(a) Interpretation: The structure from the given IUPAC name is to be drawn. Concept introduction: The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Question

Draw the molecule that corresponds to each IUPAC name. (a) 2,3-dimethylcyclopentanone; (b) 4,4-difluoroheptanal;(c) 1,1,1-trichloropentan-3-one; (d) (1S,3S)-3-ethoxycyclohexanecarbaldehyde

Answer 1

Question

Chapter E, Problem E.36P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(c)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(d)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise the absolute configuration is R and if it is counterclockwise the absolute configuration is S.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Students have asked these similar questions

Draw the molecule that corresponds to each IUPAC name. (a) 2,3-dimethylcyclopentanone; (b) 4,4-difluoroheptanal;(c) 1,1,1-trichloropentan-3-one; (d) (1S,3S)-3-ethoxycyclohexanecarbaldehyde

Label the functional group(s) in each compound as ethers or acetals.

Answer each question using the ball-and-stick model of compound A. Draw a constitutional isomer that contains an ether and give its IUPACname. Draw the products formed (including stereochemistry) when A istreated with each reagent: [1] NaH; [2] H2SO4; [3] POCl3, pyridine; [4]HCl; [5] SOCl2, pyridine; [6] TsCl, pyridine

Answer 2

Question

Chapter E, Problem E.36P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(c)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(d)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise the absolute configuration is R and if it is counterclockwise the absolute configuration is S.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 3

Question

Chapter E, Problem E.36P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(c)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(d)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise the absolute configuration is R and if it is counterclockwise the absolute configuration is S.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 4

Question

Chapter E, Problem E.36P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(c)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(d)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise the absolute configuration is R and if it is counterclockwise the absolute configuration is S.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 5

Chapter E, Problem E.36P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(c)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Interpretation Introduction

(d)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise the absolute configuration is R and if it is counterclockwise the absolute configuration is S.

Answer 6

Chapter E, Problem E.36P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Answer 7

Chapter E, Problem E.36P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise the absolute configuration is R and if it is counterclockwise the absolute configuration is S.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise the absolute configuration is R and if it is counterclockwise the absolute configuration is S.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 17

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 18

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 19

Trending nowThis is a popular solution!

Answer 20

Trending nowThis is a popular solution!

Answer 21

Trending nowThis is a popular solution!

Answer 22

Trending now

Answer 23

This is a popular solution!

Answer 24

See solution

Check out sample textbook solution

Answer 25

Ch. E - Prob. E.1P Ch. E - Prob. E.2P Ch. E - Prob. E.3P Ch. E - Prob. E.4P Ch. E - Prob. E.5P Ch. E - Prob. E.6P Ch. E - Prob. E.7P Ch. E - Prob. E.8P Ch. E - Prob. E.9P Ch. E - Prob. E.10P

Solution Summary: The structure for the given IUPAC name is drawn by identifying the highest priority functional group from the suffix, main ring from root name and the number of substituents from locators.

Concept explainers

Chapter E Solutions