Chemistry: Matter and Change
Chemistry: Matter and Change
1st Edition
ISBN: 9780078746376
Author: Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher: Glencoe/McGraw-Hill School Pub Co
Question
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Chapter 8.3, Problem 42PP
Interpretation Introduction

Interpretation:

The Lewis dot structure of per chlorate ion, ClO4() using concepts of chemical bonding needs to be drawn.

Concept introduction:

For drawing Lewis structure one should know the formula of formal charge atom.

This is represented as follows:

Formal charge = valence electrons non-bonding electrons/lone pair electrons bonding electrons 2.

Expert Solution & Answer
Check Mark

Explanation of Solution

Number of valence electron on Cl7(chlorine)

Number of valence electron on O6(oxygen)

Total number of valence electron on ClO4()7+4(6)+1=32 electrons.

Now, Cl forms double bond with 3 O atoms which results in zero lone pair of Cl and 2 lome pairs on each O atoms. It forms one single bond with 1 oxygen atom which results in the formation of negative charge on it. This is in conjugation with all the oxygen atoms. Also, the O atom with negative charge has 3 lone pair of electrons. Thus, the structure is represented as follows:

Chemistry: Matter and Change, Chapter 8.3, Problem 42PP

Now octet is satisfied for each atom but one has to adjust the formal charge.

Formal charge of chlorine =7082=3

Formal charge of all 3 oxygen atoms =6622=1

Lone pair on chlorine =0

Bonding electron for chlorine =8

Lone pair on oxygen =3

Bonding electron for oxygen =2

Now to adjust and reduce formal charge of chlorine, 3 oxygen atoms will donate 1 lone pair. And stabilize the Lewis dot structure.

