General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
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Question
Chapter 12.5, Problem 12.15P
Interpretation Introduction
(a)
Interpretation:
The structure of propyl cyclopentane needs to be determined.
Concept introduction:
The rules to write the IUPAC name of molecules are as follows:
- Check the longest C chain and assign root word for that.
- Add prefix for the branch or side chain with its position.
- Add di, tri, tetra prefix for more than one prefix.
- The primary suffix indicates the single, double and triple bond in the molecule.
- Secondary suffix indicates the presence of functional group in the molecule.
- In cyclic compounds the ring is named as cycloalkane.
Interpretation Introduction
(b)
Interpretation:
Structure of 1,2-dimethylcyclobutane needs to be determined.
Concept introduction:
The rules to write the IUPAC name of molecules are as follows:
- Check the longest C chain and assign root word for that.
- Add prefix for the branch or side chain with its position.
- Add di, tri, tetra prefix for more than one prefix.
- The primary suffix indicates the single, double and triple bond in the molecule.
- Secondary suffix indicates the presence of functional group in the molecule.
- In cyclic compounds the ring is named as cycloalkane.
Interpretation Introduction
(c)
Interpretation:
The structure of 1, 1, 2-trimethylcyclopropane needs to be determined.
Concept introduction:
The rules to write the IUPAC name of molecules are as follows:
- Check the longest C chain and assign root word for that.
- Add prefix for the branch or side chain with its position.
- Add di, tri, tetra prefix for more than one prefix.
- The primary suffix indicates the single, double and triple bond in the molecule.
- Secondary suffix indicates the presence of functional group in the molecule.
- In cyclic compounds the ring is named as cycloalkane.
Interpretation Introduction
(d)
Interpretation:
The structure of 4-ethyl-1,2-dimethylcyclohexane needs to be determined.
Concept introduction:
The rules to write the IUPAC name of molecules are as follows:
- Check the longest C chain and assign root word for that.
- Add prefix for the branch or side chain with its position.
- Add di, tri, tetra prefix for more than one prefix.
- The primary suffix indicates the single, double and triple bond in the molecule.
- Secondary suffix indicates the presence of functional group in the molecule.
- In cyclic compounds the ring is named as cycloalkane.
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By adding tetraethyl lead to iso-octane:
A.
Exhaust smoke can be reduced
B.
Knocking can be completely suppressed
C.
Octane number above 100 can be obtained
D.
Specific fuel consumption can be reduced
Give the structure corresponding to each IUPAC name
(a) 3-ethyl-3-methyloctane
(b) 2,3,4,5-tetramethyldecane
Draw the structure that corresponds with each name.(a) 3-ethyloctane (b) 4-isopropyldecane (c) sec-butylcycloheptane(d) 2,3-dimethyl-4-propylnonane (e) 2,2,4,4-tetramethylhexane (f) trans-1,3-diethylcyclopentane(g) cis-1-ethyl-4-methylcyclohexane (h) isobutylcyclopentane (i) tert-butylcyclohexane(j) pentylcyclohexane (k) cyclobutylcyclohexane (l) cis-1-bromo-3-chlorocyclohexane
Chapter 12 Solutions
General, Organic, and Biological Chemistry - 4th edition
Ch. 12.1 - How many hydrogen atoms are present in each...Ch. 12.1 - Which formulas represent acyclic alkanes and which...Ch. 12.2 - Are the compounds in each pair constitutional...Ch. 12.2 - Draw two isomers with molecular formula C6H14 that...Ch. 12.2 - Prob. 12.3PCh. 12.2 - Classify the carbon atoms in each compound as 1°,...Ch. 12.2 - Prob. 12.4PCh. 12.2 - Prob. 12.5PCh. 12.2 - Prob. 12.6PCh. 12.2 - Prob. 12.7P
