General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 12, Problem 50P
Give the structure corresponding to each IUPAC name
- 3-ethyl-3-methylhexane
- 2,2,3,4-tetramethylhexane
- 4-ethyl-2,2-dimethyloctane
- 1,3,5-triethylcycloheptane
- 3-ethyl-3,4-dimethylnonane
- 2-ethyl-1 -methyl-3-propylcyclopentane
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Give the structure corresponding to each IUPAC name.
a. 3-methylhexane
b. 3,3-dimethylpentane
c. 3,5,5-trimethyloctane
d. 3-ethyl-4-methylhexane
e. 3-ethyl-5-isobutylnonane
Draw skeletal structure corresponding to each IUPAC name
1,2-dimethylcyclopentene
6-ethyl-2-octyne
3,3-dimethyl-1,4-pentadiene
trans-5-methyl-2-hexene
5,6-dimethyl-2-heptyne
3,4,5,6-tetramethyl-1-decyne
4-methyl-1-hexene
methylcyclohexene
Give the structure corresponding to each IUPAC name.
a.1,2-dimethylcyclobutane
b.1,1,2-trimethylcyclopropane
c. 4-ethyl-1,2-dimethylcyclohexane
d.1-sec-butyl-3-isopropylcyclopentane
e.1,1,2,3,4-pentamethylcycloheptane
Chapter 12 Solutions
General, Organic, and Biological Chemistry - 4th edition
Ch. 12.1 - How many hydrogen atoms are present in each...Ch. 12.1 - Which formulas represent acyclic alkanes and which...Ch. 12.2 - Are the compounds in each pair constitutional...Ch. 12.2 - Draw two isomers with molecular formula C6H14 that...Ch. 12.2 - Prob. 12.3PCh. 12.2 - Classify the carbon atoms in each compound as 1°,...Ch. 12.2 - Prob. 12.4PCh. 12.2 - Prob. 12.5PCh. 12.2 - Prob. 12.6PCh. 12.2 - Prob. 12.7P
Ch. 12.2 - Prob. 12.8PCh. 12.2 - Prob. 12.9PCh. 12.4 - Give the IUPAC name for each compound.Ch. 12.4 - Prob. 12.10PCh. 12.4 - Give the IUPAC name for each compound....Ch. 12.4 - Prob. 12.5PPCh. 12.4 - Prob. 12.6PPCh. 12.4 - Prob. 12.12PCh. 12.5 - Prob. 12.13PCh. 12.5 - Prob. 12.14PCh. 12.5 - Give the IUPAC name for each compound.Ch. 12.5 - Prob. 12.15PCh. 12.7 - Answer the following questions about pentane...Ch. 12.7 - Prob. 12.17PCh. 12.7 - Prob. 12.18PCh. 12.8 - Prob. 12.19PCh. 12.9 - Prob. 12.20PCh. 12.9 - Prob. 12.21PCh. 12.9 - Prob. 12.22PCh. 12 - Prob. 23PCh. 12 - Prob. 24PCh. 12 - The waxy coating on the surface of apple skins...Ch. 12 - Prob. 26PCh. 12 - Classify each carbon as 1°, 2°, 3°, or 4°. a....Ch. 12 - Give the structure of an alkane that fits each...Ch. 12 - Prob. 29PCh. 12 - Label each pair of compounds as constitutional...Ch. 12 - Consider compounds A, B, and C. Label each pair of...Ch. 12 - Consider compounds D,E, and F. Label each pair of...Ch. 12 - Prob. 33PCh. 12 - Consider compounds A-E and label each pair of...Ch. 12 - Draw structures that fit the following...Ch. 12 - Draw the five constitutional isomers having...Ch. 12 - Prob. 37PCh. 12 - Prob. 38PCh. 12 - Draw the five constitutional isomers that have...Ch. 12 - Pristane is a high molecular weight alkane found...Ch. 12 - Give the IUPAC name for each of the five...Ch. 12 - Give the IUPAC name for each of the five cyclic...Ch. 12 - Give the IUPAC name for each compoundCh. 12 - Give the IUPAC name for each compound.Ch. 12 - Give the IUPAC name for each compound. c....Ch. 12 - Give the IUPAC name for each compound.Ch. 12 - Give the IUPAC name for each cycloalkane.Ch. 12 - Give the IUPAC name for each ccycloalkane.Ch. 12 - Prob. 49PCh. 12 - Give the structure corresponding to each IUPAC...Ch. 12 - Each of the following IUPAC names is incorrect....Ch. 12 - Each of the following IUPAC names is incorrect....Ch. 12 - Draw three constitutional isomers having molecular...Ch. 12 - Draw four constitutional isomers having molecular...Ch. 12 - Draw a skeletal structure for each compound octane...Ch. 12 - Convert each compound to a skeletal structure CH3(...Ch. 12 - Convert each skeletal structure to a complete...Ch. 12 - Convert each skeletal structure to a complete...Ch. 12 - Which compound in each pair has the higher melting...Ch. 12 - Which compound in each pair has the higher boiling...Ch. 12 - Branching in an alkane chain decreases surface...Ch. 12 - Explain why the boiling points of heptane [CH3( CH...Ch. 12 - Explain why hexane is more soluble in...Ch. 12 - Mineral oil and Vaseline are both mixtures of...Ch. 