Chapter 8 Solutions

Chemistry: Matter and Change

Ch. 8.1 - Prob. 11SSCCh. 8.1 - Prob. 12SSCCh. 8.1 - Prob. 13SSCCh. 8.2 - Prob. 14PPCh. 8.2 - Prob. 15PPCh. 8.2 - Prob. 16PPCh. 8.2 - Prob. 17PPCh. 8.2 - Prob. 18PPCh. 8.2 - Prob. 19PPCh. 8.2 - Prob. 20PPCh. 8.2 - Prob. 21PPCh. 8.2 - Prob. 22PPCh. 8.2 - Prob. 23PPCh. 8.2 - Prob. 24PPCh. 8.2 - Prob. 25PPCh. 8.2 - Prob. 26PPCh. 8.2 - Prob. 27PPCh. 8.2 - Prob. 28PPCh. 8.2 - Prob. 29PPCh. 8.2 - Prob. 30PPCh. 8.2 - Prob. 31SSCCh. 8.2 - Prob. 32SSCCh. 8.2 - Prob. 33SSCCh. 8.2 - Prob. 34SSCCh. 8.2 - Prob. 35SSCCh. 8.2 - Prob. 36SSCCh. 8.3 - Prob. 37PPCh. 8.3 - Prob. 38PPCh. 8.3 - Prob. 39PPCh. 8.3 - Prob. 40PPCh. 8.3 - Prob. 41PPCh. 8.3 - Prob. 42PPCh. 8.3 - Prob. 43PPCh. 8.3 - Prob. 44PPCh. 8.3 - Prob. 45PPCh. 8.3 - Prob. 46PPCh. 8.3 - Prob. 47PPCh. 8.3 - Prob. 48PPCh. 8.3 - Prob. 49PPCh. 8.3 - Prob. 50SSCCh. 8.3 - Prob. 51SSCCh. 8.3 - Prob. 52SSCCh. 8.3 - Prob. 53SSCCh. 8.3 - Prob. 54SSCCh. 8.3 - Prob. 55SSCCh. 8.4 - Prob. 56PPCh. 8.4 - Prob. 57PPCh. 8.4 - Prob. 58PPCh. 8.4 - Prob. 59PPCh. 8.4 - Prob. 60PPCh. 8.4 - Prob. 61SSCCh. 8.4 - Prob. 62SSCCh. 8.4 - Prob. 63SSCCh. 8.4 - Prob. 64SSCCh. 8.4 - Prob. 65SSCCh. 8.4 - Prob. 66SSCCh. 8.4 - Prob. 67SSCCh. 8.5 - Prob. 68SSCCh. 8.5 - Prob. 69SSCCh. 8.5 - Prob. 70SSCCh. 8.5 - Prob. 71SSCCh. 8.5 - Prob. 72SSCCh. 8.5 - Prob. 73SSCCh. 8.5 - Prob. 74SSCCh. 8.5 - Prob. 75SSCCh. 8.5 - Prob. 76SSCCh. 8.5 - Prob. 77SSCCh. 8 - Prob. 78ACh. 8 - Prob. 79ACh. 8 - Prob. 80ACh. 8 - Prob. 81ACh. 8 - Prob. 82ACh. 8 - Prob. 83ACh. 8 - Prob. 84ACh. 8 - Prob. 85ACh. 8 - Prob. 86ACh. 8 - Prob. 87ACh. 8 - Prob. 88ACh. 8 - Prob. 90ACh. 8 - Prob. 91ACh. 8 - Prob. 92ACh. 8 - Prob. 93ACh. 8 - Prob. 94ACh. 8 - Prob. 95ACh. 8 - Prob. 96ACh. 8 - Prob. 97ACh. 8 - Prob. 98ACh. 8 - Prob. 99ACh. 8 - Prob. 100ACh. 8 - Prob. 101ACh. 8 - Prob. 102ACh. 8 - Prob. 103ACh. 8 - Prob. 104ACh. 8 - Prob. 105ACh. 8 - Prob. 106ACh. 8 - Prob. 107ACh. 8 - Prob. 108ACh. 8 - Prob. 109ACh. 8 - Prob. 110ACh. 8 - Prob. 111ACh. 8 - Prob. 112ACh. 8 - Prob. 113ACh. 8 - Prob. 114ACh. 8 - Prob. 115ACh. 8 - Prob. 116ACh. 8 - Prob. 117ACh. 8 - Prob. 118ACh. 8 - Prob. 119ACh. 8 - Rank the bonds according to increasing polarity....Ch. 8 - Prob. 121ACh. 8 - Prob. 122ACh. 8 - Use Lewis structures to predict the molecular...Ch. 8 - Prob. 124ACh. 8 - Prob. 125ACh. 8 - Prob. 126ACh. 8 - Prob. 127ACh. 8 - Prob. 128ACh. 8 - Prob. 129ACh. 8 - Prob. 130ACh. 8 - Prob. 131ACh. 8 - Prob. 132ACh. 8 - Prob. 133ACh. 8 - Prob. 134ACh. 8 - Prob. 135ACh. 8 - Prob. 136ACh. 8 - Prob. 137ACh. 8 - Prob. 138ACh. 8 - Prob. 139ACh. 8 - Prob. 140ACh. 8 - Prob. 141ACh. 8 - Prob. 142ACh. 8 - Prob. 143ACh. 8 - Prob. 144ACh. 8 - Prob. 145ACh. 8 - Prob. 1STPCh. 8 - Prob. 2STPCh. 8 - Prob. 3STPCh. 8 - Prob. 4STPCh. 8 - Prob. 5STPCh. 8 - Prob. 6STPCh. 8 - Prob. 7STPCh. 8 - Prob. 8STPCh. 8 - Prob. 9STPCh. 8 - Prob. 10STPCh. 8 - Prob. 11STPCh. 8 - Prob. 12STPCh. 8 - Prob. 13STPCh. 8 - Prob. 14STPCh. 8 - Prob. 15STPCh. 8 - Prob. 16STPCh. 8 - Prob. 17STPCh. 8 - Prob. 18STPCh. 8 - Prob. 19STP
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