Ch. 12.2 - Prob. 12.8PCh. 12.2 - Prob. 12.9PCh. 12.4 - Give the IUPAC name for each compound.Ch. 12.4 - Prob. 12.10PCh. 12.4 - Give the IUPAC name for each compound....Ch. 12.4 - Prob. 12.5PPCh. 12.4 - Prob. 12.6PPCh. 12.4 - Prob. 12.12PCh. 12.5 - Prob. 12.13PCh. 12.5 - Prob. 12.14PCh. 12.5 - Give the IUPAC name for each compound.Ch. 12.5 - Prob. 12.15PCh. 12.7 - Answer the following questions about pentane...Ch. 12.7 - Prob. 12.17PCh. 12.7 - Prob. 12.18PCh. 12.8 - Prob. 12.19PCh. 12.9 - Prob. 12.20PCh. 12.9 - Prob. 12.21PCh. 12.9 - Prob. 12.22PCh. 12 - Prob. 23PCh. 12 - Prob. 24PCh. 12 - The waxy coating on the surface of apple skins...Ch. 12 - Prob. 26PCh. 12 - Classify each carbon as 1°, 2°, 3°, or 4°. a....Ch. 12 - Give the structure of an alkane that fits each...Ch. 12 - Prob. 29PCh. 12 - Label each pair of compounds as constitutional...Ch. 12 - Consider compounds A, B, and C. Label each pair of...Ch. 12 - Consider compounds D,E, and F. Label each pair of...Ch. 12 - Prob. 33PCh. 12 - Consider compounds A-E and label each pair of...Ch. 12 - Draw structures that fit the following...Ch. 12 - Draw the five constitutional isomers having...Ch. 12 - Prob. 37PCh. 12 - Prob. 38PCh. 12 - Draw the five constitutional isomers that have...Ch. 12 - Pristane is a high molecular weight alkane found...Ch. 12 - Give the IUPAC name for each of the five...Ch. 12 - Give the IUPAC name for each of the five cyclic...Ch. 12 - Give the IUPAC name for each compoundCh. 12 - Give the IUPAC name for each compound.Ch. 12 - Give the IUPAC name for each compound. c....Ch. 12 - Give the IUPAC name for each compound.Ch. 12 - Give the IUPAC name for each cycloalkane.Ch. 12 - Give the IUPAC name for each ccycloalkane.Ch. 12 - Prob. 49PCh. 12 - Give the structure corresponding to each IUPAC...Ch. 12 - Each of the following IUPAC names is incorrect....Ch. 12 - Each of the following IUPAC names is incorrect....Ch. 12 - Draw three constitutional isomers having molecular...Ch. 12 - Draw four constitutional isomers having molecular...Ch. 12 - Draw a skeletal structure for each compound octane...Ch. 12 - Convert each compound to a skeletal structure CH3(...Ch. 12 - Convert each skeletal structure to a complete...Ch. 12 - Convert each skeletal structure to a complete...Ch. 12 - Which compound in each pair has the higher melting...Ch. 12 - Which compound in each pair has the higher boiling...Ch. 12 - Branching in an alkane chain decreases surface...Ch. 12 - Explain why the boiling points of heptane [CH3( CH...Ch. 12 - Explain why hexane is more soluble in...Ch. 12 - Mineral oil and Vaseline are both mixtures of...Ch. 12 - Write a balanced equation for the combustion of...Ch. 12 - Write a balanced equation for the combustion of...Ch. 12 - Write a balanced equation for the incomplete...Ch. 12 - Prob. 68PCh. 12 - Prob. 69PCh. 12 - Prob. 70PCh. 12 - Prob. 71PCh. 12 - Prob. 72PCh. 12 - Prob. 73PCh. 12 - Prob. 74PCh. 12 - Prob. 75PCh. 12 - Prob. 76PCh. 12 - Prob. 77PCh. 12 - Prob. 78PCh. 12 - Prob. 79PCh. 12 - A major component of animal fat is tristearin, (a)...Ch. 12 - Answer the following questions about the alkane...Ch. 12 - Prob. 82PCh. 12 - Answer the questions in Problem 12.81 for the...Ch. 12 - Prob. 84PCh. 12 - Prob. 85CPCh. 12 - Draw the structure of the 12 constitutional...Ch. 12 - Cyclopentane has a higher boiling point than...Ch. 12 - Prob. 88CP
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