8 Alkenes: Reactions And Synthesis 9 Alkynes: An Introduction To Organic Synthesis 10 Organohalides 11 Reactions Of Alkyl Halides: Nucleophilic Substitutions And Eliminations 12 Structure Determination: Mass Spectrometry And Infrared Spectroscopy 13 Structure Determination: Nuclear Magnetic Resonance Spectroscopy 14 Conjugated Compounds And Ultraviolet Spectroscopy 15 Benzene And Aromaticity 16 Chemistry Of Benzene: Electrophilic Aromatic Substitution 17 Alcohols And Phenols 18 Ethers And Epoxides; Thiols And Sulfides 19 Aldehydes And Ketones: Nucleophilic Addition Reactions 20 Carboxylic Acids And Nitriles 21 Carboxylic Acid Derivatives: Nucleophilic Acyl Substitution Reactions 22 Carbonyl Alpha-substitution Reactions 23 Carbonyl Condensation Reactions 24 Amines And Heterocycles 25 Biomolecules: Carbohydrates 26 Biomolecules: Amino Acids, Peptides, And Proteins 27 Biomolecules: Lipids 28 Biomolecules: Nucleic Acids 29 The Organic Chemistry Of Metabolic Pathways 30 Orbitals And Organic Chemistry: Pericyclic Reactions 31 Synthetic Polymers expand_more
7.1 Industrial Preparation And Use Of Alkenes 7.2 Calculating Degree Of Unsaturation 7.3 Naming Alkenes 7.4 Cis–trans Isomerism In Alkenes 7.5 Alkene Stereochemistry And The E,z Designation 7.6 Stability Of Alkenes 7.7 Electrophilic Addition Reactions Of Alkenes 7.8 Orientation Of Electrophilic Additions: Markovnikov’s Rule 7.9 Carbocation Structure And Stability 7.10 The Hammond Postulate 7.11 Evidence For The Mechanism Of Electrophilic Additions: Carbocation Rearrangements 7.SE Something Extra expand_more
Problem 22VC Problem 23VC Problem 24VC: The following carbocation is an intermediate in the electrophilic addition reaction of HCl with two... Problem 25VC Problem 26MP: Predict the major product and show the complete mechanism for each electrophilic reaction below. Problem 27MP Problem 28MP: When 1, 3-butadiene reacts with one mole of HBr, two isolable products result. Propose a mechanism... Problem 29MP: When methyl vinyl ether reacts with a strong acid, the proton adds to C2 exclusively, instead of C1... Problem 30MP: Addition of HCl to 1-isopropylcyclohexene yields a rearranged product. Propose a mechanism, showing... Problem 31MP: Addition of HCl to 1-isopropenyl-l-methylcyclopentane yields l-chloro-l,2,2-trimethylcyclohexane.... Problem 32MP: Limonene, a fragrant hydrocarbon found in lemons and oranges, is biosynthesized from geranyl... Problem 33MP Problem 34AP: Calculate the degree of unsaturation in the following formulas, and draw five possible structures... Problem 35AP Problem 36AP Problem 37AP: Name the following alkenes: Problem 38AP: Draw structures corresponding to the following systematic names: (a) (4E)-2, 4-Dimethyl-l,... Problem 39AP Problem 40AP Problem 41AP Problem 42AP Problem 43AP Problem 44AP: Draw and name the 17 alkene isomers, C6H12, including E, Z isomers. Problem 45AP Problem 46AP Problem 47AP: Which of the following E, Z designations are correct, and which are incorrect? Problem 48AP Problem 49AP: trans-2-Butene is more stable than cis-2-butene by only 4 kJ/mol, but trans-2, 2, 5,... Problem 50AP Problem 51AP: Normally, a trans alkene is more stable than its cis isomer. trans-Cyclooctene, however, is less... Problem 52AP: trans-Cyclooctene is less stable than cis-cyclooctene by 38.5 kJ/mol, but trans-cyclononene is less... Problem 53AP Problem 54AP Problem 55AP: Use Hammond’s Postulate to determine which alkene in each pair would be expected to form a... Problem 56AP Problem 57AP: Predict the major product in each of the following reactions: Problem 58AP Problem 59AP Problem 60AP Problem 61AP: Allene (1,2-propadiene), H2C=C=CH2, has two adjacent double bonds. What kind of hybridization must... Problem 62AP: The heat of hydrogenation for allene (Problem 7-61) to yield propane is -295 kJ/mol, and the heat of... Problem 63AP: Retin A, or retinoic acid, is a medication commonly used to reduce wrinkles and treat severe acne.... Problem 64AP Problem 65AP: tert-Butyl esters [RC02C(CH3)3] are converted into carboxylic acids (RCO2H) by reaction with... Problem 66AP: Vinylcyclopropane reacts with HBr to yield a rearranged alkyl bromide. Follow the flow of electrons... Problem 67AP Problem 68AP Problem 69AP Problem 70AP Problem 71AP Problem 72AP: Reaction of 2, 3-dimethyl-l-butene with HBr leads to an alkyl bromide, C6H13Br. On treatment of this... format_list_bulleted