General, Organic, and Biological Chemistry - 4th edition
General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
Question
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Chapter 12, Problem 84P
Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the following alkane should be determined.

  General, Organic, and Biological Chemistry - 4th edition, Chapter 12, Problem 84P , additional homework tip  1

Concept Introduction:

Alkanes are compounds containing only carbon and hydrogen atoms bonded through single bonds only.

In order to give an IUPAC name to an alkane following rules are followed:

  1. The longest carbon chain that is parent chain is determined and suffix −ane for alkane is used in the name.
  2. For cyclic alkanes, the prefix cyclo is used in the name to indicate that the alkane is cyclic.
  3. The numbering of the parent chain is done in such a way that the substituents get the lowest numbers.
  4. Name should be written in alphabetical order.
  5. Hyphen is used to connect the number to the name.
  6. For number of carbons atoms in alkane chain, the prefix is given as:

    Carbon-1  meth

    Carbon-2  eth

    Carbon-3  prop

    Carbon-4  but

    Carbon-5  pent

    Carbon-6  hex

    Carbon-7  hept

    Carbon-8  oct

    Carbon-9  non

    Carbon-10  dec

Interpretation Introduction

(b)

Interpretation:

One constitutional isomer of the following alkane should be drawn.

  General, Organic, and Biological Chemistry - 4th edition, Chapter 12, Problem 84P , additional homework tip  2

Concept Introduction:

Constitutional isomers can be defined as the pair of molecules with the same molecular formula, but different structural formula. This phenomenon is known as isomerism.

Interpretation Introduction

(c)

Interpretation:

The solubility of given molecule in water should be explained.

Concept Introduction:

The solubility of a molecule depends on the polarity of the solvent and solution that means like dissolve like. In other words, the polar molecule is soluble in polar solvent only and in non-polar solvents, the soluble molecule will be non-polar in nature.

Interpretation Introduction

(d)

Interpretation:

The solubility of given molecule in organic solvent should be explained.

Concept Introduction:

The solubility of a molecule depends on the polarity of the solvent and solution that means like dissolve like. In other words, the polar molecule is soluble in polar solvent only and in non-polar solvents, the soluble molecule will be non-polar in nature.

Interpretation Introduction

(e)

Interpretation:

The balanced equation for the complete combustion of the given compound should be determined.

Concept Introduction:

Chemical equation is written in such a way that the symbolic representation of reaction represents the reaction taking place in the system. The reactants are written on the left-hand side and the products are written on the right-hand side of the equation and are separated by an arrow, two or more reactants and products are separated by "+".

The reactions for those the number of atoms of each element in the reactant and in the product, side are equal, such reactions are said to be a balanced chemical equation.

Interpretation Introduction

(f)

Interpretation:

The skeletal structure of the given compound should be determined.

Concept Introduction:

The formula of a compound that shows the bonds between the atoms and other atoms omitting carbon and hydrogen atoms is said to be skeletal structure of that compound. In these structures, the bond between any atom(s) and hydrogen is also omitted.

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Chapter 12 Solutions

General, Organic, and Biological Chemistry - 4th edition

Ch. 12.2 - Prob. 12.8PCh. 12.2 - Prob. 12.9PCh. 12.4 - Give the IUPAC name for each compound.Ch. 12.4 - Prob. 12.10PCh. 12.4 - Give the IUPAC name for each compound....Ch. 12.4 - Prob. 12.5PPCh. 12.4 - Prob. 12.6PPCh. 12.4 - Prob. 12.12PCh. 12.5 - Prob. 12.13PCh. 12.5 - Prob. 12.14PCh. 12.5 - Give the IUPAC name for each compound.Ch. 12.5 - Prob. 12.15PCh. 12.7 - Answer the following questions about pentane...Ch. 12.7 - Prob. 12.17PCh. 12.7 - Prob. 12.18PCh. 12.8 - Prob. 12.19PCh. 12.9 - Prob. 12.20PCh. 12.9 - Prob. 12.21PCh. 12.9 - Prob. 12.22PCh. 12 - Prob. 23PCh. 12 - Prob. 24PCh. 12 - The waxy coating on the surface of apple skins...Ch. 12 - Prob. 26PCh. 12 - Classify each carbon as 1°, 2°, 3°, or 4°. a....Ch. 12 - Give the structure of an alkane that fits each...Ch. 12 - Prob. 29PCh. 12 - Label each pair of compounds as constitutional...Ch. 12 - Consider compounds A, B, and C. Label each pair of...Ch. 12 - Consider compounds D,E, and F. Label each pair of...Ch. 12 - Prob. 33PCh. 12 - Consider compounds A-E and label each pair of...Ch. 12 - Draw structures that fit the following...Ch. 12 - Draw the five constitutional isomers having...Ch. 12 - Prob. 37PCh. 12 - Prob. 38PCh. 12 - Draw the five constitutional isomers that have...Ch. 12 - Pristane is a high molecular weight alkane found...Ch. 12 - Give the IUPAC name for each of the five...Ch. 12 - Give the IUPAC name for each of the five cyclic...Ch. 12 - Give the IUPAC name for each compoundCh. 12 - Give the IUPAC name for each compound.Ch. 12 - Give the IUPAC name for each compound. c....Ch. 12 - Give the IUPAC name for each compound.Ch. 12 - Give the IUPAC name for each cycloalkane.Ch. 12 - Give the IUPAC name for each ccycloalkane.Ch. 12 - Prob. 49PCh. 12 - Give the structure corresponding to each IUPAC...Ch. 12 - Each of the following IUPAC names is incorrect....Ch. 12 - Each of the following IUPAC names is incorrect....Ch. 12 - Draw three constitutional isomers having molecular...Ch. 12 - Draw four constitutional isomers having molecular...Ch. 12 - Draw a skeletal structure for each compound octane...Ch. 12 - Convert each compound to a skeletal structure CH3(...Ch. 12 - Convert each skeletal structure to a complete...Ch. 12 - Convert each skeletal structure to a complete...Ch. 12 - Which compound in each pair has the higher melting...Ch. 12 - Which compound in each pair has the higher boiling...Ch. 12 - Branching in an alkane chain decreases surface...Ch. 12 - Explain why the boiling points of heptane [CH3( CH...Ch. 12 - Explain why hexane is more soluble in...Ch. 12 - Mineral oil and Vaseline are both mixtures of...Ch. 12 - Write a balanced equation for the combustion of...Ch. 12 - Write a balanced equation for the combustion of...Ch. 12 - Write a balanced equation for the incomplete...Ch. 12 - Prob. 68PCh. 12 - Prob. 69PCh. 12 - Prob. 70PCh. 12 - Prob. 71PCh. 12 - Prob. 72PCh. 12 - Prob. 73PCh. 12 - Prob. 74PCh. 12 - Prob. 75PCh. 12 - Prob. 76PCh. 12 - Prob. 77PCh. 12 - Prob. 78PCh. 12 - Prob. 79PCh. 12 - A major component of animal fat is tristearin, (a)...Ch. 12 - Answer the following questions about the alkane...Ch. 12 - Prob. 82PCh. 12 - Answer the questions in Problem 12.81 for the...Ch. 12 - Prob. 84PCh. 12 - Prob. 85CPCh. 12 - Draw the structure of the 12 constitutional...Ch. 12 - Cyclopentane has a higher boiling point than...Ch. 12 - Prob. 88CP
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