Explanation Primary amines have the higher boiling points as they have polar nitrogen-hydrogen bond present in them. Primary amine has the ability to form strong intermolecular hydrogen bonding with -NH 2 group. In ether, the carbon-oxygen-carbon bond is similar to the carbon-carbon bond in alkanes

Chemical Principles: The Quest for Insight

7th Edition

ISBN: 9781464183959

Author: Peter Atkins, Loretta Jones, Leroy Laverman

Publisher: W. H. Freeman

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Question

Chapter 11, Problem 11D.2AST

Interpretation Introduction

Interpretation:

Among a primary amine and ether, the functional group with higher boiling point has to be identified and the reason has to be explained.

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Chapter 11, Problem 11D.1BST

Chapter 11, Problem 11D.2BST

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Chapter 11 Solutions

Chemical Principles: The Quest for Insight

Ch. 11 - Prob. 11A.1AST Ch. 11 - Prob. 11A.1BST Ch. 11 - Prob. 11A.2AST Ch. 11 - Prob. 11A.2BST Ch. 11 - Prob. 11A.3AST Ch. 11 - Prob. 11A.3BST Ch. 11 - Prob. 11A.4AST Ch. 11 - Prob. 11A.4BST Ch. 11 - Prob. 11A.5AST Ch. 11 - Prob. 11A.5BST

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Among a primary amine and ether, the functional group with higher boiling point has to be identified and the reason has to be explained.

Solution Summary: The author explains that primary amine has a higher boiling point than ether due to the presence of strong intermolecular hydrogen bonding.

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Interpretation: Among a primary amine and ether, the functional group with higher boiling point has to be identified and the reason has to be explained.

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Chapter 11 Solutions

Interpretation:

Among a primary amine and ether, the functional group with higher boiling point has to be identified and the reason has to be explained.