12 - Write a balanced equation for the combustion of...Ch. 12 - Write a balanced equation for the combustion of...Ch. 12 - Write a balanced equation for the incomplete...Ch. 12 - Prob. 68PCh. 12 - Prob. 69PCh. 12 - Prob. 70PCh. 12 - Prob. 71PCh. 12 - Prob. 72PCh. 12 - Prob. 73PCh. 12 - Prob. 74PCh. 12 - Prob. 75PCh. 12 - Prob. 76PCh. 12 - Prob. 77PCh. 12 - Prob. 78PCh. 12 - Prob. 79PCh. 12 - A major component of animal fat is tristearin, (a)...Ch. 12 - Answer the following questions about the alkane...Ch. 12 - Prob. 82PCh. 12 - Answer the questions in Problem 12.81 for the...Ch. 12 - Prob. 84PCh. 12 - Prob. 85CPCh. 12 - Draw the structure of the 12 constitutional...Ch. 12 - Cyclopentane has a higher boiling point than...Ch. 12 - Prob. 88CP
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- The following names are incorrect by IUPAC rules. Determine the correct IUPAC name for each compound. a. 2-Ethyl-2-pentene b. 4,5-Dimethyl-4-hexene c. 3,5-Cyclopentadiene d. l,2-Dimethyl-4-cyclohexenearrow_forwardThe following names are incorrect by IUPAC rules. Determine the correct IUPAC name for each compound. a. 2-Methyl-4-pentene b. 3-Methyl-2,4-pentadiene c. 3-Methyl-3-cyclopentene d. 1,2-Dimethyl-3-cyclohexenearrow_forwardWhich IUPAC name? 5-isopropyl-2-methylhexane 2-isopropyl-5-methylhexane 2-isopropylheptane 2,2,3,6-tetramethylheptane 2,3,6-trimethylheptanearrow_forward
- Given each of the IUPAC names provided, draw the corresponding structure.(a) 2,4-dicyclopropyl-2-ethoxyhexane(b) 1,2-dichloro-1-(2-methylpropyl)-4-nitrocyclohexane(c) 1,3-dicyclopentyl-1,2,3,4-tetramethoxycyclooctane(d) 1-cyclobutyl-4-(1,1-dimethylethyl)-2,4-dinitrononane(e) 1-(1,1-dimethylbutyl)-2-ethoxy-1,2,3-trinitrocyclobutane(f) 1,2,4-tricyclopropyl-1-(2,2-dichloropentyl)cyclohexane(g) 4-(2-chloro-1-methoxyethyl)-1,1-dinitroheptane(h) 3,3,4-trichloro-1-cyclohexoxy-4-(1,1-dichloroethyl)decanearrow_forwardDraw the structure corresponding to each IUPAC name. a.3-ethyl-2-methylhexane b. sec-butylcyclopentane c.4-isopropyl-2,4,5-trimethylundecane d.cyclobutylcycloheptane e.3-ethyl-1,1-dimethylcyclohexane f. 4-butyl-1,1-diethylcyclooctane g.6-isopropyl-2,3-dimethyldodecane h. 2,2,6,6,7-pentamethyloctane i. cis-1-ethyl-3-methylcyclopentane j. trans-1-tert-butyl-4-ethylcyclohexanearrow_forwardA correct IUPAC name for the following compound is: 1. 2-isopropyl-1-pentene 2. 2-methyl-3-methylenehexane 3. 2-methyl-3-propyl-3-butene 4. 2-methyl-3-propyl-1-butene 5. 3-methyl-2-propyl-1-butenearrow_forward
- iupac name? Cyclohexane 2,2-dimethylbutane 1,2-dimethylcyclobutane 2-methyl-2-pentene Methylcyclopentanearrow_forwardGiven each of the IUPAC names provided, draw the corresponding structure. (a) 1-(1,1-dimethylethyl)-2,4-diethylcyclohexane; (b) 1,4-dibutyl-2-(1-methylpropyl)cyclooctane; (c) 1,1-dicyclopropyl-3-(1,1-dimethylethyl)cycloheptanearrow_forward1. What orbitals (around Carbon) are used to form each bond in the following molecules: A. CH3CH3 B. CH2CH2 2. Draw the structure corresponding to each IUPAC name: 3-ethyl-1,1-dimethylcyclohexane, 6-isopropyl-2,3-dimethylnonanearrow_forward
- Draw the structure that corresponds with each name.(a) 3-ethyloctane (b) 4-isopropyldecane (c) sec-butylcycloheptane(d) 2,3-dimethyl-4-propylnonane (e) 2,2,4,4-tetramethylhexane (f) trans-1,3-diethylcyclopentane(g) cis-1-ethyl-4-methylcyclohexane (h) isobutylcyclopentane (i) tert-butylcyclohexane(j) pentylcyclohexane (k) cyclobutylcyclohexane (l) cis-1-bromo-3-chlorocyclohexanearrow_forwardEach of the following IUPAC names is incorrect. Explain why it is incorrect and give the correct IUPAC name.a. 2,2-dimethyl-4-ethylheptaneb. 5-ethyl-2-methylhexanec. 2-methyl-2-isopropylheptaned. 1,5-dimethylcyclohexanee. 1-ethyl-2,6-dimethylcycloheptanef. 5,5,6-trimethyloctaneg. 3-butyl-2,2-dimethylhexanearrow_forwardDraw the open structures of the molecules named below according to the IUPAC naming system. 1-chloro-3-ethyl benzene 4- (tert-butyl) -5-ethyl octane 3-Methylpentanal (1E, 3Z, 5E) -5-chloro-6-phenyl hexa-1,3,5-trien-1-olarrow_forward
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